Search Results - "Tsuda, Akihiko"
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Spectroscopic Visualization of Vortex Flows Using Dye-Containing Nanofibers
Published in Angewandte Chemie (International ed.) (2007)“…Which way around? A J‐aggregated zinc porphyrin dendrimer can be used to detect the macroscopic chirality of a vortex. The sign of the circular dichroism…”
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Design of Porphyrin Nanoclusters toward Discovery of Novel Properties and Functions
Published in Bulletin of the Chemical Society of Japan (2009)“…We have designed a variety of functional metalloporphyrin nanoclusters, connected via covalent or noncovalent linkages, since a discovery of fused…”
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Photo-on-Demand Phosgenation Reactions with Chloroform for Selective Syntheses of N‑Substituted Ureas and Isocyanates
Published in ACS omega (15-02-2022)“…Two new reaction processes involving the in situ oxidative photochemical conversion of CHCl3 to COCl2 allowed selective syntheses of N-substituted ureas and…”
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Vortex-induced alignment of a water soluble supramolecular nanofiber composed of an amphiphilic dendrimer
Published in Molecules (Basel, Switzerland) (17-06-2013)“…We have synthesized a novel amphiphilic naphthalene imide bearing a cationic dendrimer wedge (NID). NID molecules in water self-assemble to form a…”
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Brominated Methanes as Photoresponsive Molecular Storage of Elemental Br2
Published in Chemistry, an Asian journal (01-10-2012)“…The photochemical generation of elemental Br2 from brominated methanes is reported. Br2 was generated by the vaporization of carbon oxides and HBr through…”
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Spectroscopic visualization of sound-induced liquid vibrations using a supramolecular nanofibre
Published in Nature chemistry (01-11-2010)“…The question of whether sound vibration of a medium can bring about any kind of molecular or macromolecular events is a long-standing scientific controversy…”
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Syntheses, Structural Characterizations, and Optical and Electrochemical Properties of Directly Fused Diporphyrins
Published in Journal of the American Chemical Society (24-10-2001)“…Directly fused diporphyrins display the extensive π conjugation as evinced by highly perturbed electronic absorption spectra as well as lowered and largely…”
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Chiroptical Sensing of Asymmetric Hydrocarbons Using a Homochiral Supramolecular Box from a Bismetalloporphyrin Rotamer
Published in Angewandte Chemie International Edition (01-01-2007)“…The surrounding shapes the box: The zinc porphyrin dimer 1 bearing pyridyl groups can chiroptically sense an asymmetric hydrocarbon, such as limonene, by…”
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Porphyrin Boxes Constructed by Homochiral Self-Sorting Assembly: Optical Separation, Exciton Coupling, and Efficient Excitation Energy Migration
Published in Journal of the American Chemical Society (15-12-2004)“…meso-Pyridine-appended zinc(II) porphyrins M n and their meso − meso-linked dimers D n assemble spontaneously, in noncoordinating solvents such as CHCl3, into…”
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Direct Syntheses of Diphenylmethanol Derivatives from Substituted Benzenes and CHCl3 through Friedel‐Crafts Alkylation and Post‐Synthetic Hydrolysis or Alcoholysis Catalyzed by Alumina
Published in ChemistryOpen (Weinheim) (01-05-2022)“…The present study reports an innovative finding that alumina containing water or primary alcohol catalyzes the hydrolysis or alcoholysis, respectively, of the…”
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Completely Fused Diporphyrins and Triporphyrin
Published in Angewandte Chemie International Edition (17-07-2000)“…Extremely delocalized π‐electronic systems are found in triply linked, fused porphyrins, which are formed by the oxidation of diporphyrins [Eq. (1)]. Stronger…”
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Photophysical Properties of Porphyrin Tapes
Published in Journal of the American Chemical Society (11-12-2002)“…The novel fused Zn(II)porphyrin arrays (Tn, porphyrin tapes) in which the porphyrin macrocycles are triply linked at meso − meso, β − β, β − β positions have…”
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Hydrodynamic Helical Orientations of Nanofibers in a Vortex
Published in Symmetry (2014)“…In this review article, I report our recent studies on spectroscopic visualizations of macroscopic helical alignments of nanofibers in vortex flows. Our…”
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Directed 1D Assembly of a Ring-Shaped Inorganic Nanocluster Templated by an Organic Rigid-Rod Molecule: An Inorganic/Organic Polypseudorotaxane
Published in Angewandte Chemie (International ed.) (28-02-2008)“…Facing up to matters: Template‐assisted cofacial assembly of a ring‐shaped polyoxomolybdate cluster (MC) by an oligomeric p‐phenylenebutadiynylene rigid rod…”
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A Chiral Metal-Organic 1D-Coordination Polymer Upon Complexation of Phenylene-Bridged Bipyrrole and Palladium (II) Ion
Published in Frontiers in chemistry (01-12-2020)“…Metal-organic 1D-coordination polymers, having unique electronic and optical properties, are expected to be a novel advanced functional material capable of…”
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Amplified Chiral Transformation through Helical Assembly
Published in Angewandte Chemie (International ed.) (01-01-2007)“…Majority rules: “Chiral amplification” in asymmetric transformations can be realized if a helical supramolecular polymer, derived from the substrate (S), obeys…”
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Spectroscopic Visualization of Right- and Left-Handed Helical Alignments of DNA in Chiral Vortex Flows
Published in Bulletin of the Chemical Society of Japan (15-10-2011)“…In a vortex generated by mechanical rotary stirring in an optical cell, DNA molecules in pure water temporarily align helically to the spiral flow, and…”
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Excitation Energy Migration Processes in Self-Assembled Porphyrin Boxes Constructed by Conjugated Porphyrin Dimers
Published in The journal of physical chemistry. B (22-07-2010)“…meso-Pyridine-appended alkynylene-bridged zinc(II) porphyrin dimers D2 and D4 assemble spontaneously, in noncoordinating solvents such as toluene, into…”
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Editorial: Supramolecular Chirogenesis in Chemical and Related Sciences
Published in Frontiers in chemistry (06-04-2021)Get full text
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Spectroscopic and Theoretical Studies of Optically Active Porphyrin Dimers: A System Uninterpretable by Exciton Coupling Theory
Published in Chemphyschem (12-06-2006)“…The electronic excited states of a meso–meso β–β doubly linked bis‐porphyrin are comprehensively investigated by measuring its circular dichroism (CD) and…”
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