Lewis Basic Selenium Catalyzed Chloroamidation of Olefins Using Nitriles as the Nucleophiles

Lewis Basic Selenium Catalyzed Chloroamidation of Olefins Using Nitriles as the Nucleophiles

A Lewis base catalyzed chloroamidation of olefinic substrates was achieved using diphenyl selenide as the catalyst. The reaction conditions are mild and suitable for a wide range of substrates including those which are acid labile.

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Bibliographic Details
Published in:Organic letters Vol. 15; no. 6; pp. 1310 - 1313
Main Authors: Tay, Daniel Weiliang, Tsoi, Ivan Tan, Er, Jun Cheng, Leung, Gulice Yiu Chung, Yeung, Ying-Yeung
Format: Journal Article
Language:English
Published: United States American Chemical Society 15-03-2013
Online Access:Get full text
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Description
Summary:A Lewis base catalyzed chloroamidation of olefinic substrates was achieved using diphenyl selenide as the catalyst. The reaction conditions are mild and suitable for a wide range of substrates including those which are acid labile.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol400249x