Search Results - "Tropiano, Manuel"

A lanthanide based sensor for the time-gated detection of hydrogen sulfide by Tropiano, Manuel, Faulkner, Stephen

“…A kinetically stable Eu(III) complex for the detection of sulfide in water is reported. The probe shows excellent selectivity and fast reaction time. Its…”
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Reversible Luminescence Switching of a Redox-Active Ferrocene–Europium Dyad by Tropiano, Manuel, Kilah, Nathan L, Morten, Michael, Rahman, Habibur, Davis, Jason J, Beer, Paul D, Faulkner, Stephen

“…The copper-catalyzed cycloaddition reaction between a propargyl-appended europium complex and azidomethylferrocene yields a d–f dyad whose photophysical…”
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Kinetically Stable Lanthanide Complexes Displaying Exceptionally High Quantum Yields upon Long-Wavelength Excitation: Synthesis, Photophysical Properties, and Solution Speciation by Routledge, Jack D, Jones, Michael W, Faulkner, Stephen, Tropiano, Manuel

“…We demonstrate how highly emissive, kinetically stable complexes can be prepared using the macrocyclic scaffold of DO3A bearing coordinating aryl ketones as…”
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Ratiometric oxygen sensing using lanthanide luminescent emitting interfaces by Lehr, Joshua, Tropiano, Manuel, Beer, Paul D, Faulkner, Stephen, Davis, Jason J

“…Herein we describe the first example of a ratiometric lanthanide luminescent oxygen sensing interface. Immobilisation of terbium and europium cyclen complexes…”
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Thermodynamics of Core Metal Replacement and Self-Assembly of Ca2+ 15-Metallacrown-5 by Tegoni, Matteo, Furlotti, Michele, Tropiano, Manuel, Lim, Choong Sun, Pecoraro, Vincent L

“…The equilibria for core Ca2+ replacement by Ln3+ in copper(II) 15-MC-5 complexes have been investigated using a series of visible spectrophotometric titrations…”
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Reversible Recruitment and Emission of DO3A-Derived Lanthanide Complexes at Ligating Molecular Films on Gold by Lehr, Joshua, Bennett, Jamie, Tropiano, Manuel, Sørensen, Thomas J, Faulkner, Stephen, Beer, Paul D, Davis, Jason J

“…The recruitment of DO3A-derived lanthanide complexes by ligation to isophthalic acid and catechol-modified gold surfaces, and their resulting sensitization, is…”
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Manipulating the Charge Transfer Absorption for Narrowband Light Detection in the Near-Infrared by Kaiser, Christina, Schellhammer, Karl Sebastian, Benduhn, Johannes, Siegmund, Bernhard, Tropiano, Manuel, Kublitski, Jonas, Spoltore, Donato, Panhans, Michel, Zeika, Olaf, Ortmann, Frank, Meredith, Paul, Armin, Ardalan, Vandewal, Koen

“…Charge generation and recombination processes at interfaces between electron donating (donor, D) and accepting molecules (acceptor, A) are mediated by…”
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Lanthanide Complexes of Azidophenacyl-DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays by Tropiano, Manuel, Kenwright, Alan M., Faulkner, Stephen

“…Lanthanide complexes of azidophenacyl DO3A are effective substrates for click reactions with ethyne derivatives, giving rise to aryl triazole appended…”
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Intrinsic non-radiative voltage losses in fullerene-based organic solar cells by Benduhn, Johannes, Tvingstedt, Kristofer, Piersimoni, Fortunato, Ullbrich, Sascha, Fan, Yeli, Tropiano, Manuel, McGarry, Kathryn A., Zeika, Olaf, Riede, Moritz K., Douglas, Christopher J., Barlow, Stephen, Marder, Seth R., Neher, Dieter, Spoltore, Donato, Vandewal, Koen

“…Organic solar cells demonstrate external quantum efficiencies and fill factors approaching those of conventional photovoltaic technologies. However, as…”
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Kinetically Inert Lanthanide Complexes as Reporter Groups for Binding of Potassium by 18-crown‑6 by Junker, Anne Kathrine R, Tropiano, Manuel, Faulkner, Stephen, Sørensen, Thomas Just

“…The barcode-like spectrum of lanthanide-centered emission has been used in imaging and to make responsive luminescent reporters. The intensities and the shapes…”
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Spectrally resolved confocal microscopy using lanthanide centred near-IR emission by Liao, Zhiyu, Tropiano, Manuel, Mantulnikovs, Konstantins, Faulkner, Stephen, Vosch, Tom, Sørensen, Thomas Just

“…The narrow, near infrared (NIR) emission from lanthanide ions has attracted great interest, particularly with regard to developing tools for bioimaging, where…”
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Exploring the effect of remote substituents and solution structure on the luminescence of three lanthanide complexes by Tropiano, Manuel, Blackburn, Octavia A., Tilney, James A., Hill, Leila R., Just Sørensen, Thomas, Faulkner, Stephen

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Triheterometallic Lanthanide Complexes Prepared from Kinetically Inert Lanthanide Building Blocks by Sørensen, Thomas Just, Tropiano, Manuel, Kenwright, Alan M., Faulkner, Stephen

“…Three molecular structures, each containing three different lanthanide(III) centres, have been prepared by coupling three kinetically inert lanthanide(III)…”
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Lanthanide Complexes that Respond to Changes in Cyanide Concentration in Water by Routledge, Jack D., Zhang, Xuejian, Connolly, Michael, Tropiano, Manuel, Blackburn, Octavia A., Kenwright, Alan M., Beer, Paul D., Aldridge, Simon, Faulkner, Stephen

“…Cyanide ions are shown to interact with lanthanide complexes of phenacylDO3A derivatives in aqueous solution, giving rise to changes in the luminescence and…”
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Front Cover: Triheterometallic Lanthanide Complexes Prepared from Kinetically Inert Lanthanide Building Blocks (Eur. J. Inorg. Chem. 15/2017) by Sørensen, Thomas Just, Tropiano, Manuel, Kenwright, Alan M., Faulkner, Stephen

“…The cover picture shows the antenna effect, in which a chromophore excited state can sensitize the lanthanide‐centered emission by energy transfer via a Dexter…”
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Preparation and study of an f,f,f',f'' covalently linked tetranuclear hetero-trimetallic complex - a europium, terbium, dysprosium triad by Sørensen, Thomas Just, Tropiano, Manuel, Blackburn, Octavia A, Tilney, James A, Kenwright, Alan M, Faulkner, Stephen

“…A heterotrimetallic tetranuclear lanthanide complex containing two dysprosium ions, a terbium ion and a europium ion has been prepared by coupling three…”
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Synthesis and Spectroscopic Study of d–f Hybrid Lanthanide Complexes Derived from triazolylDO3A by Tropiano, Manuel, Record, Christopher J, Morris, Eleanor, Rai, Hardeep S, Allain, Clémence, Faulkner, Stephen

“…Lanthanide complexes of triazolylDO3A have been used to prepare bimetallic d–f hybrid complexes in which the triazolyl pendant arm coordinates to both the…”
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Thermodynamics of core metal replacement and self-assembly of Ca(2+) 15-metallacrown-5 by Tegoni, Matteo, Furlotti, Michele, Tropiano, Manuel, Lim, Choong Sun, Pecoraro, Vincent L

“…The equilibria for core Ca(2+) replacement by Ln(3+) in copper(II) 15-MC-5 complexes have been investigated using a series of visible spectrophotometric…”
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Direct two-photon excitation of Sm3+, Eu3+, Tb3+, Tb.DOTA−, and Tb.propargylDO3A in solution by Sørensen, Thomas Just, Blackburn, Octavia A., Tropiano, Manuel, Faulkner, Stephen

“…[Display omitted] ► Emission is observed following two-photon excitation of Sm(III), Eu(III) and Tb(III). ► Two-photon excitation spectra reported for Eu(III)…”
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Using Remote Substituents to Control Solution Structure and Anion Binding in Lanthanide Complexes by Tropiano, Manuel, Blackburn, Octavia A., Tilney, James A., Hill, Leila R., Placidi, Matteo P., Aarons, Rebecca J., Sykes, Daniel, Jones, Michael W., Kenwright, Alan M., Snaith, John S., Sørensen, Thomas Just, Faulkner, Stephen

“…A study of the anion‐binding properties of three structurally related lanthanide complexes, which all contain chemically identical anion‐binding motifs, has…”
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