Search Results - "Trapp, Nils"

Halogen Bonding Molecular Capsules by Dumele, Oliver, Trapp, Nils, Diederich, François

“…Molecular capsules based solely on the interaction of halogen bonding (XB) are presented along with their host–guest binding properties in solution. The first…”
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A Crystal Structure of an Oligoproline PPII-Helix, at Last by Wilhelm, Patrick, Lewandowski, Bartosz, Trapp, Nils, Wennemers, Helma

“…The first crystal structure of an oligoproline adopting an all-trans polyproline II (PPII) helix is presented. The high-resolution structure provides detailed…”
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Supramolecular Capsules: Strong versus Weak Chalcogen Bonding by Riwar, Leslie‐Joana, Trapp, Nils, Root, Katharina, Zenobi, Renato, Diederich, François

“…Resorcin[4]arene cavitands containing either 2,1,3‐benzotelluradiazole or 2,1,3‐benzothiadiazole motifs were dimerized to supramolecular capsules by chalcogen…”
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Chalcogen Bonding “2S–2N Squares” versus Competing Interactions: Exploring the Recognition Properties of Sulfur by Ams, Mark R., Trapp, Nils, Schwab, Anatol, Milić, Jovana V., Diederich, François

“…Chalcogen bonding (CB) is the focus of increased attention for its applications in medicinal chemistry, materials science, and crystal engineering. However,…”
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Alleno-Acetylenic Cage (AAC) Receptors: Chiroptical Switching and Enantioselective Complexation of trans-1,2-Dimethylcyclohexane in a Diaxial Conformation by Gropp, Cornelius, Trapp, Nils, Diederich, François

“…Four enantiopure 1,3‐diethynylallenes (DEAs) with OH termini were attached to the rim of a resorcin[4]arene cavitand. The system undergoes conformational…”
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Halogen‐Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase by Dumele, Oliver, Schreib, Benedikt, Warzok, Ulrike, Trapp, Nils, Schalley, Christoph A., Diederich, François

“…Supramolecular capsules were assembled by neutral halogen bonding (XB) and studied in the solid state, in solution, and in the gas phase. The geometry of the…”
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Iterative Assembly of Polycyclic Saturated Heterocycles from Monomeric Building Blocks by Saito, Fumito, Trapp, Nils, Bode, Jeffrey W

“…Polycyclic saturated heterocycles with predictable shapes and structures are assembled by iterative couplings of bifunctional stannyl amine protocol (SnAP)…”
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Helicene Quinones: Redox-Triggered Chiroptical Switching and Chiral Recognition of the Semiquinone Radical Anion Lithium Salt by Electron Nuclear Double Resonance Spectroscopy by Schweinfurth, David, Zalibera, Michal, Kathan, Michael, Shen, Chengshuo, Mazzolini, Marcella, Trapp, Nils, Crassous, Jeanne, Gescheidt, Georg, Diederich, François

“…We present the synthesis and characterization of enantiomerically pure [6]­helicene o-quinones (P)-(+)-1 and (M)-(−)-1 and their application to chiroptical…”
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Studies towards the Total Synthesis of Amycolamicin: A Chiral Auxiliary‐Based Diels‐Alder Approach towards the Decalin Core by Frossard, Thomas M., Trapp, Nils, Altmann, Karl‐Heinz

“…The stereoselective synthesis of (1S,2S,5R)‐5‐((4‐methoxybenzyl)oxy)‐2‐methyl‐8‐methylene‐1,2,4a,5,6,7,8,8a‐octahy‐dronaphthalene‐1‐carboxylic acid (2) is…”
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Skeletal metalation of lactams through a carbonyl-to-nickel-exchange logic by Zhong, Hongyu, Egger, Dominic T., Gasser, Valentina C. M., Finkelstein, Patrick, Keim, Loris, Seidel, Merlin Z., Trapp, Nils, Morandi, Bill

“…Classical metalation reactions such as the metal-halogen exchange have had a transformative impact on organic synthesis owing to their broad applicability in…”
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Homochiral [2]Catenane and Bis[2]catenane from Alleno-Acetylenic Helicates - A Highly Selective Narcissistic Self-Sorting Process by Gidron, Ori, Jirásek, Michael, Trapp, Nils, Ebert, Marc-Olivier, Zhang, Xiangyang, Diederich, François

“…Homochiral strands of alternating alleno-acetylenes and phenanthroline ligands (P)-1 and (P 2)-2, as well as their corresponding enantiomers, selectively…”
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Dispersion and Halogen-Bonding Interactions: Binding of the Axial Conformers of Monohalo- and (±)-trans-1,2-Dihalocyclohexanes in Enantiopure Alleno-Acetylenic Cages by Gropp, Cornelius, Husch, Tamara, Trapp, Nils, Reiher, Markus, Diederich, François

“…Enantiopure alleno-acetylenic cage (AAC) receptors with a resorcin[4]­arene scaffold, from which four homochiral alleno-acetylenes converge to shape a cavity…”
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Chiroptical Detection of Nonchromophoric, Achiral Guests by Enantiopure Alleno-Acetylenic Helicages by Gidron, Ori, Ebert, Marc-Olivier, Trapp, Nils, Diederich, François

“…Enantiopure alleno‐acetylenic ligands assemble diastereoselectively upon the addition of a zinc(II) salt to form triple‐stranded helicates, which provide a…”
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Single‐Crystal‐to‐Single‐Crystal (SCSC) Linear Polymerization of a Desymmetrized Anthraphane by Servalli, Marco, Trapp, Nils, Schlüter, A. Dieter

“…In this work we present one of the rare cases of single‐crystal‐to‐single‐crystal (SCSC) linear polymerizations, resulting in a novel ladder‐type polymer. The…”
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Molecular Recognition and Cocrystallization of Methylated and Halogenated Fragments of Danicalipin A by Enantiopure Alleno-Acetylenic Cage Receptors by Gropp, Cornelius, Fischer, Stefan, Husch, Tamara, Trapp, Nils, Carreira, Erick M, Diederich, François

“…Enantiopure (P)4- and (M)4-configured alleno-acetylenic cage (AAC) receptors offer a highly defined interior for the complexation and structure elucidation of…”
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Structures and Properties of Molecular Torsion Balances to Decipher the Nature of Substituent Effects on the Aromatic Edge-to-Face Interaction by Gardarsson, Haraldur, Schweizer, W. Bernd, Trapp, Nils, Diederich, François

“…Various recent computational studies initiated this systematic re‐investigation of substituent effects on aromatic edge‐to‐face interactions. Five series of…”
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Complexation and Structure Elucidation of the Axial Conformers of Mono- and (±)-trans-1,2-Disubstituted Cyclohexanes by Enantiopure Alleno-Acetylenic Cage Receptors by Cornelius Gropp, Nils Trapp

“…Single crystal X-ray diffraction is a powerful method to unambiguously characterize the structure of molecules with atomic resolution. Herein, we review the…”
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Weak Arene Stabilization of Bulky Amido-Germanium(II) and Tin(II) Monocations by Li, Jiaye, Schenk, Christian, Winter, Florian, Scherer, Harald, Trapp, Nils, Higelin, Alexander, Keller, Sarah, Pöttgen, Rainer, Krossing, Ingo, Jones, Cameron

“…Guilty as charged: Germanium(II) and tin(II) monocations which are stabilized by an extremely bulky amido ligand and a very weakly coordinating anion are…”
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Site-Selectivity of Prato Additions to C70: Experimental and Theoretical Studies of a New Thermodynamic Product at the dd-[5,6]-Junction by Liosi, Korinne, Romero-Rivera, Adrian, Semivrazhskaya, Olesya, Caniglia, Caravaggio D, Garcia-Borràs, Marc, Trapp, Nils, Osuna, Sílvia, Yamakoshi, Yoko

“…Three Prato monoadduct isomers were synthesized and structurally characterized by 1H, 13C NMR spectra and single-crystal X-ray diffraction, and one adduct on…”
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Substituent Effects on Singlet Exciton Fission in Polycrystalline Thin Films of Cyano-Substituted Diaryltetracenes by Margulies, Eric A, Kerisit, Nicolas, Gawel, Przemyslaw, Mauck, Catherine M, Ma, Lin, Miller, Claire E, Young, Ryan M, Trapp, Nils, Wu, Yi-Lin, Diederich, François, Wasielewski, Michael R

“…Cyano-substituted tetracenes (5,11-dicyano-6,12-diphenyltetracene, Tet) undergo exoergic singlet fission (SF), a spin-allowed photophysical process that…”
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