Selective fluorination of dichloromethane by highest oxidation state transition-metal oxide fluorides

In contrast to the reactivity of high oxidation state binary transition-metal fluorides with organic solvents, many transition-metal oxide fluorides do not react with CH 2Cl 2. Only the highest oxidation state species react, at temperatures below room temperature, via Cl-F exchange with > 90% sel...

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Bibliographic Details

Published in:	Journal of fluorine chemistry Vol. 76; no. 1; pp. 105 - 107
Main Authors:	Holloway, John H., Hope, Eric G., Townson, Paul J., Powell, Richard L.
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 1996
Subjects:	Dichloromethane ESR spectroscopy Selective fluorination Transition-metal oxide fluorides Dichloromethane Transition-metal oxide fluorides ESR spectroscopy Selective fluorination
Online Access:	Get full text
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