Search Results - "Tong, Ming‐Liang"
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Single Ion Magnets from 3d to 5f: Developments and Strategies
Published in Chemistry : a European journal (28-05-2018)“…Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence of the magnetic field, originate from their single spin‐carrier centre. In…”
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Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Published in Science (American Association for the Advancement of Science) (21-12-2018)“…Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials…”
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A Dysprosium Metallocene Single‐Molecule Magnet Functioning at the Axial Limit
Published in Angewandte Chemie International Edition (11-09-2017)“…ion of a chloride ligand from the dysprosium metallocene [(Cpttt)2DyCl] (1Dy Cpttt=1,2,4‐tri(tert‐butyl)cyclopentadienide) by the triethylsilylium cation…”
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Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet
Published in Angewandte Chemie International Edition (24-04-2017)“…An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide…”
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Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies
Published in Coordination chemistry reviews (01-01-2019)“…[Display omitted] •Briefly state the design strategies for luminescent lanthanide single-molecule magnets (SMMs).•Systematically survey the recent advances of…”
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Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants
Published in Coordination chemistry reviews (01-12-2014)“…•The cryogenic magnetocaloric effect in different magnetic systems is discussed.•The assembly strategies toward 3d-, 4f- and 3d–4f based molecular magnetic…”
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Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
Published in Coordination chemistry reviews (15-03-2017)“…[Display omitted] •Systematic summary of guest effects in spin-crossover Hofmann clathrates.•Molecular volume calculated by a convenient formula is applied to…”
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Isolation of a Perfectly Linear Uranium(II) Metallocene
Published in Angewandte Chemie International Edition (03-02-2020)“…Reduction of the uranium(III) metallocene [(η5‐C5iPr5)2UI] (1) with potassium graphite produces the “second‐generation” uranocene [(η5‐C5iPr5)2U] (2), which…”
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Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets
Published in Journal of the American Chemical Society (02-03-2016)“…Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states separated by an energy barrier are among the most promising…”
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Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown
Published in Angewandte Chemie International Edition (01-03-2021)“…Combining Ising‐type magnetic anisotropy with collinear magnetic interactions in single‐molecule magnets (SMMs) is a significant synthetic challenge. Herein we…”
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Dynamic Magnetic Properties of Germole‐ligated Lanthanide Sandwich Complexes
Published in Chemistry : a European journal (03-07-2023)“…The first germole‐ligated single‐molecule magnets are reported, with contrasting properties found for the near‐linear sandwich complexes [(η8‐COT)Ln(η5‐CpGe]−,…”
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Guest‐Driven Light‐Induced Spin Change in an Azobenzene Loaded Metal–Organic Framework
Published in Angewandte Chemie International Edition (20-12-2021)“…Stimuli‐responsive materials that can be reversibly switched by light are of immense interest. Among them, photo‐responsive spin crossover (SCO) complexes have…”
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Guest‐Switchable Multi‐Step Spin Transitions in an Amine‐Functionalized Metal–Organic Framework
Published in Angewandte Chemie International Edition (20-11-2017)“…Materials with hysteretic multi‐step spin‐crossover (SCO) have potential application in high‐order data storage. Here, an unprecedented hysteretic four‐step…”
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The coordination chemistry of cyclohexanepolycarboxylate ligands. Structures, conformation and functions
Published in Coordination chemistry reviews (01-02-2011)“…▶ This review gives an overview on the coordination chemistry of eight cyclohexanepolycarboxylic acids and explores their possible applications in materials…”
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Uranocenium: Synthesis, Structure, and Chemical Bonding
Published in Angewandte Chemie International Edition (22-07-2019)“…ion of iodide from [(η5‐C5iPr5)2UI] (1) produced the cationic uranium(III) metallocene [(η5‐C5iPr5)2U]+ (2) as a salt of [B(C6F5)4]−. The structure of 2…”
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Distinct Molecular Motions in a Switchable Chromophore Dielectric 4-N,N-Dimethylamino-4′-N′-methylstilbazolium Trifluoromethanesulfonate
Published in Advanced functional materials (05-12-2012)“…Molecular motion associated with rotational and orientational phase transitions is one of the prominent structural strategies for assembling the functional…”
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The Effect of an Active Guest on the Spin Crossover Phenomenon
Published in Angewandte Chemie International Edition (21-01-2013)“…Throw the switch: A new strategy for regulating spin crossover (SCO) properties by the control of an active guest molecule is proposed. As a proof of concept,…”
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Magnetization Dynamics on Isotope‐Isomorphic Holmium Single‐Molecule Magnets
Published in Angewandte Chemie International Edition (20-12-2021)“…Here we reported the deuteration of the metal‐binding equatorial water molecules in a reported HoIII single‐molecule magnet (SMM) with pentagonal‐bipyramidal…”
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Single‐Crystal Transformation Engineering the Spin Change of Metal–Organic Frameworks via Cluster Deconstruction
Published in Angewandte Chemie International Edition (13-11-2023)“…Spin crossover (SCO) materials with new architectures will expand and enrich the research in the SCO field. Here, we report two metal–organic frameworks (MOFs)…”
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A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behavior
Published in Inorganic chemistry (06-08-2012)“…The field-induced blockage of magnetization behavior was first observed in an YbIII-based molecule with a trigonally distorted octahedral coordination…”
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