Search Results - "Tomson, C."
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Mimicking the Constrained Geometry of a Nitrogen-Fixation Intermediate
Published in Journal of the American Chemical Society (06-05-2020)“…Both biological and industrial nitrogen reduction catalysts activate N2 at multinuclear binding sites with constrained Fe–Fe distances. This contrasts with…”
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Palladium-Catalyzed Enantioselective Arylation of Aryl Sulfenate Anions: A Combined Experimental and Computational Study
Published in Journal of the American Chemical Society (21-06-2017)“…A novel approach to produce chiral diaryl sulfoxides from aryl benzyl sulfoxides and aryl bromides via an enantioselective arylation of aryl sulfenate anions…”
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Ring‐Size‐Modulated Reactivity of Putative Dicobalt‐Bridging Nitrides: C−H Activation versus Phosphinimide Formation
Published in Angewandte Chemie International Edition (11-12-2017)“…Dicobalt complexes supported by flexible macrocyclic ligands were used to target the generation of the bridging nitrido species [(nPDI2)Co2(μ‐N)(PMe3)2]3+…”
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Tuning Metal–Metal Interactions through Reversible Ligand Folding in a Series of Dinuclear Iron Complexes
Published in Inorganic chemistry (16-09-2019)“…A dinucleating macrocyclic ligand with two redox-active, pyridyldiimine components was shown to undergo reversible ligand folding to accommodate various…”
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N−H Bond Formation at a Diiron Bridging Nitride
Published in Angewandte Chemie International Edition (24-08-2020)“…Despite their connection to ammonia synthesis, little is known about the ability of iron‐bound, bridging nitrides to form N−H bonds. Herein we report a linear…”
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New guideline for perioperative management of people with inherited salt-wasting alkaloses
Published in British journal of anaesthesia : BJA (01-06-2016)Get full text
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Metallophilic and Inter‐Ligand Interactions in Diargentous Compounds Bound by a Geometrically Flexible Macrocycle
Published in European journal of inorganic chemistry (25-09-2023)“…Abstract A series of mono‐ and di‐nuclear Ag I complexes supported by a flexible macrocyclic ligand are reported. The geometric flexibility of the ligand was…”
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A method of identifying and correcting miscoding, misclassification and misdiagnosis in diabetes: a pilot and validation study of routinely collected data
Published in Diabetic medicine (01-02-2010)“…Diabet. Med. 27, 203–209 (2010) Aims Incorrect classification, diagnosis and coding of the type of diabetes may have implications for patient management and…”
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Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)niobium(III) Imido Complexes
Published in Organometallics (08-11-2010)“…We have investigated both the chemical reduction of (BDI)NbV imido complexes (BDI = HC[C(Me)NAr]2; Ar = 2,6- i Pr2-C6H3) to the formal Nb(III) oxidation state…”
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Variation between centres in access to renal transplantation in UK: longitudinal cohort study
Published in BMJ (20-07-2010)“…Objective To assess whether equity exists in access to renal transplantation in the UK after adjustment for case mix in incident patients with end stage renal…”
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Redox Noninnocence of Nitrosoarene Ligands in Transition Metal Complexes
Published in Inorganic chemistry (20-06-2011)“…Studies on the coordination of nitrosoarene (ArNO) ligands to late-transition metals are used to provide the first definition of the geometric, spectroscopic,…”
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Influence of Metal Identity and Complex Nuclearity in Kumada Cross-Coupling Polymerizations with a Pyridine Diimine-Based Ligand Scaffold
Published in ACS polymers Au (13-12-2023)“…Cross-coupling polymerizations have fundamentally changed the field of conjugated polymers (CPs) by expanding the scope of accessible materials. Despite the…”
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Anion Capture at the Open Core of a Geometrically Flexible Dicopper(II,II) Macrocycle Complex
Published in Inorganics (01-09-2023)“…Multicopper active sites for small molecule activation in materials and enzymatic systems rely on controlled but adaptable coordination spheres about copper…”
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Central pulse pressure in patients with chronic kidney disease and in renal transplant recipients
Published in Journal of human hypertension (01-03-2014)“…Patients with chronic kidney disease (CKD) and renal transplant recipients (RTR) have increased cardiovascular risk. The value of measuring central pulse…”
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Tuning metal-metal interactions for cooperative small molecule activation
Published in Chemical communications (Cambridge, England) (21-03-2021)“…Cluster complexes have attracted interest for decades due to their promise of drawing analogies to metallic surfaces and metalloenzyme active sites, but only…”
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The Actinium Aqua Ion: A Century in the Making
Published in ACS central science (22-03-2017)“…The 225Ac nucleus may hold great promise for radiotherapeutics…”
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Managing hypertension in patients with chronic kidney disease
Published in British journal of hospital medicine (London, England : 2005) (02-11-2016)“…Hypertension is a common clinical problem in patients with chronic kidney disease. This article should equip the non-specialty doctor with the general…”
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Asymptomatic microscopic or dipstick haematuria in adults: which investigations for which patients? A review of the evidence
Published in BJU international (01-08-2002)Get full text
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Oriented internal electrostatic fields: an emerging design element in coordination chemistry and catalysis
Published in Chemical science (Cambridge) (18-05-2022)“…The power of oriented electrostatic fields (ESFs) to influence chemical bonding and reactivity is a phenomenon of rapidly growing interest. The presence of…”
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