Search Results - "Tommasino, Jean Bernard"
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Hemicryptophane-assisted electron transfer: a structural and electronic study
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2013)“…Three copper(II)@hemicryptophane complexes with various cavity sizes and shapes, Cu(II)@1, Cu(II)@2 and Cu(II)@3, were synthesized and characterized by…”
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Single End-to-End Azidocopper(II) Chain Based on an Electroactive Ligand: A Structural, Electrochemical, Magnetic and Ab Initio Study
Published in European Journal of Inorganic Chemistry (01-11-2009)“…By combining azide and the (Z)‐1,1,1‐trifluoro‐4‐(quinolin‐8‐ylamino)but‐3‐en‐2‐one enaminone ligand, HL, an azido‐bridged copper(II) one dimensional polymer…”
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Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework
Published in Journal of the American Chemical Society (21-12-2016)“…The manganese-nitronyl-nitroxide two-dimensional coordination polymer {[Mn2(NITIm)3]ClO4} n (1) (NITImH =…”
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Multi-biofunctional complexes combining antiseptic copper(II) with antibiotic sulfonamide ligands: Structural, redox and antibacterial study
Published in Polyhedron (14-06-2011)“…Elaboration of five new hybrid inorganic–organic complexes associating antibacterial and antiseptic properties via an original synthetic route. Their…”
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Striking Difference in Antiproliferative Activity of Ruthenium- and Osmium-Nitrosyl Complexes with Azole Heterocycles
Published in Inorganic chemistry (03-06-2013)“…Ruthenium nitrosyl complexes of the general formulas (cation)+[cis-RuCl4(NO)(Hazole)]−, where (cation)+ = (H2ind)+, Hazole = 1H-indazole (Hind) (1c),…”
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Tailoring antibacteria agents: Sulfonamide-based dinuclear and 1D polymer Cu(II) complexes
Published in Polyhedron (23-04-2012)“…Cu(II)–sulfonamide complexes, magnetism and electrochemical studies. Cooperativity for bioactivity? Starting from two bioactive sulfonamide-based ligands (HL1:…”
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Novel copper (II) and zinc (II) complexes with enrofloxacin and oxolinic acid: synthesis, characterization, Hirshfeld surface and DFT/CAM-B3LYPD3BJ studies: NBO, QTAIM and RDG analysis
Published in Journal of molecular structure (15-06-2023)“…•The synthesised complexes were studied experimentally and by molecular modelling.•The combination of the D3BJ term with the functional CAM-B3LYP improved the…”
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Structural stability of DHMAI antibacterial dental composite following in vitro biological aging
Published in Dental materials (01-09-2020)“…•7.5% DHMAI composite showed a reduction in residual functions rate, release of monomers.•7.5% DHMAI composite had preserved structural properties after 3…”
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Effectiveness of the DHMAI monomer in the development of an antibacterial dental composite
Published in Dental materials (01-12-2017)“…•The 7.5 % DHMAI antibacterial composite greatly decreased S. mutans CFU, metabolic activity and biofilm formation.•Adding 7.5 % DHMAI in experimental…”
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Ruthenium-Nitrosyl Complexes with Glycine, l‑Alanine, l‑Valine, l‑Proline, d‑Proline, l‑Serine, l‑Threonine, and l‑Tyrosine: Synthesis, X‑ray Diffraction Structures, Spectroscopic and Electrochemical Properties, and Antiproliferative Activity
Published in Inorganic chemistry (03-03-2014)“…The reactions of [Ru(NO)Cl5]2– with glycine (Gly), l-alanine (l-Ala), l-valine (l-Val), l-proline (l-Pro), d-proline (d-Pro), l-serine (l-Ser), l-threonine…”
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Versatile Chemical Transformations of Benzoxazole Based Ligands on Complexation with 3d-Metal Ions
Published in Inorganic chemistry (20-02-2012)“…Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or…”
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Mechanism Elucidation of the cis–trans Isomerization of an Azole Ruthenium–Nitrosyl Complex and Its Osmium Counterpart
Published in Inorganic chemistry (03-06-2013)“…Synthesis and X-ray diffraction structures of cis and trans isomers of ruthenium and osmium metal complexes of general formulas (nBu4N)[cis-MCl4(NO)(Hind)],…”
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Heteropentanuclear Oxalato-Bridged nd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity
Published in Chemistry : a European journal (21-09-2015)“…A series of heteropentanuclear oxalate‐bridged Ru(NO)‐Ln (4d–4f) metal complexes of the general formula (nBu4N)5[Ln{RuCl3(μ‐ox)(NO)}4], where Ln=Y (2), Gd (3),…”
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Osmium-Nitrosyl Oxalato-Bridged Lanthanide-Centered Pentanuclear Complexes - Synthesis, Crystal Structures and Magnetic Properties
Published in European journal of inorganic chemistry (01-03-2015)“…A series of pentanuclear heterometallic coordination compounds of the general formula (Bu4N)5[Ln{Os(NO)(μ‐ox)Cl3}4(H2O)n] [Ln = Y (for 2) and Dy (for 3′) when…”
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Heteropentanuclear Oxalato‐Bridged n d–4f ( n =4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity
Published in Chemistry : a European journal (21-09-2015)“…Abstract A series of heteropentanuclear oxalate‐bridged Ru(NO)‐Ln (4d–4f) metal complexes of the general formula ( n Bu 4 N) 5 [Ln{RuCl 3 (μ‐ox)(NO)} 4 ],…”
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Heterolytic Splitting of Allylic Alcohols with Palladium(0)−TPPTS in Water. Stabilities of the Allylphosphonium Salt of TPPTS and of the Ionic Complex [Pd(η3-allyl)(TPPTS)2]
Published in Organometallics (08-09-2008)“…The Pd(TPPTS)3 complex (TPPTS is the sodium salt of tris(m-sulfophenyl)phosphine) easily ionizes allyl alcohol in water over a wide range of pH: OH− and TPPTS…”
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Osmium-Nitrosyl Complexes with Glycine, Picolinic Acid, L-Proline and D-Proline: Synthesis, Structures and Antiproliferative Activity
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-07-2013)“…The reactions of [Os(NO)Cl5]2– with glycine (GlyH), picolinic acid (PicoH), L‐proline (L‐ProH) and D‐proline (D‐ProH) afforded four novel complexes of the…”
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Osmium-Nitrosyl Oxalato-Bridged Lanthanide-Centered Pentanuclear Complexes - Synthesis, Crystal Structures and Magnetic Properties
Published 05-04-2019“…European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, 2015 (9), pp.1616-1624 A series of pentanuclear heterometallic coordination compounds of the…”
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