Search Results - "Todorova, Tanya K."

A bioinspired molybdenum–copper molecular catalyst for CO2 electroreduction by Mouchfiq, Ahmed, Todorova, Tanya K, Dey, Subal, Fontecave, Marc, Mougel, Victor

“…Non-noble metal molecular catalysts mediating the electrocatalytic reduction of carbon dioxide are still scarce. This work reports the electrochemical…”
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Controlling Hydrogen Evolution during Photoreduction of CO2 to Formic Acid Using [Rh(R-bpy)(Cp)Cl]+ Catalysts: A Structure–Activity Study by Todorova, Tanya K, Huan, Tran Ngoc, Wang, Xia, Agarwala, Hemlata, Fontecave, Marc

“…The photochemical reduction of CO2 to formic acid catalyzed by a series of [Rh­(4,4′-R-bpy)­(Cp*)­Cl]+ and [Rh­(5,5′-COOH-bpy)­(Cp*)­Cl]+ complexes (Cp* =…”
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A Bioinspired Nickel(bis-dithiolene) Complex as a Homogeneous Catalyst for Carbon Dioxide Electroreduction by Fogeron, Thibault, Todorova, Tanya K, Porcher, Jean-Philippe, Gomez-Mingot, Maria, Chamoreau, Lise-Marie, Mellot-Draznieks, Caroline, Li, Yun, Fontecave, Marc

“…Inspired by the metal active sites of formate dehydrogenase and CO-dehydrogenase, a nickel complex containing a NiS4 motif with two dithiolene ligands…”
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Synthesis, Characterization, and DFT Analysis of Bis-Terpyridyl-Based Molecular Cobalt Complexes by Aroua, Safwan, Todorova, Tanya K, Hommes, Paul, Chamoreau, Lise-Marie, Reissig, Hans-Ulrich, Mougel, Victor, Fontecave, Marc

“…Terpyridine ligands are widely used in chemistry and material sciences owing to their ability to form stable molecular complexes with a large variety of metal…”
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Synthetic and computational assessment of a chiral metal-organic framework catalyst for predictive asymmetric transformation by Canivet, Jérôme, Bernoud, Elise, Bonnefoy, Jonathan, Legrand, Alexandre, Todorova, Tanya K, Quadrelli, Elsje Alessandra, Mellot-Draznieks, Caroline

“…Understanding and controlling molecular recognition mechanisms at a chiral solid interface is a continuously addressed challenge in heterogeneous catalysis…”
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Molecular Level Characterization of the Structure and Interactions in Peptide-Functionalized Metal-Organic Frameworks by Todorova, Tanya K., Rozanska, Xavier, Gervais, Christel, Legrand, Alexandre, Ho, Linh N., Berruyer, Pierrick, Lesage, Anne, Emsley, Lyndon, Farrusseng, David, Canivet, Jérôme, Mellot-Draznieks, Caroline

“…We use density functional theory, newly parameterized molecular dynamics simulations, and last generation 15N dynamic nuclear polarization surface enhanced…”
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cis-[RuII(bpy)₂(H₂O)₂]²⁺ Water-Oxidation Catalyst Revisited by Sala, Xavier, Ertem, Mehmed Z, Vigara, Laura, Todorova, Tanya K, Chen, Weizhong, Rocha, Reginaldo C, Aquilante, Francesco, Cramer, Christopher J, Gagliardi, Laura, Llobet, Antoni

“…The only operating mechanism in the oxidation of water to dioxygen catalyzed by the mononuclear cis‐[RuII(bpy)2(H2O)2]2+ complex when treated with excess CeIV…”
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Synthesis and Properties of a Fifteen-Coordinate Complex: The Thorium Aminodiboranate [Th(H₃BNMe₂BH₃)₄] by Daly, Scott R, Piccoli, Paula M.B, Schultz, Arthur J, Todorova, Tanya K, Gagliardi, Laura, Girolami, Gregory S

“…Playing with a full deck: Single‐crystal X‐ray and neutron diffraction data show that the Th center in the title complex 1 (see structure; Th orange, B beige,…”
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Mechanistic Understanding of CO2 Reduction Reaction (CO2RR) Toward Multicarbon Products by Heterogeneous Copper-Based Catalysts by Todorova, Tanya K, Schreiber, Moritz W, Fontecave, Marc

“…In the recent years, significant progress has been made toward designing active and selective catalysts for electrochemical CO2 reduction, with particular…”
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A multistep single-crystal-to-single-crystal bromodiacetylene dimerization by Hoheisel, Tobias N., Schrettl, Stephen, Marty, Roman, Todorova, Tanya K., Corminboeuf, Clémence, Sienkiewicz, Andrzej, Scopelliti, Rosario, Schweizer, W. Bernd, Frauenrath, Holger

“…Packing constraints and precise placement of functional groups are the reason that organic molecules in the crystalline state often display unusual physical or…”
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Biphasic water splitting by osmocene by Ge, Peiyu, Todorova, Tanya K, Patir, Imren Hatay, Olaya, Astrid J, Vrubel, Heron, Mendez, Manuel, Hu, Xile, Corminboeuf, Clémence, Girault, Hubert H

“…The photochemical reactivity of osmocene in a biphasic water-organic solvent system has been investigated to probe its water splitting properties. The…”
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Electroreduction of CO2 to Formate with Low Overpotential using Cobalt Pyridine Thiolate Complexes by Dey, Subal, Todorova, Tanya K., Fontecave, Marc, Mougel, Victor

“…Electrocatalytic CO2 reduction to value‐added products provides a viable alternative to the use of carbon sources derived from fossil fuels. Carrying out these…”
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Understanding, Controlling and Programming Cooperativity in Self-Assembled Polynuclear Complexes in Solution by Riis-Johannessen, Thomas, Dalla Favera, Natalia, Todorova, Tanya K., Huber, Stefan M., Gagliardi, Laura, Piguet, Claude

“…Deviations from statistical binding, that is cooperativity, in self‐assembled polynuclear complexes partly result from intermetallic interactions ΔEM,M, whose…”
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Volatilities of Actinide and Lanthanide N,N‑Dimethylaminodiboranate Chemical Vapor Deposition Precursors: A DFT Study by Vlaisavljevich, Bess, Miró, Pere, Koballa, Drew, Todorova, Tanya K, Daly, Scott R, Girolami, Gregory S, Cramer, Christopher J, Gagliardi, Laura

“…N,N-Dimethylaminodiboranate complexes with praseodymium, samarium, erbium, and uranium, which are potential chemical vapor deposition precursors for the…”
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The Ligand-Based Quintuple Bond-Shortening Concept and Some of Its Limitations by Noor, Awal, Bauer, Tobias, Todorova, Tanya K., Weber, Birgit, Gagliardi, Laura, Kempe, Rhett

“…Herein, the ligand‐based concept of shortening quintuple bonds and some of its limitations are reported. In dichromium–diguanidinato complexes, the length of…”
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A bioinspired molybdenum-copper molecular catalyst for CO 2 electroreduction by Mouchfiq, Ahmed, Todorova, Tanya K, Dey, Subal, Fontecave, Marc, Mougel, Victor

“…Non-noble metal molecular catalysts mediating the electrocatalytic reduction of carbon dioxide are still scarce. This work reports the electrochemical…”
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Controlling Hydrogen Evolution during Photoreduction of CO 2 to Formic Acid Using [Rh(R-bpy)(Cp)Cl] + Catalysts: A Structure-Activity Study by Todorova, Tanya K, Huan, Tran Ngoc, Wang, Xia, Agarwala, Hemlata, Fontecave, Marc

“…The photochemical reduction of CO to formic acid catalyzed by a series of [Rh(4,4'-R-bpy)(Cp*)Cl] and [Rh(5,5'-COOH-bpy)(Cp*)Cl] complexes (Cp* =…”
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The Ru−Hbpp Water Oxidation Catalyst by Bozoglian, Fernando, Romain, Sophie, Ertem, Mehmed Z, Todorova, Tanya K, Sens, Cristina, Mola, Joaquim, Rodríguez, Montserrat, Romero, Isabel, Benet-Buchholz, Jordi, Fontrodona, Xavier, Cramer, Christopher J, Gagliardi, Laura, Llobet, Antoni

“…A thorough characterization of the Ru−Hbpp (in,in-{[RuII(trpy)(H2O)]2(μ-bpp)}3+ (trpy is 2,2′:6′,2′′-terpyridine, bpp is bis(2-pyridyl)-3,5-pyrazolate)) water…”
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Bioinspired Tungsten Dithiolene Catalysts for Hydrogen Evolution: A Combined Electrochemical, Photochemical, and Computational Study by Gomez-Mingot, Maria, Porcher, Jean-Philippe, Todorova, Tanya K, Fogeron, Thibault, Mellot-Draznieks, Caroline, Li, Yun, Fontecave, Marc

“…Bis­(dithiolene)­tungsten complexes, WVIO2 (L = dithiolene)2 and WIVO (L = dithiolene)2, which mimic the active site of formate dehydrogenases, have been…”
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New Cobalt‐Bisterpyridyl Catalysts for Hydrogen Evolution Reaction by Aroua, Safwan, Todorova, Tanya K., Mougel, Victor, Hommes, Paul, Reissig, Hans‐Ulrich, Fontecave, Marc

“…Preparation of a series of terpyridyl ligands bearing different substituents recently led to the synthesis of new cobalt‐bisterpyridyl complexes spanning over…”
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