Search Results - "Todaro, Louis"
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Cyclic Peptoids
Published in Journal of the American Chemical Society (21-03-2007)“…Foldamers are an intriguing family of biomimetic oligomers that exhibit a propensity to adopt stable secondary structures. N-Substituted glycine oligomers, or…”
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2
E- or Z-Selective synthesis of 4-fluorovinyl-1,2,3-triazoles with fluorinated second-generation Julia-Kocienski reagents
Published in Organic & biomolecular chemistry (07-02-2015)“…A highly modular approach to N-substituted 4-(1-fluorovinyl)triazoles is described. In situ desilylation and Cu-catalyzed ligation reaction of TMS-protected…”
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3
Efficient Microwave-Assisted Synthesis of Amine-Substituted Tetrakis(pentafluorophenyl)porphyrin
Published in Organic letters (26-10-2006)“…We report an efficient and rapid means for the synthesis of tetrakis(pentafluorophenyl)porphyrin (TPPF20) derivatives by microwave irradiation in an…”
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4
On the Two-Component Microwave-Mediated Reaction of Isonitriles with Carboxylic Acids: Regarding Alleged Formimidate Carboxylate Mixed Anhydrides
Published in Journal of the American Chemical Society (08-10-2008)“…Microwave induced two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate…”
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5
Routes to New Hafnium(IV) Tetraaryl Porphyrins and Crystal Structures of Unusual Phosphate-, Sulfate-, and Peroxide-Bridged Dimers
Published in Inorganic chemistry (21-01-2008)“…New routes for the synthesis of mono tetraaryl porphyrinato hafnium(IV) complexes, Hf(IV)Por(L)2, are reported, where the secondary ligands, L, are determined…”
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Synthesis of the AB Subunit of Angelmicin B through a Tandem Alkoxy Radical Fragmentation-Etherification Sequence
Published in Organic letters (03-04-2008)“…The synthesis of the tricyclic enone 2, corresponding to the AB subunit of the novel tyrosine kinase inhibitor angelmicin B, is described. The strategy centers…”
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7
High-Yielding Aqueous 18F-Labeling of Peptides via Al18F Chelation
Published in Bioconjugate chemistry (21-09-2011)“…The coordination chemistry of a new pentadentate bifunctional chelator (BFC), NODA-MPAA 1, containing the 1,4,7-triazacyclononane-1,4-diacetate (NODA) motif…”
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Why Are Silyl Ethers Conformationally Different from Alkyl Ethers? Chair−Chair Conformational Equilibria in Silyloxycyclohexanes and Their Dependence on the Substituents on Silicon. The Wider Roles of Eclipsing, of 1,3-Repulsive Steric Interactions, and of Attractive Steric Interactions
Published in Journal of the American Chemical Society (10-12-2003)“…An NMR study of the diaxial/diequatorial chair equilibrium in a range of silylated derivatives of trans-1,4- and trans-1,2-dihydroxycyclohexane is reported and…”
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9
The Use of Squaric Acid as a Scaffold for Cofacial Phenyl Rings
Published in Organic letters (09-12-2004)“…To examine the possibility of using squaric acid as a scaffold for organizing phenyl rings in a cofacial orientation, we undertook an investigation of the…”
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10
Stereoselective Synthesis of P-Chiral Phosphorus Compounds from N-tert-Butoxycarbonyl Amino Acids
Published in Journal of organic chemistry (15-10-2004)“…Reaction of the N-t-Boc amino acids alanine and valine with PhPCl2 gives the P-chiral trans-1,3,2-oxazaphospholidinones exclusively. Variable-temperature NMR…”
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11
31P Magic Angle Spinning NMR Spectroscopy of Paramagnetic Rare-Earth-Substituted Keggin and Wells−Dawson Solids
Published in Journal of the American Chemical Society (16-01-2008)“…Paramagnetic rare-earth elements have been examined as NMR structural probes in polyoxoanionic solids, which have a variety of applications as luminescent…”
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Influence of the Lanthanide Ion and Solution Conditions on Formation of Lanthanide Wells–Dawson Polyoxotungstates
Published in Journal of cluster science (01-06-2006)“…Lanthanide complexes of polyoxometalates, including the α2-P2W17O6110− ligand, have been pioneered by Michael T. Pope, to whom this paper is dedicated…”
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51V Magic Angle Spinning NMR Spectroscopy of Keggin Anions [PV n W12- n O40](3+n)-: Effect of Countercation and Vanadium Substitution on Fine Structure Constants
Published in Journal of the American Chemical Society (22-09-2004)“…Vanadium environments in Keggin oxopolytungstates were characterized by 51V solid-state MAS NMR spectroscopy. (C4H9)4N+-, K+-, Cs+-, as well as mixed Na+/Cs+-…”
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51V Magic Angle Spinning NMR Spectroscopy of Six-Coordinate Lindqvist Oxoanions: A Sensitive Probe for the Electronic Environment in Vanadium-Containing Polyoxometalates. Counterions Dictate the 51V Fine Structure Constants in Polyoxometalate Solids
Published in Journal of the American Chemical Society (14-05-2003)“…Geometric and electronic environments of vanadium have been addressed by 51V magic angle spinning NMR spectroscopy of six-coordinated polyoxometalate solids…”
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15
2-(2-Piperidyl)- and 2-(2-Pyrrolidyl)chromans as Nicotine Agonists: Synthesis and Preliminary Pharmacological Characterization
Published in Journal of medicinal chemistry (20-12-2001)“…As part of an effort to develop a new class of subtype selective nicotine agonists, we have synthesized and tested a group of 12 hydroxylated 2-(2-piperidyl)-…”
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Synthesis of the dideoxynucleosides "ddC" and "CNT" from glutamic acid, ribonolactone, and pyrimidine bases
Published in Journal of organic chemistry (01-09-1988)Get full text
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Enantioselective synthesis of calcium channel blockers of the diltiazem group
Published in Journal of organic chemistry (01-01-1992)Get full text
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Intramolecular Ring-Opening Of Cyclopropanones by Enolate Anions
Published in Journal of organic chemistry (01-02-1995)Get full text
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Synthesis of an A′B′ Precursor to Angelmicin B: Product Diversification in the Suárez Lactol Fragmentation
Published in European Journal of Organic Chemistry (01-11-2011)“…We describe a synthetic strategy for the angelimicin family of anthraquinoid natural products that involves converting a central highly oxygenated decalin…”
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Atropisomers of 1,4-benzodiazepines. Synthesis and resolution of a diazepam-related 1,4-benzodiazepine
Published in Journal of the American Chemical Society (01-05-1990)Get full text
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