Search Results - "Titanyuk, Igor D"
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Synthesis of α‑Aryldiazophosphonates via a Diazo Transfer Reaction
Published in Journal of organic chemistry (04-03-2022)“…The simple synthetic procedure for preparation of α-aryl-α-diazophosphonates via a diazo transfer reaction is proposed. Benzylphosphonates reacted with tosyl…”
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Tandem Catalytic Carbene Addition/Bicyclization of Enynes. One-Step Synthesis of Fluorinated Bicyclic Amino Esters by Ruthenium Catalysis
Published in Organic letters (18-08-2005)“…The reaction of diazo compounds with enynes, containing a fluorinated amino acid moiety, in the presence of the precatalyst Cp*(Cl)Ru(COD) leads to fluorinated…”
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Trifluoroacetaldehyde N‑Tosylhydrazone as a Precursor of Trifluorodiazoethane in Reactions of Insertion into the Heteroatom–Hydrogen Bond
Published in Organic letters (15-11-2019)“…Trifluorodiazoethane is a widely explored trifluoroethylating reagent, which is suitable for the preparation of a large number of fluorine-containing organic…”
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Synthesis of α-aryl-diazophosphonates via palladium-catalyzed cross-coupling of aryl iodides with diethyl diazomethylphosphonate
Published in Tetrahedron letters (10-12-2014)“…[Display omitted] An efficient procedure for the Pd-catalyzed arylation of diethyl α-diazomethylphosphonate with aryl iodides is described. It can serve as a…”
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Ruthenium-Catalysed Synthesis of Fluorinated Bicyclic Amino Esters through Tandem Carbene Addition/Cyclopropanation of Enynes
Published in Chemistry : a European journal (16-08-2011)“…The reaction of fluorinated 1,6‐ and 1,7‐enynes, containing the moiety N(PG)C(CF3)(CO2R), with diazo compounds in the presence of [RuCl(cod)(Cp*)]…”
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An expedient synthesis of diethyl diazomethylphosphonate
Published in Mendeleev communications (01-05-2011)“…A simple three-step preparation of diethyl diazomethylphosphonate was performed from chloroacetone and triethyl phosphite in total yield 70%…”
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Synthesis of enantiopure cyclic amino acid derivatives via a sequential diastereoselective Petasis reaction/ring closing olefin metathesis process
Published in Tetrahedron: asymmetry (15-02-2017)“…[Display omitted] A novel approach to the synthesis of enantiopure cyclic amino esters is reported. The utilization of allylboronic acid together with…”
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Efficient and stereoselective synthesis of (S)-α-propargylglycine derivatives from allenylboronic acid
Published in Mendeleev communications (01-09-2019)“…[Display omitted] The Petasis–Mannich reaction of allenylboronic acid with glyoxylic acid and (S)-1-phenylethylamine diastereoselectively leads to…”
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Trifluoromethylated cyclopropanes and epoxides from CuI-mediated transformations of α-trifluoromethyl-diazophosphonate
Published in Journal of fluorine chemistry (01-07-2007)“…An efficient method for transformation of diethyl 1-diazo-2,2,2-trifluoroethylphosphonate to α-(trifluoromethyl)-cyclopropylphosphonates and…”
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Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids
Published in Mendeleev communications (2005)“…A new approach to trifluoromethyl-depsipeptides involving the formation of a COO–CH(CF 3)CO link by a metal carbene insertion reaction into the COOH group of…”
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A CONVENIENT METHOD FOR BROMOSULFENYLATION: REACTIONS OF SULFENAMIDES WITH OLEFINS IN THE PRESENCE OF POBr3
Published in Phosphorus, sulfur, and silicon and the related elements (01-01-1999)“…A general method for the one-pot transformation of alkenes into abromoalkyl-arylsulfdes has been proposed based on the sulfenylation reaction by means of…”
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