Search Results - "Tisserand, Steve"

Generation of Nucleophilic Chromium Acetylides from gem-Trichloroalkanes and Chromium Chloride: Synthesis of Propargyl Alcohols by Kashinath, Dhurke, Tisserand, Steve, Puli, Narender, Falck, John R., Baati, Rachid

“…Nucleophilic mixed chromium(II) and chromium(III) acetylides are generated from the smooth reduction of primary 1,1,1‐trichloroalkanes with chromium(II)…”
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A mechanistic study of the chromium(II)-mediated transformations of trichloromethyl alkyls and carbinols: evidence for carbene, carbyne, and carbenoid intermediates by Bejot, Romain, Tisserand, Steve, Li, De Run, Falck, J.R., Mioskowski, Charles

“…Using CrCl 2 in THF at room temperature, trichloromethyl carbinols and trichloromethylalkanes are readily transformed to the highly reactive α-chlorocarbenes,…”
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Stereoselective Transformations of Trihalomethylcarbinols Induced by Chromous Chloride by Bejot, Romain, Tisserand, Steve, Reddy, L. Manmohan, Barma, Deb K., Baati, Rachid, Falck, J. R., Mioskowski, Charles

“…Reduction of trihalomethylcarbinols 1 with CrCl2 affords good to excellent yields of (Z)‐α‐haloenol esters 2 and (Z)‐β‐haloenol ethers 3 through acyl or…”
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Total synthesis of rhein and diacerhein via a directed ortho metalation of an aromatic substrate by Gonnot, Vanessa, Tisserand, Steve, Nicolas, Marc, Baati, Rachid, Mioskowski, Charles

“…Rhein 1 and diacerhein 2 have been successfully synthesized in few steps using a highly selective DOM reaction. An efficient total synthesis of rhein and…”
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Highly Diastereoselective Diels−Alder Reactions of Baylis−Hillman Adducts by Aggarwal, Varinder K, Patin, Amaury, Tisserand, Steve

“…Baylis−Hillman adducts were found to be excellent dienophiles in Diels−Alder reactions, providing essentially complete diastereocontrol (although mixtures of…”
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Expedient Total Syntheses of Rhein and Diacerhein via Fries Rearrangement by Tisserand, Steve, Baati, Rachid, Nicolas, Marc, Mioskowski, Charles

“…Short and practical total syntheses of rhein (1) and diacerhein (2) have been achieved via a Fries rearrangement and bis-carbonylation strategy followed by…”
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Reactivity of γ-chloro- gem-trichloroalkanes with chromous chloride by Tisserand, Steve, Bejot, Romain, Billaud, Célia, Li, De Run, Falck, J.R., Mioskowski, Charles

“…CrCl 2-mediated condensation of γ-chloro- gem-trichloroalkanes with aldehyde generates homoallylic alcohols through a hydride rearrangement followed by a…”
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Stereoselective Transformations of Trihalomethylcarbinols Induced by Chromous Chloride by Bejot, Romain, Tisserand, Steve, Reddy, L. Manmohan, Barma, Deb K., Baati, Rachid, Falck, J. R., Mioskowski, Charles

“…Die Reduktion von Trihalogenmethylcarbinolen 1 mit CrCl2 liefert in guten bis ausgezeichneten Ausbeuten (Z)‐α‐Halogen‐Enolester 2 und (Z)‐β‐Halogen‐Enolether 3…”
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Stereoselective Transformations of Trihalomethylcarbinols Induced by Chromous Chloride by Bejot, Romain, Tisserand, Steve, Reddy, L. Manmohan, Barma, Deb K., Baati, Rachid, Falck, J. R., Mioskowski, Charles

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