Search Results - "Tilset, Mats"

Mechanistic Aspects of C−H Activation by Pt Complexes by Lersch, Martin, Tilset, Mats

“…Insight into the nature of C-H bond activation may have implications for important aspects of the technology that is needed for the proposed and intensely…”
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Synthesis and Stability of Tagged UiO-66 Zr-MOFs by Kandiah, Mathivathani, Nilsen, Merete Hellner, Usseglio, Sandro, Jakobsen, Søren, Olsbye, Unni, Tilset, Mats, Larabi, Cherif, Quadrelli, Elsje Alessandra, Bonino, Francesca, Lillerud, Karl Petter

“…The development in the field MOF materials is moving from the discovery of new structures toward applications of the most promising materials. In most cases,…”
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Oxidative Access via Aqua Regia to an Electrophilic, Mesoionic Dicobaltoceniumyltriazolylidene Gold(III) Catalyst by Vanicek, Stefan, Beerhues, Julia, Bens, Tobias, Levchenko, Volodymyr, Wurst, Klaus, Bildstein, Benno, Tilset, Mats, Sarkar, Biprajit

“…A gold­(III) complex with the hitherto most electron poor mesoionic carbene ligand is presented. Aqua regia was the oxidizing agent of choice for the synthesis…”
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Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition by Glessi, Cristiano, Mahgoub, Aya, Hagen, Cornelis W, Tilset, Mats

“…Seven gold(I) N-heterocyclic carbene (NHC) complexes were synthesized, characterized, and identified as suitable precursors for focused electron beam-induced…”
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Theoretical Investigations on the Chemical Bonding, Electronic Structure, And Optical Properties of the Metal−Organic Framework MOF-5 by Yang, Li-Ming, Vajeeston, Ponniah, Ravindran, Ponniah, Fjellvåg, Helmer, Tilset, Mats

“…The chemical bonding, electronic structure, and optical properties of metal−organic framework-5 (MOF-5) were systematically investigated using ab initio…”
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Versatile Methods for Preparation of New Cyclometalated Gold(III) Complexes by Langseth, Eirin, Görbitz, Carl Henrik, Heyn, Richard H, Tilset, Mats

“…Versatile methods for the high-yield syntheses of new cyclometalated gold(III) complexes are described. Mono- or dialkylated or arylated gold(III) complexes…”
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Generation and Structural Characterization of a Gold(III) Alkene Complex by Langseth, Eirin, Scheuermann, Margaret L., Balcells, David, Kaminsky, Werner, Goldberg, Karen I., Eisenstein, Odile, Heyn, Richard H., Tilset, Mats

“…A Missing Gold Link: An AuIII alkene complex has been prepared and characterized by NMR spectroscopy and X‐ray crystallography. Its bonding features have been…”
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Pure enantiomers of benzoylamino-tranylcypromine: LSD1 inhibition, gene modulation in human leukemia cells and effects on clonogenic potential of murine promyelocytic blasts by Valente, Sergio, Rodriguez, Veronica, Mercurio, Ciro, Vianello, Paola, Saponara, Bruna, Cirilli, Roberto, Ciossani, Giuseppe, Labella, Donatella, Marrocco, Biagina, Monaldi, Daria, Ruoppolo, Giovanni, Tilset, Mats, Botrugno, Oronza A., Dessanti, Paola, Minucci, Saverio, Mattevi, Andrea, Varasi, Mario, Mai, Antonello

“…The pure enantiomers of the N-(2-, 3-, and 4-(2-aminocyclopropyl)phenyl)benzamides hydrochlorides 11a–j were prepared and tested against LSD1 and MAO enzymes…”
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Crystal structure of (N^C) cyclometalated AuIII diazide at 100 K by Volodymyr Levchenko, Sigurd Øien-Ødegaard, David Wragg, Mats Tilset

“…The title compound, an (N^C)-cyclometalated gold(III) diazide, namely, diazido[5-ethoxycarbonyl-2-(5-ethoxycarbonylpyridin-2-yl)phenyl-κ2C1,N]gold(III),…”
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On the Mechanism of Cyclopropanation Reactions Catalyzed by a Rhodium(I) Catalyst Bearing a Chelating Imine-Functionalized NHC Ligand: A Computational Study by Rosenberg, Marianne L., Krapp, Andreas, Tilset, Mats

“…A computational study at the DFT level using BP86 and dispersion-corrected D-BP86 methods has been performed on the mechanism of a highly…”
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A rapid synthesis of asymmetric alkyl- and aryl-2,9-disubstitued 1,10-phenanthrolines by Jakobsen, Søren, Tilset, Mats

“…The finding that alkyl- and aryllithium reagents add almost instantly to the N–C2/C9 bond of 1,10-phenanthrolines led us to the development of a reaction…”
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Crystal structure of catena-poly[[[aquabis(dimethylformamide-κO)magnesium(II)]-μ3-(2,2′-bipyridine-5,5′-dicarboxylato-κ5O2:O2′:N,N′:O5)-[dichloridoplatinum(II)]] dimethylformamide monosolvate] by Fredrik Lundvall, Mats Tilset

“…The title compound, {[MgPtCl2(C12H6N2O4)(C3H7NO)2(H2O)]·C3H7NO}n, is a one-dimensional coordination polymer. The structure consists of Pt-functionalized…”
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Highly cis-Selective Rh(I)-Catalyzed Cyclopropanation Reactions by Rosenberg, Marianne Lenes, Vlašaná, Klára, Gupta, Nalinava Sen, Wragg, David, Tilset, Mats

“…The performance of recently reported highly cis-diastereoselective Rh(I) cyclopropanation catalysts has been significantly improved by a systematic study of…”
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Mechanistic Investigation of Benzene C−H Activation at a Cationic Platinum(II) Center:  Direct Observation of a Platinum(II) Benzene Adduct by Johansson, Lars, Tilset, Mats, Labinger, Jay A, Bercaw, John E

“…The platinum(II) methyl cation [(N−N)Pt(CH3)(solv)]+BF4 - (N−N = ArNC(Me)C(Me)NAr, Ar = 2,6-(CH3)2C6H3, solv = H2O (2a) or TFE = CF3CH2OH (2b)) is prepared…”
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Adding a New Dimension to the Investigation of Platinum-Mediated Arene C−H Activation Reactions Using 2D NMR Exchange Spectroscopy. Dynamics of Pt(II) Phenyl/Benzene Site Exchange by Wik, Bror Johan, Lersch, Martin, Krivokapic, Alexander, Tilset, Mats

“…Protonation of (N−N)PtPh2 (1; N−N = diimine ArNCMe−CMeNAr with Ar = 2,6-Me2C6H3 (a), 2,4,6-Me3C6H2 (b), 4-Br-2,6-Me2C6H2 (c), 3,5-Me2C6H3 (d), and 4-CF3C6H4…”
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The Metal Is the Kinetic Site of Protonation of (Diimine)Pt Dimethyl Complexes by Wik, Bror Johan, Lersch, Martin, Tilset, Mats

“…Protonolysis of (diimine)PtMe2 (1) complexes in CD2Cl2 containing CD3CN at −78 °C yields (diimine)PtMe2(H)(NCCD3)+ (4), (diimine)PtMe(NCCD3)+ (5), and methane…”
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Tailoring the Dimensionality of Metal–Organic Frameworks Incorporating Pt and Pd. From Molecular Complexes to 3D Networks by Hafizović, Jasmina, Krivokapić, Alexander, Szeto, Kai C, Jakobsen, Søren, Lillerud, Karl Petter, Olsbye, Unni, Tilset, Mats

“…Metal–organic frameworks (MOFs) incorporating Pt(II) or Pd(II) are formed in one-pot reactions from pyridine-3,5-dicarboxylic acid with Pt(II) or Pd(II) and a…”
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A Combined Experimental and Density Functional Theory Investigation of Hydrocarbon Activation at a Cationic Platinum(II) Diimine Aqua Complex under Mild Conditions in a Hydroxylic Solvent by Heiberg, Hanne, Johansson, Lars, Gropen, Odd, Ryan, Olav B, Swang, Ole, Tilset, Mats

“…Controlled protonolysis of (Nf-Nf)Pt(CH3)2 (1; Nf-Nf = ArNCMeCMeNAr, Ar = 3,5-(CF3)2C6H3) with HBF4·Et2O in dichloromethane in the presence of small…”
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Di-μ-chlorido-bis[(2,2′-bipyridine-5,5′-dicarboxylic acid-κ 2 N , N ′)chloridocopper(II)] dimethylformamide tetrasolvate by Øien, Sigurd, Wragg, David Stephen, Lillerud, Karl Petter, Tilset, Mats

“…In the title compound, [Cu 2 Cl 4 (C 12 H 8 N 2 O 4 ) 2 ]·4C 3 H 7 NO, which contains a chloride-bridged centrosymmetric Cu II dimer, the Cu II atom is in a…”
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Synthesis and Characterization of 14-Electron Cyclopentadienyl Chromium(II) Complexes Containing a Heterocyclic Carbene Ligand by Voges, Mark H, Rømming, Christian, Tilset, Mats

“…Chromocene reacts with 1,3-dimesitylimidazolium chloride in THF to yield cyclopentadiene and CpCrCl(1,3-dimesitylimidazolin-2-ylidene) (1), which contains an…”
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