Search Results - "Tilley, T Don"

Electrophilic Activation of Silicon–Hydrogen Bonds in Catalytic Hydrosilations by Lipke, Mark C., Liberman‐Martin, Allegra L., Tilley, T. Don

“…Hydrosilation reactions represent an important class of chemical transformations and there has been considerable recent interest in expanding the scope of…”
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Binding, Release and Functionalization of Intact Pnictogen Tetrahedra Coordinated to Dicopper Complexes by Piesch, Martin, Nicolay, Amélie, Haimerl, Maria, Seidl, Michael, Balázs, Gábor, Don Tilley, T., Scheer, Manfred

“…The bridging MeCN ligand in the dicopper(I) complexes [(DPFN)Cu2(μ,η1 : η1‐MeCN)][X]2 (X=weakly coordinating anion, NTf2 (1 a), FAl[OC6F10(C6F5)]3 (1 b),…”
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Mechanistic Interrogation of Alkyne Hydroarylations Catalyzed by Highly Reduced, Single-Component Cobalt Complexes by Suslick, Benjamin A, Tilley, T. Don

“…Highly reactive catalysts for ortho-hydroarylations of alkynes have previously been reported to result from activation of CoBr2 by Grignard reagents, but the…”
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Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition by Ziegler, Micah S, Lakshmi, K. V, Tilley, T. Don

“…A discrete, dicopper μ-alkynyl complex, [Cu2(μ-η1:η1 -CC­(C6H4)­CH3)­DPFN]­NTf2 (DPFN = 2,7-bis­(fluoro-di­(2-pyridyl)­methyl)-1,8-naphthyridine; NTf2 – =…”
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Identifying the Length Dependence of Orbital Alignment and Contact Coupling in Molecular Heterojunctions by Malen, Jonathan A, Doak, Peter, Baheti, Kanhayalal, Tilley, T. Don, Segalman, Rachel A, Majumdar, Arun

“…Transport in metal−molecule−metal junctions is defined by the alignment and coupling of molecular orbitals with continuum electronic states in the metal…”
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Expanded Helicenes: A General Synthetic Strategy and Remarkable Supramolecular and Solid-State Behavior by Kiel, Gavin R, Patel, Sajan C, Smith, Patrick W, Levine, Daniel S, Tilley, T. Don

“…A divergent synthetic strategy allowed access to several members of a new class of helicenes, the “expanded helicenes”, which are composed of alternating…”
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Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound by Liberman-Martin, Allegra L, Bergman, Robert G, Tilley, T. Don

“…Bis­(perfluorocatecholato)­silane Si­(catF)2 was prepared, and stoichiometric binding to Lewis bases was demonstrated with fluoride, triethylphosphine oxide,…”
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Comparison of Cobalt-based Nanoparticles as Electrocatalysts for Water Oxidation by Chou, Nam Hawn, Ross, Philip N., Bell, Alexis T., Tilley, T. Don

“…Water oxidation electrocatalysts: The controlled synthesis of ε‐Co, CoO, and Co3O4 nanoparticles with nearly identical particle size and shape allows…”
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Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes by Waterman, Rory, Hayes, Paul G, Tilley, T. Don

“…A variety of transition-metal complexes with terminal silylene ligands have become available in recent years, because of the discovery of several preparative…”
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Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes by Calimano, Elisa, Tilley, T. Don

“…Oxidative addition of bulky primary, secondary, and tertiary silanes to PNP (PNP = [N(2-PiPr2-4-Me-C6H3)2]−) iridium complexes (PNP)IrH2 and (PNP)Ir(COE) (11)…”
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Tetracopper σ‐Bound μ ‐Acetylide and ‐Diyne Units Stabilized by a Naphthyridine‐based Dinucleating Ligand by Ríos, Pablo, See, Matthew S., Handford, Rex C., Cooper, Jason K., Don Tilley, T.

“…Abstract Reactions of a dicopper(I) tert ‐butoxide complex with alkynes possessing boryl or silyl capping groups resulted in formation of unprecedented…”
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Efficient and selective alkene hydrosilation promoted by weak, double Si-H activation at an iron center by Smith, Patrick W, Dong, Yuyang, Tilley, T. Don

“…Cationic iron complexes [Cp*( i Pr 2 MeP)FeH 2 SiHR] + , generated and characterized in solution, are very efficient catalysts for the hydrosilation of…”
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Zirconacyclopentadiene‐Annulated Polycyclic Aromatic Hydrocarbons by Kiel, Gavin R., Ziegler, Micah S., Tilley, T. Don

“…Syntheses of large polycyclic aromatic hydrocarbons (PAHs) and graphene nanostructures demand methods that are capable of selectively and efficiently fusing…”
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Regioselective, Transition Metal-Free C–O Coupling Reactions Involving Aryne Intermediates by Dong, Yuyang, Lipschutz, Michael I, Tilley, T. Don

“…A new transition-metal-free synthetic method for C–O coupling between various aryl halides and alkoxides is described. This type of transformation is typically…”
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C–H Activation by RuCo3O4 Oxo Cubanes: Effects of Oxyl Radical Character and Metal–Metal Cooperativity by Amtawong, Jaruwan, Skjelstad, Bastian Bjerkem, Handford, Rex C, Suslick, Benjamin A, Balcells, David, Tilley, T. Don

“…High-valent multimetallic-oxo/oxyl species have been implicated as intermediates in oxidative catalysis involving proton-coupled electron transfer (PCET)…”
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Dinucleating Naphthyridine-Based Ligand for Assembly of Bridged Dicopper(I) Centers: Three-Center Two-Electron Bonding Involving an Acetonitrile Donor by Davenport, Timothy C., Tilley, T. Don

“…Unusual bonding: A ligand system that promotes formation of a rare μ‐η1:η1 acetonitrile‐bridged dicopper(I) complex (see picture) has been developed. The…”
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Elucidation of Diverse Solid‐State Packing in a Family of Electron‐Deficient Expanded Helicenes via Microcrystal Electron Diffraction (MicroED) by Samkian, Adrian E., Kiel, Gavin R., Jones, Christopher G., Bergman, Harrison M., Oktawiec, Julia, Nelson, Hosea M., Tilley, T. Don

“…Solid‐state packing plays a defining role in the properties of a molecular organic material, but it is difficult to elucidate in the absence of single crystals…”
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Shape-Selective Synthesis of Pentacene Macrocycles and the Effect of Geometry on Singlet Fission by Bergman, Harrison M, Kiel, Gavin R, Witzke, Ryan J, Nenon, David P, Schwartzberg, Adam M, Liu, Yi, Tilley, T. Don

“…Pentacene’s extraordinary photophysical and electronic properties are highly dependent on intermolecular through-space interactions. Macrocyclic arrangements…”
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Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6‑ i Pr2‑C6H3)]2} by Lipschutz, Michael I, Tilley, T. Don

“…A convenient method of preparing two- and three-coordinate Ni­(I) complexes of the form L–NiI–X (L = P t Bu3, P i Pr3, DPPE, NHC; X = −N­(SiMe3)­(2,6- i…”
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Selective Synthesis of a Series of Isostructural MIICuI Heterobimetallic Complexes Spontaneously Assembled by an Unsymmetrical Naphthyridine‐Based Ligand by Nicolay, Amélie, Tilley, T. Don

“…Metal–metal cooperation is integral to the function of many enzymes and materials, and model complexes hold enormous potential for providing insights into the…”
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