Search Results - "Tiller, Joerg C"
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Shape memory natural rubber
Published in Journal of polymer science. Part B, Polymer physics (15-07-2016)“…Charles Goodyear discovered the vulcanization of natural rubber (NR) 170 years ago and transferred the gooey natural compound into the first representative of…”
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A Shape-Adaptive, Antibacterial-Coating of Immobilized Quaternary-Ammonium Compounds Tethered on Hyperbranched Polyurea and its Mechanism of Action
Published in Advanced functional materials (01-01-2014)“…Quaternary‐ammonium‐compounds are potent cationic antimicrobials used in everyday consumer products. Surface‐immobilized, quaternary‐ammonium‐compounds create…”
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Shape-Memory Natural Rubber: An Exceptional Material for Strain and Energy Storage
Published in Macromolecular chemistry and physics (25-04-2013)“…Shape‐memory polymers (SMPs) are smart, responsive materials with numerous potential applications. Based on previously introduced shape‐memory natural rubber…”
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Near-Model Amphiphilic Polymer Conetworks Based on Four-Arm Stars of Poly(vinylidene fluoride) and Poly(ethylene glycol): Synthesis and Characterization
Published in Macromolecules (10-04-2018)“…Amphiphilic polymer conetworks (APCN) were prepared in N,N-dimethylformamide (DMF) by the interconnection of four-arm star poly(vinylidene fluoride) (PVDF, M…”
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Multicore Artificial Metalloenzymes Derived from Acylated Proteins as Catalysts for the Enantioselective Dihydroxylation and Epoxidation of Styrene Derivatives
Published in Chemistry : a European journal (25-07-2018)“…Artificial metalloenzymes (AME′s) are an interesting class of selective catalysts, where the chiral environment of proteins is used as chiral ligand for a…”
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Contact-Active Antimicrobial Coatings Derived from Aqueous Suspensions
Published in Angewandte Chemie International Edition (13-10-2006)“…Kills germs on contact! Environmentally friendly aqueous dispersions of polymer nanobeads with a surface‐grafted antimicrobial emulsifier were prepared…”
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Chemical Cross-linking of Polypropylenes Towards New Shape Memory Polymers
Published in Macromolecular rapid communications. (01-04-2015)“…In this work, syndiotactic polypropylene (sPP) as well as isotactic polypropylene (iPP) are cross‐linked to gain a shape memory effect. Both prepared PP…”
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Nontoxic, Hydrophilic Cationic Polymers-Identified as Class of Antimicrobial Polymers
Published in Macromolecular bioscience (01-12-2015)“…Amphiphilic polycations are an alternative to biocides but also toxic to mammalian cells. Antimicrobially active hydrophilic polycations based on…”
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Increasing the Local Concentration of Drugs by Hydrogel Formation
Published in Angewandte Chemie International Edition (14-07-2003)“…Drugs that gel: The first hydrogel‐forming drug, a pyrene‐derivatized form of the antibiotic vancomycin (see structure), exhibits an 11‐fold higher…”
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Entropically driven Polymeric Enzyme Inhibitors by End‐Group directed Conjugation
Published in Chemistry : a European journal (26-03-2018)“…A new generic concept for polymeric enzyme inhibitors is presented using the example of poly(2‐methyl‐2‐oxazoline) (PMOx) terminated with an iminodiacetate…”
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Stress-Induced Melting of Crystals in Natural Rubber: a New Way to Tailor the Transition Temperature of Shape Memory Polymers
Published in Macromolecular rapid communications. (26-09-2012)“…Lightly cross‐linked natural rubber (NR, cis‐1,4‐polyisoprene) was found to be an exceptional cold programmable shape memory polymer (SMP) with strain storage…”
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Urease-induced calcification of segmented polymer hydrogels – A step towards artificial biomineralization
Published in Acta biomaterialia (01-09-2014)“…Natural organic/inorganic composites, such as nacre, bones and teeth, are perfectly designed materials with exceptional mechanical properties. Numerous…”
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Polymer Enzyme Conjugates as Chiral Ligands for Sharpless Dihydroxylation of Alkenes in Organic Solvents
Published in Chembiochem : a European journal of chemical biology (02-01-2015)“…Conjugates of enzymes and poly(2‐methyloxazoline) were used as organosoluble amphiphilic polymer nanocontainers for dissolving osmate, thereby converting the…”
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Amphiphilic Polymer Conetworks Based on End Group Cross-Linked Poly(2-oxazoline) Homo- and Triblock Copolymers
Published in Macromolecules (14-05-2013)“…Novel amphiphilic polymer conetworks (APCNs) were prepared via end group cross-linking. To this end, poly(2-methyloxazoline) (PMOx), poly(2-butyloxazoline)…”
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Synthesis and characterization of chiral and thermo responsive amphiphilic conetworks
Published in Polymer (Guilford) (06-01-2010)“…Amphiphilic polymer conetworks (APCN) combine the properties of different polymers on the nanoscale affording advanced materials with unique properties. Here,…”
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Programming of Shape Memory Natural Rubber for Near-Discrete Shape Transitions
Published in ACS applied materials & interfaces (28-01-2015)“…Typical shape memory polymers are hot-programmed and show a shape transition over a broad temperature range of 10 K and more. Cold-programmed shape memory…”
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Amphiphilic polymer conetworks as chiral separation membranes
Published in Journal of membrane science (15-04-2011)“…[Display omitted] ► Amphiphilic polymer conetworks are a new class of chiral separating membranes. ► The described membranes consist of chiral nanophase and…”
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Amphiphilic Network as Nanoreactor for Enzymes in Organic Solvents
Published in Nano letters (01-01-2005)“…Enzymes are powerful biocatalysts that work naturally in water but are also active in organic solvents. Here, we present a nanophase-separated amphiphilic…”
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Designing Surfaces That Kill Bacteria on Contact
Published in Proceedings of the National Academy of Sciences - PNAS (22-05-2001)“…Poly(4-vinyl-N-alkylpyridinium bromide) was covalently attached to glass slides to create a surface that kills airborne bacteria on contact. The antibacterial…”
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Stress-Induced Stabilization of Crystals in Shape Memory Natural Rubber
Published in Macromolecular rapid communications. (25-01-2013)“…In contrast to all known shape memory polymers, the melting temperature of crystals in shape memory natural rubber (SMNR) can be greatly manipulated by the…”
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