Search Results - "Thybaut, J W"

Experimental investigation of ethylene hydroformylation to propanal on Rh and Co based catalysts by NAVIDI, N, THYBAUT, J. W, MARIN, G. B

“…Intrinsic hydroformylation kinetics have been measured in a high-throughput kinetic test setup at temperatures varying from 448 to 498 K, with the total…”
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Single-Event MicroKinetics: Catalyst design for complex reaction networks by Thybaut, J.W., Marin, G.B.

“…Single-Event MicroKinetic (SEMK) models, originally developed for describing the kinetics in complex mixtures, have become a versatile tool for rational…”
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Unraveling Diffusion and Other Shape Selectivity Effects in ZSM5 Using n‑Hexane Hydroconversion Single-Event Microkinetics by Vandegehuchte, B. D, Thybaut, J. W, Marin, G. B

“…Potentially dominant factors governing the shape selectivity in n-hexane hydroconversion over a Pt/H-ZSM5 catalyst were evaluated by means of single-event…”
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Oxidative coupling of methane: catalytic behaviour assessment via comprehensive microkinetic modelling by Alexiadis, V.I., Thybaut, J.W., Kechagiopoulos, P.N., Chaar, M., Van Veen, A.C., Muhler, M., Marin, G.B.

“…•Comprehensive one-dimensional heterogeneous microkinetic model for methane oxidative coupling.•Active sites density, oxygen, and hydroxyl chemisorption heat…”
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A Single-Event MicroKinetic model for “ethylbenzene dealkylation/xylene isomerization” on Pt/H-ZSM-5 zeolite catalyst by Toch, K., Thybaut, J.W., Vandegehuchte, B.D., Narasimhan, C.S.L., Domokos, L., Marin, G.B.

“…[Display omitted] ► C8 aromatics conversion is adequately modeled using single-event microkinetics. ► Combined entropic and energetic effects determine the…”
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A Single-Event MicroKinetic assessment of n-alkane hydroconversion on ultrastable Y zeolites after Atomic Layer Deposition of alumina by Vandegehuchte, B.D., Thybaut, J.W., Detavernier, C., Deduytsche, D., Dendooven, J., Martens, J.A., Sree, S.P., Korányi, T.I., Marin, G.B.

“…Single-Event MicroKinetic (SEMK) model regression analysis provided considerably more insight in the effect of Atomic Layer Deposition (ALD) of alumina on the…”
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A single-event microkinetic analysis of the catalytic cracking of (cyclo)alkanes on an equilibrium catalyst in the absence of coke formation by Quintana-Solórzano, R., Thybaut, J.W., Marin, G.B.

“…Single-event microkinetics (SEMK) are applied to model the catalytic cracking of (cyclo)alkanes on an equilibrium catalyst in the absence of coke formation…”
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Pore mouth versus intracrystalline adsorption of isoalkanes on ZSM-22 and ZSM-23 zeolites under vapour and liquid phase conditions by Denayer, J F, Ocakoglu, A R, Huybrechts, W, Martens, J A, Thybaut, J W, Marin, G B, Baron, G V

“…Methylbranched C5-C9 alkanes do not adsorb in the intracrystalline void space of ZSM-23, neither from the vapour nor the liquid phase, but are adsorbed in…”
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Assessment of dominant factors affecting liquid phase hydroisomerization on bifunctional zeolites by Fúnez, A., Thybaut, J.W., Marin, G.B., Sánchez, P., De Lucas, A., Valverde, J.L.

“…Liquid phase n-octane hydroisomerization was investigated over a series of zeolites containing 1 wt% Pt. PtBETA was the most active catalyst followed by PtMOR…”
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Kinetic assessment of dry reforming of methane on Pt+Ni containing composite of fluorite-like structure by Bobrova, L.N., Bobin, A.S., Mezentseva, N.V., Sadykov, V.A., Thybaut, J.W., Marin, G.B.

“…[Display omitted] •Methane dry reforming kinetics over the Pt+Ni/PrSmCeZrO/YSZ nanocomposite catalyst has been assessed.•First-order kinetics in methane was…”
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Relumped single-event microkinetic model for alkane hydrocracking on shape-selective catalysts: catalysis on ZSM-22 pore mouths, bridge acid sites and micropores by Laxmi Narasimhan, C.S., Thybaut, J.W., Marin, G.B., Denayer, J.F., Baron, G.V., Martens, J.A., Jacobs, P.A.

“…A relumped single-event microkinetic (SEMK) model is developed to describe alkane hydroconversion on shape-selective Pt-H/ZSM-22. The model, considers n…”
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Kinetic modeling of pore mouth catalysis in the hydroconversion of n-octane on Pt-H-ZSM-22 by Laxmi Narasimhan, C.S., Thybaut, J.W., Marin, G.B., Jacobs, Pierre A., Martens, J.A., Denayer, J.F., Baron, Gino V.

“…A microkinetic model based on the single-event theory was developed to describe the hydroconversion of n-octane on Pt-H-ZSM-22 zeolite. In the model, alkene…”
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Alkene Protonation Enthalpy Determination from Fundamental Kinetic Modeling of Alkane Hydroconversion on Pt/H–(US)Y-Zeolite by Thybaut, J.W, Marin, G.B, Baron, G.V, Jacobs, P.A, Martens, J.A

“…Alkane, c.q., C5 to C12, hydrocracking was performed on Pt/H–Y-zeolite and on Pt/H–USY-zeolites with Si/Al ratio of 13 and 30 at temperatures of 506–563 K,…”
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Analysis of volume‐to‐surface ratio effects on methane oxidative coupling using microkinetic modeling by Alexiadis, V. I., Serres, T., Marin, G. B., Mirodatos, C., Thybaut, J. W., Schuurman, Y.

“…The effect of the volume‐to‐surface (V/S) ratio on the catalytic performance of a La–Sr/CaO catalyst in a fixed bed reactor under oxidative coupling of methane…”
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Pyridine hydrodenitrogenation over industrial NiMo/γ-Al2O3 catalyst: Application of gas phase kinetic models to liquid phase reactions by Raghuveer, C.S., Thybaut, J.W., De Bruycker, R., Metaxas, K., Bera, T., Marin, G.B.

“…[Display omitted] •Extension of gas to liquid phase kinetics towards sulphided catalysts.•Solvent adsorption and bimolecular product was accounted for in the…”
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n-Hexadecane hydrocracking Single-Event MicroKinetics on Pt/H-beta by Vandegehuchte, B.D., Thybaut, J.W., Martínez, A., Arribas, M.A., Marin, G.B.

“…[Display omitted] ► The single-event concept was successfully applied to n-alkane hydrocracking on beta. ► The beta zeolite showed minor shape selectivity in…”
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Phase Composition and Catalytic Properties of MnNaW/SiO2 Oxide System in Oxidative Conversion of Methane by Ismailov, E. H., Taghiyev, D. B., Zulfugarova, S. M., Osmanova, S. N., Azimova, G. R., Thybaut, J. W.

“…MnNaW/SiO 2 oxide system based on a mesoporous silica matrix synthesized using tetraethoxysilane and cetyltrimethylammonium bromide as precursors were prepared…”
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Bridging the gap between liquid and vapor phase hydrocracking by Thybaut, J.W., Laxmi Narasimhan, C.S., Marin, G.B.

“…Research aimed at fundamental understanding of industrial reactions often leads to important differences, or so-called gaps, between laboratory and industrial…”
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Single-Event MicroKinetics (SEMK) for Methanol to Hydrocarbons (MTH) on H-ZSM-23 by Kumar, P., Thybaut, J.W., Teketel, S., Svelle, S., Beato, P., Olsbye, U., Marin, G.B.

“…•A Single-Event Microkinetic (SEMK) model is developed for ZSM-23.•Alkylation/cracking steps forming primary carbenium ions are additionally accounted for on…”
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Pore mouth physisorption of alkanes on ZSM-22: estimation of physisorption enthalpies and entropies by additivity method by Laxmi Narasimhan, C.S., Thybaut, J.W., Marin, G.B., Martens, J.A., Denayer, J.F., Baron, G.V.

“…ZSM-22 (TON-type) zeolite has a pore size close to that of alkanes and exhibits pronounced molecular sieve effects with alkanes. n-Alkanes physisorb through…”
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