Search Results - "Thyagarajan, Sunita"

Hydrogen Peroxide and Dioxygen Activation by Dinuclear Copper Complexes in Aqueous Solution: Hydroxyl Radical Production Initiated by Internal Electron Transfer by Zhu, Qing, Lian, Yuxiang, Thyagarajan, Sunita, Rokita, Steven E, Karlin, Kenneth D, Blough, Neil V

“…Dinuclear Cu(II) complexes, CuII 2 N n ( n = 4 or 5), were recently found to specifically cleave DNA in the presence of a reducing thiol and O2 or in the…”
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In pursuit of a stable peroxynitrite complex—NOx (x=1–3) derivatives of Tpt-Bu,MeCo by Thyagarajan, Sunita, Incarvito, Christopher D, Rheingold, Arnold L, Theopold, Klaus H

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Selective DNA Strand Scission with Binuclear Copper Complexes:  Implications for an Active Cu 2 −O 2 Species by Thyagarajan, Sunita, Murthy, Narasimha N., Narducci Sarjeant, Amy A., Karlin, Kenneth D., Rokita, Steve E.

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Selective DNA Strand Scission with Binuclear Copper Complexes:  Implications for an Active Cu2−O2 Species by Thyagarajan, Sunita, Murthy, Narasimha N, Narducci Sarjeant, Amy A, Karlin, Kenneth D, Rokita, Steve E

“…A homologous series of binuclear copper(II) complexes [CuII 2(N n )(Y)2]2+ (1−3) (n = 3−5 and Y = (ClO4)- or (NO3)-) were studied to investigate the…”
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Recognition of guanines at a double helix-coil junction in DNA by a trinuclear copper complex by Ito, Takeo, Thyagarajan, Sunita, Karlin, Kenneth D, Rokita, Steven E

“…Coordination between guanine N7 and a trinuclear copper complex appears critical for selective and efficient strand scission of DNA at a helix-coil junction as…”
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Intramolecular C−H Activation by Inferred Terminal Cobalt Imido Intermediates by Thyagarajan, Sunita, Shay, Daniel T, Incarvito, Christopher D, Rheingold, Arnold L, Theopold, Klaus H

“…Reaction of TpR,MeCo(I) dinitrogen complexes (R = i Pr, t Bu) with trimethylsilyl azide yields structurally characterized compounds that imply the formation of…”
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Carbon-hydrogen bond activation using sterically hindered hydrotris(pyrazolyl)borate cobalt complexes by Thyagarajan, Sunita

“…Chapter 1 deals with the reactivity of Tp t-Bu,MeCoH with dioxygen in solution and in the solid state. While the solution reaction yielded Tpt -Bu,MeCoOH and…”
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In pursuit of a stable peroxynitrite complex—NO x ( x=1–3) derivatives of Tp t-Bu,MeCo by Thyagarajan, Sunita, Incarvito, Christopher D, Rheingold, Arnold L, Theopold, Klaus H

“…Reaction of Tp t-Bu,MeCo(O 2) with NO yielded a mixture of Tp t-Bu,MeCo(NO 2) ( 2) and Tp t-Bu,MeCo(NO 3) ( 3) rather than the desired stable peroxynitrite…”
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