Search Results - "Thorne, James E."
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Understanding the origin of photoelectrode performance enhancement by probing surface kinetics
Published in Chemical science (Cambridge) (01-01-2016)“…Photoelectrochemical (PEC) water splitting holds the potential to meet the challenges associated with the intermittent nature of sunlight. Catalysts have often…”
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Energetics at the Surface of Photoelectrodes and Its Influence on the Photoelectrochemical Properties
Published in The journal of physical chemistry letters (15-10-2015)“…Photoelectrochemistry (PEC) holds potential as a direct route for solar energy storage. Its performance is governed by how efficiently photoexcited charges are…”
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Stable iridium dinuclear heterogeneous catalysts supported on metal-oxide substrate for solar water oxidation
Published in Proceedings of the National Academy of Sciences - PNAS (20-03-2018)“…Atomically dispersed catalysts refer to substrate-supported heterogeneous catalysts featuring one or a few active metal atoms that are separated from one…”
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Impact of the Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes
Published in The journal of physical chemistry letters (03-09-2020)“…Operando spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different…”
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Comparative study of photo-excited charge carrier dynamics of atomic layer deposited and solution-derived hematite films: Dependence of charge carrier kinetics on surface orientations
Published in Journal of photochemistry and photobiology. A, Chemistry. (01-09-2018)“…[Display omitted] •Electron/hole recombination in atomic layer deposited hematite was slower than that in solution-derived hematite.•Trapping of the long-lived…”
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Controlling the Electronic Coupling between CdSe Quantum Dots and Thiol Capping Ligands via pH and Ligand Selection
Published in Langmuir (31-07-2012)“…Comparison of the UV–vis absorption spectra of CdSe quantum dots (QDs) capped with various mercaptocarboxylic acid capping ligands reveals that only…”
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End-On Bound Iridium Dinuclear Heterogeneous Catalysts on WO3 for Solar Water Oxidation
Published in ACS central science (26-09-2018)“…Heterogeneous catalysts with atomically defined active centers hold great promise for high-performance applications. Among them, catalysts featuring active…”
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Investigation of Photoexcited Carrier Dynamics in Hematite and the Effect of Surface Modifications by an Advanced Transient Grating Technique
Published in ACS omega (31-03-2017)“…Photoexcited carrier dynamics in a hematite film with and without amorphous NiFeO x on the surface was investigated using the heterodyne transient grating…”
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Understanding Photocharging Effects on Bismuth Vanadate
Published in ACS applied materials & interfaces (12-07-2017)“…Bismuth vanadate (BiVO4) is a promising material for photoelectrochemical water oxidation. Recently, it has been shown that “photocharging” BiVO4 results in an…”
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Uncovering Photo-Excited Charge Carrier Dynamics in Hematite (α-Fe2O3) Hidden in the Nanosecond Range by the Heterodyne Transient Grating Technique Combined with the Randomly Interleaved Pulse-Train Method
Published in Journal of physical chemistry. C (21-03-2019)“…Photo-excited charge carrier dynamics in hematite (α-Fe2O3), ranging from 10–8 to 10–5 s, was investigated using the heterodyne transient grating technique in…”
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Strong O 2p–Fe 3d Hybridization Observed in Solution-Grown Hematite Films by Soft X‑ray Spectroscopies
Published in The journal of physical chemistry. B (18-01-2018)“…Photoelectrochemical (PEC) water splitting holds the potential as a direct route for solar energy conversation and storage. The performance of a PEC device is…”
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Photosensitization of ZnO single crystal electrodes with PbS quantum dots
Published in Physica status solidi. A, Applications and materials science (01-09-2014)“…Mott–Schottky analysis is used to determine the band edge positions for ZnO single crystals in acetonitrile electrolytes. The band alignment between ZnO and…”
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Sensitization of ZnO Single Crystal Electrodes with CdSe Quantum Dots
Published in Langmuir (28-10-2014)“…CdSe quantum dots (QDs) were attached to single crystal ZnO(0001) and ZnO(1100) substrates using capping groups, 4-mercaptobenzoic acid, 2-mercaptoacetic acid,…”
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Interaction of Mn with reducible CeO2(111) thin films
Published in Applied surface science (15-10-2013)“…•Oxidation/reduction processes occur upon deposition of a sub-monolayer coverage of Mn on ceria.•Mn is oxidized to Mn2+ at the cost of Ce4+ reduction to…”
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End-On Bound Iridium Dinuclear Heterogeneous Catalysts on WO 3 for Solar Water Oxidation
Published in ACS central science (26-09-2018)“…Heterogeneous catalysts with atomically defined active centers hold great promise for high-performance applications. Among them, catalysts featuring active…”
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Charge carrier kinetics in hematite with NiFeOx coating in aqueous solutions: Dependence on bias voltage
Published in Journal of photochemistry and photobiology. A, Chemistry. (15-02-2018)“…[Display omitted] •NiFeOx coating retarded the recombination rate of hematite.•NiFeOx coating plays a crucial role in improving the charge transfer efficiency…”
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Charge carrier kinetics in hematite with NiFeO^sub x^ coating in aqueous solutions: Dependence on bias voltage
Published in Journal of photochemistry and photobiology. A, Chemistry. (15-02-2018)“…Charge carrier dynamics of hematite with and without an amorphous NiFeOx coating were investigated in aqueous solution, depending on bias voltage. We found…”
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Strong O 2p–Fe 3d Hybridization Observed in Solution-Grown Hematite Films by Soft X-ray Spectroscopies
Published in The journal of physical chemistry. B (01-11-2017)“…Photoelectrochemical (PEC) water splitting holds the potential as a direct route for solar energy conversation and storage. The performance of a PEC device is…”
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Understanding the origin of photoelectrode performance enhancement by probing surface kinetics† †Electronic supplementary information (ESI) available: Calculations of Gärtner currents, JV curves of films, further IMPS data. See DOI: 10.1039/c5sc04519c
Published in Chemical science (Cambridge) (11-02-2016)“…Probing the surface kinetics of different hematite electrodes with and without surface passivations. Photoelectrochemical (PEC) water splitting holds the…”
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