Search Results - "Thoi, V Sara"

Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices by Baumann, Avery E., Burns, David A., Liu, Bingqian, Thoi, V. Sara

“…Metal-organic frameworks (MOFs) are a class of porous materials with unprecedented chemical and structural tunability. Their synthetic versatility, long-range…”
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Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions by Thoi, V Sara, Sun, Yujie, Long, Jeffrey R, Chang, Christopher J

“…Growing global energy demands and climate change motivate the development of new renewable energy technologies. In this context, water splitting using…”
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Reorganization of Interfacial Water by an Amphiphilic Cationic Surfactant Promotes CO2 Reduction by Zhang, Zhuo-Qun, Banerjee, Soumyodip, Thoi, V. Sara, Shoji Hall, Anthony

“…The presence of cetyltrimethylammonium bromide (CTAB) near the surface of a Cu electrode promotes the electrochemical reduction of CO2 to fuels. CTAB increases…”
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Graphene–Metal–Organic Framework Composite Sulfur Electrodes for Li–S Batteries with High Volumetric Capacity by Baumann, Avery E, Downing, Julia R, Burns, David A, Hersam, Mark C, Thoi, V. Sara

“…In an age of rapid acceleration toward next-generation energy storage technologies, lithium–sulfur (Li–S) batteries offer the desirable combination of low…”
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Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N‑Heterocyclic Carbene–Isoquinoline Complex by Thoi, V. Sara, Kornienko, Nikolay, Margarit, Charles G, Yang, Peidong, Chang, Christopher J

“…The solar-driven reduction of carbon dioxide to value-added chemical fuels is a longstanding challenge in the fields of catalysis, energy science, and green…”
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From Molecules to Porous Materials: Integrating Discrete Electrocatalytic Active Sites into Extended Frameworks by Banerjee, Soumyodip, Anayah, Rasha I, Gerke, Carter S, Thoi, V. Sara

“…Metal–organic and covalent–organic frameworks can serve as a bridge between the realms of homo- and heterogeneous catalytic systems. While there are numerous…”
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2D Oligosilyl Metal–Organic Frameworks as Multi‐state Switchable Materials by Burns, David A., Press, Eric M., Siegler, M. A., Klausen, Rebekka S., Thoi, V. Sara

“…We report the synthesis of a set of 2D metal–organic frameworks (MOFs) constructed with organosilicon‐based linkers. These oligosilyl MOFs feature linear…”
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Computational and Experimental Study of the Mechanism of Hydrogen Generation from Water by a Molecular Molybdenum-Oxo Electrocatalyst by Sundstrom, Eric J, Yang, Xinzheng, Thoi, V. Sara, Karunadasa, Hemamala I, Chang, Christopher J, Long, Jeffrey R, Head-Gordon, Martin

“…We investigate the mechanism for the electrocatalytic generation of hydrogen from water by the molecular molybdenum-oxo complex, [(PY5Me2)MoO]2+ (PY5Me2 =…”
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Guiding CO2RR Selectivity by Compositional Tuning in the Electrochemical Double Layer by Banerjee, Soumyodip, Gerke, Carter S, Thoi, V. Sara

“…Conspectus The electrochemical conversion of carbon dioxide to value-added chemicals provides an environmentally benign alternative to current industrial…”
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Lithium Thiophosphate Functionalized Zirconium MOFs for Li–S Batteries with Enhanced Rate Capabilities by Baumann, Avery E, Han, Xu, Butala, Megan M, Thoi, V. Sara

“…Zirconium metal–organic frameworks (Zr-MOFs) are renowned for their extraordinary stability and versatile chemical tunability. Several Zr-MOFs demonstrate a…”
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Non-Innocent Role of Porous Carbon Toward Enhancing C2–3 Products in the Electroreduction of Carbon Dioxide by Han, Xu, Thoi, V. Sara

“…Selectivity for C–C coupled products remains a major challenge for electrochemical CO2 reduction. Herein, we report a facile method by modifying a Cu foil…”
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Electric Fields at Metal–Surfactant Interfaces: A Combined Vibrational Spectroscopy and Capacitance Study by Sarkar, Sohini, Maitra, Anwesha, Banerjee, Soumyodip, Thoi, V. Sara, Dawlaty, Jahan M

“…Surfactants modulate interfacial processes. In electrochemical CO2 reduction, cationic surfactants promote carbon product formation and suppress hydrogen…”
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Surfactant Perturbation of Cation Interactions at the Electrode–Electrolyte Interface in Carbon Dioxide Reduction by Banerjee, Soumyodip, Zhang, Zhuo-Qun, Hall, Anthony Shoji, Thoi, V. Sara

“…Interfacial properties at the boundary between the electrode and electrolyte have important effects on the surface reactivity in electrocatalysis. Ionic…”
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Phosphate‐functionalized Zirconium Metal–Organic Frameworks for Enhancing Lithium–Sulfur Battery Cycling by Liu, Bingqian, Baumann, Avery E., Butala, Megan M., Thoi, V. Sara

“…Lithium–sulfur batteries are promising candidates for next‐generation energy storage devices due to their outstanding theoretical energy density. However, they…”
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Nickel N-heterocyclic carbene-pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water by Thoi, V Sara, Chang, Christopher J

“…We report a homologous series of nickel(II) complexes supported by N-heterocyclic carbene-pyridine ((R)bimpy, R = Me, Et, Pr) ligands that exhibit high…”
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Electrochemical Degradation of a Dicationic Rhenium Complex via Hoffman-Type Elimination by Saund, Simran S, Siegler, Maxime A, Thoi, V. Sara

“…Electrocatalytic reduction of carbon dioxide (CO2) by transition-metal catalysts is an attractive means for storing renewably sourced electricity in chemical…”
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Guiding CO 2 RR Selectivity by Compositional Tuning in the Electrochemical Double Layer by Banerjee, Soumyodip, Gerke, Carter S, Thoi, V Sara

“…The electrochemical conversion of carbon dioxide to value-added chemicals provides an environmentally benign alternative to current industrial practices…”
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Heterogeneous Interfaces through the Lens of Inorganic Chemistry by Thoi, V Sara, Yang, Jenny Y

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Lithiated Defect Sites in Zr Metal–Organic Framework for Enhanced Sulfur Utilization in Li–S Batteries by Baumann, Avery E, Burns, David A, Díaz, José C, Thoi, V. Sara

“…Lithium sulfur (Li–S) battery technology is one of the most promising candidates for next-generation energy storage devices; however, it is still hindered by…”
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Chemical Sulfide Tethering Improves Low-Temperature Li–S Battery Cycling by Burns, David A, Baumann, Avery E, Bennett, Kevin J, Díaz, José C, Thoi, V. Sara

“…Demands for energy storage and delivery continue to rise worldwide, making it imperative that reliable performance is achievable in diverse climates…”
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