Search Results - "Thiel, Werner R."
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Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis
Published in Angewandte Chemie (International ed.) (03-05-2010)“…Recovery and reuse of expensive catalysts after catalytic reactions are important factors for sustainable process management. The aim of this Review is to…”
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Mesoporous Organosilicas with Acidic Frameworks and Basic Sites in the Pores: An Approach to Cooperative Catalytic Reactions
Published in Angewandte Chemie (International ed.) (04-01-2010)“…Two in one: A periodic mesoporous phenylene silica (PMO) with acidic framework walls and basic pore channels was obtained by using protecting‐group techniques…”
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Palladium(II)-Phosphine Complexes Supported on Magnetic Nanoparticles: Filtration-Free, Recyclable Catalysts for Suzuki-Miyaura Cross-Coupling Reactions
Published in Advanced synthesis & catalysis (15-02-2010)“…An organic‐inorganic hybrid heterogeneous nanocatalyst system was synthesized by covalent grafting a palladium dichloride complex of the type (L)2PdCl2…”
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4
A Rechargeable Hydrogen Battery Based on Ru Catalysis
Published in Angewandte Chemie International Edition (01-07-2014)“…Apart from energy generation, the storage and liberation of energy are among the major problems in establishing a sustainable energy supply chain. Herein we…”
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Cooperative Acid-Base Effects with Functionalized Mesoporous Silica Nanoparticles: Applications in Carbon-Carbon Bond-Formation Reactions
Published in Chemistry : a European journal (20-07-2009)“…Acid–base bifunctional mesoporous silica nanoparticles (MSN) were prepared by a one‐step synthesis by co‐condensation of tetraethoxysilane (TEOS) and silanes…”
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Dinuclear Copper Complex Immobilized on a Janus-Type Material as an Interfacial Heterogeneous Catalyst for Green Synthesis
Published in ACS applied materials & interfaces (21-07-2021)“…We herein describe a rational design of a heterogeneous catalyst composed of a dinuclear cuprate anion being immobilized electrostatically on one surface of…”
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Fast and Selective Aqueous-Phase Oxidation of Styrene to Acetophenone Using a Mesoporous Janus-Type Palladium Catalyst
Published in Molecules (Basel, Switzerland) (26-10-2021)“…A heterogeneous Janus-type palladium interphase catalyst was obtained by selective surface modification of a hollow mesoporous silica material. The catalyst…”
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Copper-Catalyzed Protodecarboxylation of Aromatic Carboxylic Acids
Published in Advanced synthesis & catalysis (08-10-2007)“…A catalyst generated from copper(I) oxide and 4,7‐diphenyl‐1,10‐phenanthroline for the first time allows the catalytic protodecarboxylation even of deactivated…”
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Nanoparticle Supported, Magnetically Recoverable Oxodiperoxo Molybdenum Complexes: Efficient Catalysts for Selective Epoxidation Reactions
Published in Advanced synthesis & catalysis (01-08-2009)“…Organic‐inorganic hybrid heterogeneous nanocatalyst systems were synthesized by covalent anchoring of oxodiperoxomolybdenum complexes [(LL)MoO(O2)2] on silica…”
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10
Phosphine Functionalized CpC Ligands and Their Metal Complexes
Published in Chemistry an international journal (18-04-2023)“…Simple nucleophilic aliphatic substitution gives access to mono- and diphosphine ligands with a CpC group in the backbone. The monophosphine ligand coordinates…”
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Triazolyl Conjugated (Oligo)Phenothiazines Building Blocks for Hybrid Materials—Synthesis and Electronic Properties
Published in Molecules (Basel, Switzerland) (15-05-2021)“…The Cu-catalyzed alkyne-azide 1,3-dipolar cycloaddition variant provides a highly efficient entry to conjugated triazolyl-substituted (oligo)phenothiazine…”
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12
Photoinitiated Charge Transfer in a Triangular Silver(I) Hydride Complex and Its Oxophilicity
Published in Chemistry : a European journal (27-08-2019)“…Invited for the cover of this issue are the research groups of Rolf Diller, Gereon Niedner‐Schatteburg, Christoph Riehn and Werner R. Thiel from the TU…”
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13
Task‐Specific Janus Materials in Heterogeneous Catalysis
Published in Angewandte Chemie International Edition (26-09-2022)“…Janus materials are anisotropic nano‐ and microarchitectures with two different faces consisting of distinguishable or opposite physicochemical properties. In…”
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New Hexanuclear Group 11 Pyrazolate Complexes: Synthesis and Photophysical Features
Published in Chemistry : a European journal (14-03-2011)“…The treatment of 2,2′‐di(1,2‐pyrazol‐3‐yl)‐1,1′‐binaphthyl with two equivalents of appropriate monovalent group 11 precursors in the presence of a base leads…”
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Ruthenium(II)Phosphite Complexes as Catalysts for the Hydrogenation of Carbon Dioxide
Published in ChemCatChem (01-06-2013)“…Ru(II) for the home team: Ruthenium complexes of simple and cheap phosphite ligands give high activities in the hydrogenation of carbon dioxide under…”
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Periodic mesoporous organosilicas (PMOs): From synthesis strategies to applications
Published in Progress in materials science (01-04-2022)“…Since the first reports of periodic mesoporous organosilicas (PMOs) in 1999, this class of materials has attracted more and more attention. In general, such…”
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Mechanistic Studies on Ruthenium(II)‐Catalyzed Base‐Free Transfer Hydrogenation Triggered by Roll‐Over Cyclometalation
Published in ChemPlusChem (Weinheim, Germany) (01-02-2017)“…The synthesis of 2‐substituted pyridine–pyrimidine ligands and their complexation with arene ruthenium(II) chloride moieties is reported. Depending on the…”
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Periodic Mesoporous Organosilica Nanomaterials with Unconventional Structures and Properties
Published in Chemistry : a European journal (13-06-2023)“…Periodic mesoporous organosilicas (PMOs) are high surface area organic‐inorganic hybrid nanomaterials that have found broad applications in various fields of…”
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An Efficient Palladium N-Heterocyclic Carbene Catalyst Allowing the Suzuki-Miyaura Cross-Coupling of Aryl Chlorides and Arylboronic Acids at Room Temperature in Aqueous Solution
Published in Advanced synthesis & catalysis (26-05-2014)“…The application of a highly active Pd‐NHC catalyst for the Suzuki–Miyaura cross‐coupling of a broad variety of electronically activated and deactivated aryl…”
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Dibenzo[c,g]fluorenyliron: An Organometallic Relative of Pentahelicene
Published in Angewandte Chemie (International ed.) (14-04-2008)“…Close relatives! The Pd‐catalyzed hydrogenation of the “isolated” CC double bonds of dibenzo[c,g]fluorenide coordinated to an FeII center confirms that the…”
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