Search Results - "Thallapally, Praveen K"
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Covalent Organic Frameworks as a Decorating Platform for Utilization and Affinity Enhancement of Chelating Sites for Radionuclide Sequestration
Published in Advanced materials (Weinheim) (17-05-2018)“…The potential consequences of nuclear events and the complexity of nuclear waste management motivate the development of selective solid‐phase sorbents to…”
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Metal–organic framework with optimally selective xenon adsorption and separation
Published in Nature communications (13-06-2016)“…Nuclear energy is among the most viable alternatives to our current fossil fuel-based energy economy. The mass deployment of nuclear energy as a low-emissions…”
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Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption
Published in Nature communications (09-04-2019)“…The elimination of specific contaminants from competitors poses a significant challenge. Rather than relying on a single direct interaction, the cooperation of…”
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4
Reaction Environment Modification in Covalent Organic Frameworks for Catalytic Performance Enhancement
Published in Angewandte Chemie International Edition (24-06-2019)“…Herein, we show how the spatial environment in the functional pores of covalent organic frameworks (COFs) can be manipulated in order to exert control in…”
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Selective removal of cesium and strontium using porous frameworks from high level nuclear waste
Published in Chemical communications (Cambridge, England) (01-05-2016)“…Efficient and cost-effective removal of radioactive (137)Cs and (90)Sr found in spent fuel is an important step for safe, long-term storage of nuclear waste…”
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Potential of Metal–Organic Frameworks for Separation of Xenon and Krypton
Published in Accounts of chemical research (17-02-2015)“…Conspectus The total world energy demand is predicted to rise significantly over the next few decades, primarily driven by the continuous growth of the…”
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Iodine Adsorption in Metal Organic Frameworks in the Presence of Humidity
Published in ACS applied materials & interfaces (04-04-2018)“…Used nuclear fuel reprocessing represents a unique challenge when dealing with radionuclides such as isotopes of 85Kr and 129I2 due to their volatility and…”
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Selective CO2 Adsorption in a Supramolecular Organic Framework
Published in Angewandte Chemie International Edition (24-03-2016)“…Considering the rapidly rising CO2 level, there is a constant need for versatile materials which can selectively adsorb CO2 at low cost. The quest for…”
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Direct Observation of Xe and Kr Adsorption in a Xe-Selective Microporous Metal–Organic Framework
Published in Journal of the American Chemical Society (10-06-2015)“…The cryogenic separation of noble gases is energy-intensive and expensive, especially when low concentrations are involved. Metal–organic frameworks (MOFs)…”
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Radiation-resistant metal-organic framework enables efficient separation of krypton fission gas from spent nuclear fuel
Published in Nature communications (18-06-2020)“…Capture and storage of volatile radionuclides that result from processing of used nuclear fuel is a major challenge. Solid adsorbents, in particular…”
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Hybrid Ultra-Microporous Materials for Selective Xenon Adsorption and Separation
Published in Angewandte Chemie (International ed.) (11-07-2016)“…The demand for Xe/Kr separation continues to grow due to the industrial significance of high‐purity Xe gas. Current separation processes rely on energy…”
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12
In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High-Performance Supercapacitors
Published in ACS applied materials & interfaces (28-05-2014)“…A hierarchically structured nitrogen-doped porous carbon is prepared from a nitrogen-containing isoreticular metal-organic framework (IRMOF-3) using a…”
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Highly Selective Carbon Dioxide Uptake by [Cu(bpy-n)2(SiF6)] (bpy-1 = 4,4′-Bipyridine; bpy-2 = 1,2-Bis(4-pyridyl)ethene)
Published in Journal of the American Chemical Society (29-02-2012)“…A previously known class of porous coordination polymer (PCP) of formula [Cu(bpy-n)2(SiF6)] (bpy-1 = 4,4′-bipyridine; bpy-2 = 1,2-bis(4-pyridyl)ethene) has…”
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14
Effect of ring rotation upon gas adsorption in SIFSIX-3-M (M = Fe, Ni) pillared square grid networks
Published in Chemical science (Cambridge) (2017)“…Dynamic and flexible metal-organic frameworks (MOFs) that respond to external stimuli, such as stress, light, heat, and the presence of guest molecules, hold…”
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15
Iodine immobilization by materials through sorption and redox-driven processes: A literature review
Published in The Science of the total environment (10-05-2020)“…Radioiodine-129 (129I) in the subsurface is mobile and limited information is available on treatment technologies. Scientific literature was reviewed to…”
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Noria: A Highly Xe-Selective Nanoporous Organic Solid
Published in Chemistry : a European journal (26-08-2016)“…Separation of xenon and krypton is of industrial and environmental concern; the existing technologies use cryogenic distillation. Thus, a cost‐effective,…”
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Flexible (Breathing) Interpenetrated Metal−Organic Frameworks for CO2 Separation Applications
Published in Journal of the American Chemical Society (17-12-2008)“…A breathing 2-fold interpenetrated microporous metal−organic framework was synthesized with a flexible tetrahedral organic linker and Zn2 clusters that sorb…”
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Fluorocarbon adsorption in hierarchical porous frameworks
Published in Nature communications (09-07-2014)“…Metal-organic frameworks comprise an important class of solid-state materials and have potential for many emerging applications such as energy storage,…”
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Amorphous Molecular Organic Solids for Gas Adsorption
Published in Angewandte Chemie International Edition (13-07-2009)“…Fixing the hole: Molecular organic compounds with large accessible internal cavities display gas‐storage ability in the amorphous solid state. This finding…”
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Gas-Induced Expansion and Contraction of a Fluorinated Metal−Organic Framework
Published in Crystal growth & design (03-03-2010)“…Synthesis and gas sorption properties of a novel fluorinated metal−organic framework using commercially available 2,2-bis(4-carboxyphenyl)hexafluoropropane is…”
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