Search Results - "Tatina, Madhu Babu"
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Zinc Acetate Catalyzed Stereoselective 1,2-trans-Glycosylation Using Glycosyl Chlorides
Published in SynOpen (2017) (01-10-2022)“…Abstract We report a strategy for the stereoselective synthesis of 1,2-trans-glycosides in the absence of neighboring group participation. The present protocol…”
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2
Robust perfluorophenylboronic acid-catalyzed stereoselective synthesis of 2,3-unsaturated O -, C -, N - and S -linked glycosides
Published in Beilstein journal of organic chemistry (2019)“…A convenient protocol was developed for the synthesis of 2,3-unsaturated , - and -linked glycosides (enosides) using 20 mol % perflurophenylboronic acid…”
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3
Citric acid mediated simple and stereoselective synthesis of o-linked glycosides by Ferrier rearrangement
Published in Results in Chemistry (01-01-2022)“…Citric acid is versatile reagent for many glycals with good yield and selectivity well suited for the synthesis of pseudodisaccharides. [Display omitted]…”
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Organo-zinc Promoted Diastereoselective C‑Arylation of 1,2-Anhydrosugars from Arylboronic Acids
Published in Organic letters (18-09-2015)“…α-C-arylglycosides can be obtained through the addition of aryl zinc reagents to sugar epoxides. The required aryl zinc nucleophiles can be easily obtained…”
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5
Perfluorophenylboronic acid-catalyzed direct α-stereoselective synthesis of 2-deoxygalactosides from deactivated peracetylated d-galactal
Published in Chemical communications (Cambridge, England) (08-10-2019)“…Perfluorophenylboronic acid 1c catalyzes the direct stereoselective addition of alcohol nucleophiles to deactivated peracetylated d-galactal to give…”
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6
Efficient Synthesis of α‐Glycosyl Chlorides Using 2‐Chloro‐1,3‐dimethylimidazolinium Chloride: A Convenient Protocol for Quick One‐Pot Glycosylation
Published in European journal of organic chemistry (24-05-2018)“…A mild and convenient method for the synthesis of α‐glycosyl chlorides in high 80–96 % yields within 15–30 min using 2‐chloro‐1,3‐dimethylimidazolinium…”
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First Exclusive Stereo‐ and Regioselective Preparation of 5‐Arylimino‐1,3,4‐Selenadiazole Derivatives: Synthesis, NMR analysis, and Computational Studies
Published in Chemistry, an Asian journal (01-09-2023)“…Isoselenocyanates are valuable coupling partners required for preparing key chemical intermediates and biologically active molecules in an accelerated and…”
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8
Total Synthesis of Streptococcus suis Serotype 8 Capsular Polysaccharide Repeating Unit
Published in ChemistrySelect (Weinheim) (13-03-2023)“…The first total synthesis of capsular polysaccharide (CPS) repeating unit [2)‐α‐l‐Rhap‐1→P→4‐β‐d‐ManpNAc‐(1→4)‐α‐d‐Glcp‐(1]n of streptococcus suis serotype 8…”
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9
Construction of Fused Oxabicyclic Scaffolds from Glycals and Styrenes via One-Pot Domino Transformations
Published in Organic letters (03-05-2019)“…Triflic acid catalyzed cascade stereoselective reaction of glycals with styrenes delivers complex oxabicyclic scaffolds such as cis-oxadecalins or…”
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10
TEMPO-Promoted Domino Heck–Suzuki Arylation: Diastereoselective Cis-Diarylation of Glycals and Pseudoglycals
Published in Organic letters (07-08-2015)“…A palladium-catalyzed regio- and diastereoselective diarylation of glycals and pseudoglycals, which is a kind of Heck–Suzuki arylation, is described. A wide…”
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11
A Practical Synthesis of Densely Functionalized Pyrroles via a Three-Component Cascade Reaction between Carbohydrates, Oxoacetonitriles, and Ammonium Acetate
Published in Journal of organic chemistry (01-01-2021)“…A practical three-component reaction between unactivated carbohydrates, oxoacetonitriles, and ammonium acetate gave densely functionalized pyrroles in 75–96%…”
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12
TMSOTf-Promoted Intermolecular Cascade Reaction of Aromatic Diazo Ketones with Olefins: Selective Synthesis of 3‑Arylethylideneoxindoles
Published in Journal of organic chemistry (17-07-2020)“…A simple trimethylsilyl trifluoromethanesulfonate (TMSOTf)-promoted intermolecular cascade reaction of aromatic diazo ketones with olefins has been developed…”
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Diastereoselective sp 2 -sp 3 coupling of sugar enol ethers with unactivated cycloalkenes: new entries to C-branched sugars
Published in Organic & biomolecular chemistry (25-10-2016)“…Sugar enol ethers undergo efficient coupling at C-2 with unactivated cycloalkenes under a low Pd loading affording allylic substitution products. High…”
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14
Zinc mediated activation of terminal alkynes: stereoselective synthesis of alkynyl glycosides
Published in Organic & biomolecular chemistry (28-10-2014)“…Zinc mediated alkynylation reaction was studied for the preparation of C-glycosides from unactivated alkynes. Different glycosyl donors such as glycals and…”
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