Search Results - "Tasker, Peter A."
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A Simple Primary Amide for the Selective Recovery of Gold from Secondary Resources
Published in Angewandte Chemie (International ed.) (26-09-2016)“…Waste electrical and electronic equipment (WEEE) such as mobile phones contains a plethora of metals of which gold is by far the most valuable. Herein a simple…”
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2
From Gas Phase Observations to Solid State Reality: The Identification and Isolation of Trinuclear Salicylaldoximato Copper Complexes
Published in Molecules (Basel, Switzerland) (29-09-2022)“…Conditions have been identified in which phenolic aldoximes and ketoximes of the types used in commercial solvent extraction processes can be doubly…”
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3
Anion Receptor Design: Exploiting Outer-Sphere Coordination Chemistry To Obtain High Selectivity for Chloridometalates over Chloride
Published in Inorganic chemistry (08-09-2015)“…High anion selectivity for PtCl6 2– over Cl– is shown by a series of amidoamines, R1R2NCOCH2CH2NR3R4 (L1 with R1 = R4 = benzyl and R2 = R3 = phenyl and L3 with…”
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4
Outer-Sphere Coordination Chemistry: Amido-Ammonium Ligands as Highly Selective Tetrachloridozinc(II)ate Extractants
Published in Inorganic chemistry (03-12-2012)“…Eight new amido functionalized reagents, L1–L8, have been synthesized containing the sequence of atoms R2N–CH2–NR′–CO–R″, which upon protonation forms a…”
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5
Selective Extraction and Transport of the [PtCl6]2− Anion through Outer‐Sphere Coordination Chemistry
Published in Chemistry : a European journal (04-05-2009)“…Platinum recovery: Tripodal receptors incorporating urea, amido or sulfonamido hydrogen‐bond donors show high loading and selectivity for extraction of…”
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6
Structural, Magnetic, and Electronic Properties of Phenolic Oxime Complexes of Cu and Ni
Published in Inorganic chemistry (19-12-2011)“…Square planar complexes of the type Ni(L1)2, Ni(L2)2, Cu(L1)2, and Cu(L2)2, where L1H = 2-hydroxy-5-t-octylacetophenone oxime and L2H =…”
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7
Using the Outer Coordination Sphere to Tune the Strength of Metal Extractants
Published in Inorganic chemistry (16-05-2011)“…A series of 3-substituted salicylaldoximes has been used to demonstrate the importance of outer-sphere interactions on the efficacy of solvent extractants that…”
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Effect of pressure on the crystal structure of salicylaldoxime-I, and the structure of salicylaldoxime-II at 5.93 GPa
Published in Acta crystallographica. Section B, Structural science (01-12-2006)“…The effect of pressure on the crystal structure of salicylaldoxime has been investigated. The ambient‐pressure phase (salicylaldoxime‐I) consists of pairs of…”
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Anion Selectivity in Zwitterionic Amide-Functionalised Metal Salt Extractants
Published in Chemistry : a European journal (01-01-2007)“…Amide‐functionalised salen ligands capable of extracting metal salts have been synthesised and characterised. Single‐crystal X‐ray structure determinations of…”
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10
Metal-binding motifs of alkyl and aryl phosphinates; versatile mono and polynucleating ligands
Published in Coordination chemistry reviews (15-03-2017)“…Dimers, trimers, rings and chains formed by the most common (μ2) binding motifs of phosphinate ligands. [Display omitted] •Phosphinates are extraordinarily…”
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11
Proton Chelating Ligands Drive Improved Chemical Separations for Rhodium
Published in Inorganic chemistry (01-07-2019)“…Current methods for the extraction of rhodium carry the highest carbon footprint and worst pollution metrics of all of the elements used in modern…”
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12
Reversible Pressure‐Controlled Depolymerization of a Copper(II)‐Containing Coordination Polymer
Published in Chemistry : a European journal (12-09-2017)“…A unique pressure‐induced Cu−N bond breaking/bond forming reaction is reported. The variation of pressure on a single crystal of a one‐dimensional copper‐…”
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13
A Computational and Experimental Study on the Binding of Dithio Ligands to Sperrylite, Pentlandite, and Platinum
Published in Journal of physical chemistry. C (06-10-2016)“…This benchmark study documents a combined computational and experimental investigation into the binding of three commercial dithio collector ligands used in…”
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14
Evaluation of Simple Amides in the Selective Recovery of Gold from Secondary Sources by Solvent Extraction
Published in ACS sustainable chemistry & engineering (03-09-2019)“…The recycling of metals from end-of-life secondary sources such as electronic waste remains a significant environmental and technological challenge currently…”
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15
The Supramolecular and Coordination Chemistry of Cobalt(II) Extraction by Phosphinic Acids
Published in European journal of inorganic chemistry (09-04-2018)“…A combination of mass spectrometry, DFT calculations and 31P{1H} NMR spectroscopy has been used to define the mode of action of the commercial cobalt…”
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Outer-Sphere Coordination Chemistry: Selective Extraction and Transport of the [PtCl₆]²⁻ Anion
Published in Angewandte Chemie (International ed.) (15-02-2008)“…What's on the outside? Selective extraction and transport of [PtCl6]2− from aqueous acidic solutions in the presence of excess chloride has been demonstrated…”
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17
First-Principles Study on Ligand Binding and Positional Disorder in Pentlandite
Published in Journal of physical chemistry. C (12-11-2015)“…Density functional theory, in conjunction with a cluster expansion model, has been used to study the structure and stability of the positionally disordered…”
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18
A Comparison of the Selectivity of Extraction of [PtCl6](2-) by Mono-, Bi-, and Tripodal Receptors That Address Its Outer Coordination Sphere
Published in Inorganic chemistry (20-06-2016)“…Extraction and binding studies of [PtCl6](2-) are reported for 24 mono-, bi-, and tripodal extractants containing tris(2-aminoethyl)amine (TREN) or…”
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Piezochromism in Nickel Salicylaldoximato Complexes: Tuning Crystal-Field Splitting with High Pressure
Published in Chemistry : a European journal (18-06-2012)“…The crystal structures of bis(3‐fluoro‐salicylaldoximato)nickel(II) and bis(3‐methoxy‐salicylaldoximato)nickel(II) have been determined at room temperature…”
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EPR/ENDOR and Computational Study of Outer Sphere Interactions in Copper Complexes of Phenolic Oximes
Published in Inorganic chemistry (08-09-2015)“…Copper complexes of the phenolic oxime family of ligands (3-X-salicylaldoximes) are used extensively as metal solvent extractants. Incorporation of…”
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