Search Results - "Tang, Christina Y."
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Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues
Published in Angewandte Chemie (International ed.) (25-01-2010)“…Side‐on or end‐on? Rhodium and iridium complexes featuring aminoboranes (R2NBH2) as ligands have been synthesized and structurally characterized…”
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Hydrogen shuttling: synthesis and reactivity of a 14-electron iridium complex featuring a bis(alkyl) tethered N-heterocyclic carbene ligand
Published in Chemical communications (Cambridge, England) (01-01-2012)“…Solvent dependent double C-H activation in an Ir(NHC)(2) system generates an agostically stabilized 14-electron complex featuring a face-capping bis(alkyl)…”
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Iridium-Mediated Borylation of Benzylic CH Bonds by Borohydride
Published in Angewandte Chemie (International ed.) (07-02-2011)“…Simple source: An intramolecular iridium‐mediated CH borylation proceeds through transfer of a BH3 fragment from borohydride to a benzylic carbon center (see…”
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The Monoammoniate of Lithium Borohydride, Li(NH3)BH4: An Effective Ammonia Storage Compound
Published in Chemistry, an Asian journal (02-06-2009)“…Store it up: The ammoniate, Li(NH3)BH4, has been prepared and fully characterized by Raman and NMR spectroscopy and X‐ray powder diffraction. The potential for…”
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Dehydrogenation of Saturated CC and BN Bonds at Cationic N-Heterocyclic Carbene Stabilized M(III) Centers (M = Rh, Ir)
Published in Journal of the American Chemical Society (04-08-2010)“…Chloride abstraction from the group 9 metal bis(N-heterocyclic carbene) complexes M(NHC)2(H)2Cl [M = Rh, Ir; NHC = IPr =…”
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A New Class of Binuclear Gallium Hydrides: Synthesis and Properties of [{GaCl(hpp)H}2] (hpp=1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidate)
Published in Chemistry : a European journal (01-01-2007)“…Herein we report on the synthesis and characterization of the first representative of a new class of gallium hydrides, namely [{GaCl(hpp)H}2]…”
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Stable GaX2, InX2 and TlX2 radicals
Published in Nature chemistry (01-04-2014)“…The chemistry of the Group 13 metals is dominated by the +1 and +3 oxidation states, and simple monomeric M (II) species are typically short-lived, highly…”
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Focus group evaluation from the perspective of program implementers: findings based on the secondary 2 program
Published in TheScientificWorld (01-10-2009)“…Nine focus groups comprising 23 program implementers recruited from nine schools were conducted to evaluate the Tier 1 Program (Secondary 2 Program) of the…”
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Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Systems: Multiple C−H Activation Processes and Isomeric Normal/Abnormal Carbene Complexes
Published in Organometallics (25-05-2009)“…The reaction of [Ir(coe)2Cl]2 (coe = cyclooctene) with the N-heterocyclic carbene N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) in tetrahydrofuran…”
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Experimental implementation of the secondary 3 program of project P.A.T.H.S.: observations based on the co-walker scheme
Published in TheScientificWorld (01-01-2009)“…Classroom observations based on the Co-Walker Scheme were conducted in 34 schools in order to examine the implementation quality of the Tier 1 Program…”
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Interaction of In(I) and Tl(I) Cations with 2,6-Diaryl Pyridine Ligands: Cation Encapsulation within a Very Weakly Interacting N/Arene Host Environment
Published in Inorganic chemistry (03-12-2012)“…The interaction of 2,6-dimesitylpyridine with Tl(I) and In(I) cations has been investigated with a view to developing tractable molecular M(I) compounds which…”
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IR and Raman Characterization of the Zincocenes (η5-C5Me5)2Zn2 and (η5-C5Me5)(η1-C5Me5)Zn
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (23-10-2008)“…The measured Raman and IR spectra of solid, polycrystalline bis(pentamethylcyclopentadienyl)dizinc, (η5-C5Me5)2Zn2, 1, and…”
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Preparation and Characterization of Lithium Imidoalanate Complexes Li2[(RN)4(AlH2)6] (R = Me or t Bu): First Examples of Aluminum-Rich Imidoalanes with an Adamantoid Structure
Published in Inorganic chemistry (25-06-2007)“…Whereas methylammonium chloride, [MeNH3]Cl, reacts with LiGaH4 in an ether solution to give, according to the conditions, either the adduct MeH2N·GaH3 or the…”
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Decomposition of Monochlorogallane, [H2GaCl] n , and Adducts with Amine and Phosphine Bases: Formation of Cationic Gallane Derivatives
Published in Inorganic chemistry (03-10-2005)“…Thermal decomposition of monochlorogallane, [H2GaCl] n , at ambient temperatures results in the formation of subvalent gallium species. To Ga[HGaCl3],…”
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Molecular Structures of Two Metal Tetrakis(tetrahydroborates), Zr(BH4)4 and U(BH4)4: Equilibrium Conformations and Barriers to Internal Rotation of the Triply Bridging BH4 Groups
Published in Inorganic chemistry (16-12-2002)“…The molecular structures of Zr[(μ-H)3BH]4 and U[(μ-H)3BH]4 have been investigated by density functional theory (DFT) calculations and gas electron diffraction…”
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Bulky N-heterocyclic carbene and pyridine donor adducts of Co(II) bromide: Influence on reactivity of stoichiometry, sterics and donor capability
Published in Journal of organometallic chemistry (01-10-2013)“…The reactivity of cobalt dibromide with the bulky N-heterocyclic carbenes IMes and IPr has been explored…”
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Iridium-Mediated Borylation of Benzylic CH Bonds by Borohydride
Published in Angewandte Chemie International Edition (07-02-2011)Get full text
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Subjective outcome evaluation of the Project P.A.T.H.S.: findings based on different datasets
Published in International journal of adolescent medicine and health (01-09-2011)“…A total of 216 schools participated in the Project P.A.T.H.S. in the 2008/2009 school year. After completion of the Tier 1 Program, subjective outcome…”
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Formation and Characterization of the Cationic Gallane Derivatives [(RH2N)2GaH2]Cl (R = Me or iPr) and [{(iPrH2N)GaH2NHiPr}2GaH2]Cl
Published in European Journal of Inorganic Chemistry (01-02-2008)“…The reaction of LiGaH4 with an excess of the hydrochloride of a primary amine RNH2 in ether solution yields in [(RH2N)2GaH2]Cl (R = Me, 1, or iPr, 2)…”
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