Search Results - "Tan, Jacqueline S. J"

Dynamic Intermediates in the Radical Cation Diels–Alder Cycloaddition: Lifetime and Suprafacial Stereoselectivity by Tan, Jacqueline S. J, Hirvonen, Viivi, Paton, Robert S

“…Cation radical Diels–Alder cycloadditions proceed via an acyclic intermediate that exists on a flat region of the potential energy surface. Competition between…”
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Interfacial Properties and Monolayer Collapse of Alkyl Benzenesulfonate Surfactant Monolayers at the Decane–Water Interface from Molecular Dynamics Simulations by Tan, Jacqueline S. J, Zhang, Liping, Lim, Freda C. H, Cheong, Daniel W

“…The molecular structure of a surfactant molecule is known to have a great effect on the interfacial properties and the type of nanostructures formed. In this…”
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Frontier molecular orbital effects control the hole-catalyzed racemization of atropisomeric biaryls by Tan, Jacqueline S J, Paton, Robert S

“…Atropisomeric biaryl systems are privileged architectures used in asymmetric synthesis and pharmaceutical structures. We report that by simply removing a…”
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A systematic investigation of the ring size effects on the free radical ring‐opening polymerization (rROP) of cyclic ketene acetal (CKA) using both experimental and theoretical approach by Reddy Mothe, Srinivasa, Tan, Jacqueline S. J., Chennamaneni, Lohitha R., Aidil, Farhan, Su, Yi, Kang, Hway C., Lim, Freda C. H., Thoniyot, Praveen

“…ABSTRACT Radical ring‐opening polymerization (rROP) reaction of cyclic ketene acetals (CKA) is an interesting route to biodegradable polymers. Contrary to…”
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Frontier molecular orbital effects control the hole-catalyzed racemization of atropisomeric biarylsElectronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05066j by Tan, Jacqueline S. J, Paton, Robert S

“…Atropisomeric biaryl systems are privileged architectures used in asymmetric synthesis and pharmaceutical structures. We report that by simply removing a…”
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Frontier molecular orbital effects control the hole-catalyzed racemization of atropisomeric biaryls† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05066j by Tan, Jacqueline S. J., Paton, Robert S.

“…Biaryl atropisomerization is dramatically accelerated by the removal of an electron. The planar transition state is preferentially stabilized from depopulation…”
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