Search Results - "Takahashi, Rintaro"
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In Situ Monitoring of Polymerization-Induced Self-Assembly and Gelation During the Synthesis of Triblock Copolymers via Time-Resolved Small-Angle X‑ray Scattering and Rheology
Published in Macromolecules (13-06-2023)“…The polymerization of solvophobic monomers from both ends of solvophilic polymers produces BAB triblock copolymers in solution. The self-assembly of the…”
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Structure and Rheology of Poly(vinylidene difluoride-co-hexafluoropropylene) in an Ionic Liquid: The Solvent Behaves as a Weak Cross-Linker through Ion–Dipole Interaction
Published in Macromolecules (12-07-2022)“…Mixtures of poly(vinylidene difluoride-co-hexafluoropropylene) (PVDF-HFP) and ionic liquids (IL) are known to form flexible, self-healing, and ion-conductive…”
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Growth Kinetics of Polyelectrolyte Complexes Formed from Oppositely-Charged Homopolymers Studied by Time-Resolved Ultra-Small-Angle X‑ray Scattering
Published in The journal of physical chemistry letters (16-02-2017)“…We have monitored the kinetic process of polyelectrolyte complex formation between sodium polyacrylate (SPA) and polyallylamine hydrochrolide (PAH) in aqueous…”
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4
Flower Necklaces of Controllable Length Formed From N‑(2-Hydroxypropyl) Methacrylamide-Based Amphiphilic Statistical Copolymers
Published in Langmuir (06-10-2020)“…N-(2-Hydroxypropyl)methacrylamide (HPMA)-based statistical copolymers bearing anticancer drugs have attracted attention for their efficacy in cancer…”
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5
Competition between the micellization and the liquid–liquid phase separation in amphiphilic block copolymer solutions
Published in Polymer journal (01-02-2017)“…We have formulated the mixing Gibbs energy density for the micelle phase of an amphiphilic block copolymer solution using mean-field lattice theory. We have…”
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Kinetics of Morphological Transition between Cylindrical and Spherical Micelles in a Mixture of Anionic–Neutral and Cationic–Neutral Block Copolymers Studied by Time-Resolved SAXS and USAXS
Published in Macromolecules (22-05-2018)“…This study is concerned with the morphological transition kinetics of polyelectrolyte complex micelles formed from an anionic–neutral block copolymer and a…”
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In Situ and Ex Situ Studies of Ring-Like Assembly of Silica Nanoparticles in the Presence of Poly(propylene oxide)–Poly(ethylene oxide) Block Copolymers
Published in Langmuir (15-08-2023)“…Block copolymer-mediated self-assembly of colloidal nanoparticles has attracted great attention for fabricating various nanoparticle arrays. We have previously…”
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Self-Assembly of Calix[4]arene-Based Amphiphiles Bearing Polyethylene Glycols: Another Example of “Platonic Micelles”
Published in Langmuir (12-09-2017)“…The aggregation number of classical micelles exhibits a certain distribution, which is a recognizable feature of conventional micelles. However, we recently…”
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Stable Water-soluble Polyion Complex Micelles Composed of Oppositely Charged Diblock Copolymers and Reinforced by Hydrophobic Interactions
Published in Chemistry letters (05-08-2022)“…Polyion complex (PIC) micelles having a hydrodynamic radius of approximately 20 nm were prepared in water by simply mixing a pair of double hydrophilic…”
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Morphological Transition of Oppositely Charged Calix[4]arene Surfactant Mixture
Published in Langmuir (09-10-2018)“…When a negatively charged sulfonic or a positively charged amine group is attached to calix[4]arene surfactants, denoted as SCal7 and QACal7, respectively,…”
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Intermolecular Interactions and Self-Assembly in Aqueous Solution of a Mixture of Anionic–Neutral and Cationic–Neutral Block Copolymers
Published in Macromolecules (13-10-2015)“…We have investigated the self-assembly in dilute aqueous solutions of a mixture of an anionic–neutral block copolymer (AP) and a cationic–neutral block…”
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Reversible Vesicle–Spherical Micelle Transition in a Polyion Complex Micellar System Induced by Changing the Mixing Ratio of Copolymer Components
Published in Macromolecules (26-04-2016)“…The mixing ratio dependence of the morphology of a polyion complex micelle formed of an anionic–neutral double-hydrophilic block copolymer (AP) and a…”
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First Observation of the Hydration Layer around Polymer Chain by Scattering and Its Relationship to Thromboresistance: Dilute Solution Properties of PMEA in THF/Water
Published in The journal of physical chemistry. B (08-07-2021)“…Poly(2-methoxyethyl acrylate) (PMEA) is known to exhibit excellent thromboresistance, i.e., hardly causing blood-clot formation on its surface. Hence, PMEA…”
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Synthesis and characterization of nanoemulsion-mediated core crosslinked nanoparticles, and in vivo pharmacokinetics depending on the structural characteristics
Published in Journal of controlled release (10-08-2020)“…For designing nanoparticles as drug carriers, a covalently crosslinked structure is necessary for the structural stability in vivo. In this study, we prepared…”
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Discrete and Discontinuous Increase in the Micellar Aggregation Number: Effects of the Alkyl Chain Length on Platonic Micelles
Published in Langmuir (26-02-2019)“…Micelles with perfect monodispersity in terms of the aggregation number (N agg) have recently been discovered, whose values of N agg interestingly always…”
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Monitoring the Discontinuous Dodecamer–Icosamer Transition of a Calix[4]arene‐Derived Surfactant by Time‐Resolved Small‐Angle X‐ray Scattering
Published in Angewandte Chemie International Edition (06-06-2017)“…Calix[4]arene‐derived surfactants form monodisperse micelles with a well‐defined aggregation number (Nagg) of 4, 6, 8, 12, or 20, corresponding to the Platonic…”
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Unraveling Decisive Structural Parameters for the Self-Assembly of Supramolecular Polymer Bottlebrushes Based on Benzene Trisureas
Published in Macromolecules (08-09-2020)“…By introducing strong directed hydrogen bonds to an amphiphilic polymer, we demonstrate that phase transitions from spherical to cylindrical morphologies in…”
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Structural Polymorphism of Resorcinarene Assemblies
Published in Langmuir (09-06-2020)“…In 1997, a study based on X-ray crystallography revealed that resorcinarenes adopt a hexameric capsule-like structure. The function of resorcinarenes has been…”
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Local and global conformations of flower micelles and flower necklaces formed by an amphiphilic alternating copolymer in aqueous solution
Published in Polymer journal (01-08-2016)“…We investigated the local and global conformations of flower micelles and flower necklaces formed by the amphiphilic alternating copolymer of sodium maleate…”
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A Thermo-Responsive Polymer Micelle with a Liquid Crystalline Core
Published in Polymers (02-02-2023)“…An amphiphilic diblock copolymer (PChM-PNIPAM), composed of poly(cholesteryl 6-methacryloyloxy hexanoate) (PChM) and poly( -isopropyl acrylamide) (PNIPAM)…”
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