Search Results - "Tajada, A"
-
1
Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex
Published in Organometallics (01-09-2003)“…Complex (1) reacts with acetophenone and benzophenone to give (R = CH3 (2), Ph (3)). In the solid state, the structure of 2 determined by X-ray diffraction…”
Get full text
Journal Article -
2
Preparation and Characterization of Osmium−Stannyl Polyhydrides: d4−d2 Oxidative Addition of Neutral Molecules in a Late Transition Metal
Published in Organometallics (12-05-2003)“…Complex OsH2Cl2(PiPr3)2 (1) reacts with 2.0 equiv of HSnPh3 to give the tetrahydride-stannyl derivative OsH4Cl(SnPh3)(PiPr3)2 (2) and ClSnPh3. The structure of…”
Get full text
Journal Article -
3
The Dihydride−Osmium(IV) Complex [OsH2(κ 2-O2CCH3)(H2O)(PiPr3)2]BF4 as a Precursor for Carbon−Carbon Coupling Reactions
Published in Organometallics (27-11-2000)“…The dihydride−osmium(IV) complex [OsH2(κ 2-O2CCH3)(H2O)(PiPr3)2]BF4 (1) reacts with acetylene (1 atm) at 0 °C to give polyacetylene and the vinyl−carbyne…”
Get full text
Journal Article -
4
Synthesis of Hydrido−Vinylidene and Hydrido−Carbyne Osmium Complexes Containing Pyrazole: New Examples of N−H···Y (Y = N, F, Cl) Hydrogen Bonds
Published in Organometallics (02-08-1999)“…The hydrido−carbyne complex OsHCl2(⋮CCH2Ph)(PiPr3)2 (1) reacts with pyrazole in the presence of KOH to afford the six-coordinate hydrido−vinylidene…”
Get full text
Journal Article -
5
Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent
Published in Organometallics (22-11-1999)“…Reaction of OsH2(κ 2-OCOCH3){κ 1-OC(O)CH3}(PiPr3)2 (1) with 1/2HBF4·OEt2 leads to the dimer [{OsH2(κ 2-OCOCH3)(PiPr3)2}2(μ-OCOCH3)]BF4 (2), while the reaction…”
Get full text
Journal Article -
6
Dihydride versus Elongated Dihydrogen in [H2Os(κ 2-O2CCH3)L(PiPr3)2]+ Complexes: Influence of the L Ligand
Published in Organometallics (18-03-2002)“…The complex [OsH2(κ2-O2CCH3)(H2O)(PiPr3)2]BF4 (1) reacts with aniline, pyridine, and trimethyl phosphite. The reaction with aniline affords the dihydride…”
Get full text
Journal Article -
7
Preparation and Full Characterization of a Tetrahydride-bis(stannyl)-osmium(VI) Derivative
Published in Organometallics (15-03-2004)“…The dihydride-dichloro complex OsH2Cl2(PiPr3)2 (1) reacts with 4.0 equiv of HSnPh3 to afford 2.0 equiv of ClSnPh3 and the tetrahydride-bis(stannyl)-osmium(VI)…”
Get full text
Journal Article -
8
"Blind" protected specimen brushing versus bronchoscopic techniques in the aetiolological diagnosis of ventilator-associated pneumonia
Published in The European respiratory journal (01-07-1996)“…The aetiological diagnosis of nosocomial pneumonia in intensive care unit (ICU) patients requires a valid, cheap and safe method. This method should be…”
Get full text
Journal Article -
9
Preparation and Characterization of Osmium−Stannyl Polyhydrides: d 4 −d 2 Oxidative Addition of Neutral Molecules in a Late Transition Metal
Published in Organometallics (01-05-2003)Get full text
Journal Article -
10
The Dihydride−Osmium(IV) Complex [OsH 2 ( κ 2 -O 2 CCH 3 )(H 2 O)(P i Pr 3 ) 2 ]BF 4 as a Precursor for Carbon−Carbon Coupling Reactions
Published in Organometallics (01-11-2000)Get full text
Journal Article -
11
The problem of axillary adenopathies in the treatment of breast cancer
Published in Medicina clínica (10-09-1983)Get more information
Journal Article -
12
Gastric volvulus
Published in Revista espanola de las enfermedades del aparato digestivo (01-01-1984)Get more information
Journal Article