Search Results - "TWIEG, Robert J."
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Photocyclodehydrofluorination
Published in Chemistry : a European journal (26-10-2015)“…Mallory‐type photocyclization involves a series of photoreactions of stilbenes, o‐terphenyls and related derivatives, which undergo intramolecular cyclization…”
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Three-dimensional, single-molecule fluorescence imaging beyond the diffraction limit by using a double-helix point spread function
Published in Proceedings of the National Academy of Sciences - PNAS (03-03-2009)“…We demonstrate single-molecule fluorescence imaging beyond the optical diffraction limit in 3 dimensions with a wide-field microscope that exhibits a…”
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3
Redox‐Triggered Orientational Responses of Liquid Crystals to Chlorine Gas
Published in Angewandte Chemie (International ed.) (26-07-2018)“…Surface‐supported liquid crystals (LCs) that exhibit orientational and thus optical responses upon exposure to ppb concentrations of Cl2 gas are reported…”
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4
Three-dimensional superresolution colocalization of intracellular protein superstructures and the cell surface in live Caulobacter crescentus
Published in Proceedings of the National Academy of Sciences - PNAS (15-11-2011)“…Recently, single-molecule imaging and photocontrol have enabled superresolution optical microscopy of cellular structures beyond Abbe’s diffraction limit,…”
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5
A Photoactivatable Push−Pull Fluorophore for Single-Molecule Imaging in Live Cells
Published in Journal of the American Chemical Society (23-07-2008)“…We have reengineered a red-emitting dicyanomethylenedihydrofuran push−pull fluorophore so that it is dark until photoactivated with a short burst of…”
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6
Enhancing charge mobilities in organic semiconductors by selective fluorination: a design approach based on a quantum mechanical perspective
Published in Chemical science (Cambridge) (01-10-2017)“…Selective fluorination of organic semiconducting molecules is proposed as a means to achieving enhanced hole mobility. Naphthalene is examined here as a root…”
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Synthesis and Characterization of Novel Bio-Chiral Dopants Obtained from Bio-Betulin Produced by a Fermentation Process
Published in Crystals (Basel) (01-07-2021)“…Cholesteric liquid crystals are frequently produced by the addition of chiral dopants to achiral nematic hosts. We report here the synthesis and performance of…”
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Bright, Red Single-Molecule Emitters: Synthesis and Properties of Environmentally Sensitive Dicyanomethylenedihydrofuran (DCDHF) Fluorophores with Bisaromatic Conjugation
Published in Chemistry of materials (10-03-2009)“…A group of new fluorescent dye materials for single-molecule imaging applications, comprised of an amine donor, a π-system consisting of phenyl and thiophene…”
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Photophysical Properties of Acene DCDHF Fluorophores: Long-Wavelength Single-Molecule Emitters Designed for Cellular Imaging
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (20-09-2007)“…We report the solvatochromic, viscosity-sensitive, and single-molecule photophysics of the fluorophores DCDHF-N-6 and DCDHF-A-6. These molecules are members of…”
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10
Synthesis and Characterization of New Truxenones for Nonlinear Optical Applications
Published in Chemistry of materials (05-09-2006)“…The synthesis of several new truxenones and one tris(dicyanomethylene) derivative substituted by different amines at positions 4, 9, and 14 is reported. A…”
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Liquid Crystals with Interfacial Ordering that Enhances Responsiveness to Chemical Targets
Published in Advanced materials (Weinheim) (01-07-2018)“…The development of stimuli‐responsive materials suitable for use in wearable sensors is a key unresolved challenge. Liquid crystals (LCs) are particularly…”
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12
Nonlinear Optical Chromophores as Nanoscale Emitters for Single-Molecule Spectroscopy
Published in Accounts of chemical research (01-07-2005)“…Fluorescence imaging of single molecules at room temperature is a powerful technique for studying complex condensed phase systems and revealing structure and…”
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13
Multiple ferroelectric nematic phases of a highly polar liquid crystal compound
Published in Liquid crystals (21-10-2022)“…Ferroelectric nematic liquid crystals represent not only fascinating, fundamental science, but they also hold promise for new technologies including…”
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14
Small-Molecule Labeling of Live Cell Surfaces for Three-Dimensional Super-Resolution Microscopy
Published in Journal of the American Chemical Society (08-10-2014)“…Precise imaging of the cell surface of fluorescently labeled bacteria requires super-resolution methods because the size-scale of these cells is on the order…”
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15
Dispersion of Third‐Harmonic Generation in Organic Cavity Polaritons
Published in Advanced optical materials (01-09-2019)“…Organic cavity polaritons are bosonic quasiparticles arising from the strong interaction between organic molecular excitons and photons within microcavities…”
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16
Actuating Liquid Crystals Rapidly and Reversibly by Using Chemical Catalysis
Published in Advanced materials (Weinheim) (01-06-2024)“…Microtubules and catalytic motor proteins underlie the microscale actuation of living materials, and they have been used in reconstituted systems to harness…”
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Computational Chemistry‐Guided Design of Selective Chemoresponsive Liquid Crystals Using Pyridine and Pyrimidine Functional Groups
Published in Advanced functional materials (28-03-2018)“…Computational chemistry‐guided designs of chemoresponsive liquid crystals (LCs) with pyridine or pyrimidine groups that bind to metal‐cation‐functionalized…”
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Diffusion of Lipid-like Single-Molecule Fluorophores in the Cell Membrane
Published in The journal of physical chemistry. B (20-04-2006)“…The dicyanomethylenedihydrofuran (DCDHF) class of single-molecule fluorophores contains an amine donor and a dicyanomethylenedihydrofuran acceptor linked by a…”
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Diphenyl-1,3,4-oxadiazoles: synthesis and influence of side chain semifluorination and lateral ring fluorination on liquid crystalline properties
Published in Molecular Crystals and Liquid Crystals (01-06-2022)“…We present the synthesis and liquid crystalline properties of four sets of diphenyl-1,3,4-oxadiazole based compounds (Sets 1-4). The influence of side chain…”
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Minimalist columnar liquid crystals: influence of fluorination on the mesogenic behavior of tetramethoxytriphenylene derivatives
Published in Materials advances (11-11-2024)“…Conventional columnar liquid crystals are almost invariably functionalized with multiple long aliphatic tails. In contrast, the molecule…”
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