Search Results - "Többens, Daniel"
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The phase diagram of a mixed halide (Br, I) hybrid perovskite obtained by synchrotron X-ray diffraction
Published in RSC advances (09-04-2019)“…By using synchrotron X-ray powder diffraction, the temperature dependent phase diagram of the hybrid perovskite tri-halide compounds, methyl ammonium lead…”
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20.8% Slot‐Die Coated MAPbI3 Perovskite Solar Cells by Optimal DMSO‐Content and Age of 2‐ME Based Precursor Inks
Published in Advanced energy materials (01-03-2021)“…Solar cells incorporating metal‐halide perovskite (MHP) semiconductors are continuing to break efficiency records for solution‐processed solar cell devices…”
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Compositional and Interfacial Engineering Yield High-Performance and Stable p‑i‑n Perovskite Solar Cells and Mini-Modules
Published in ACS applied materials & interfaces (24-03-2021)“…Through the optimization of the perovskite precursor composition and interfaces to selective contacts, we achieved a p-i-n-type perovskite solar cell (PSC)…”
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4
Experimental Evidence of Confined Methane Hydrate in Hydrophilic and Hydrophobic Model Carbons
Published in Journal of physical chemistry. C (03-10-2019)“…Methane hydrate confined in porous materials is postulated as an alternative energy storage strategy. By applying model carbons with ordered and uniformly…”
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Infrared Spectroscopic Study of Vibrational Modes across the Orthorhombic–Tetragonal Phase Transition in Methylammonium Lead Halide Single Crystals
Published in Journal of physical chemistry. C (15-03-2018)“…Single crystals of the methylammonium (MA) lead halides MAPbI3, MAPbBr3, and MAPbCl3 have been investigated using infrared spectroscopy with the aim of…”
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Cooperative light-induced breathing of soft porous crystals via azobenzene buckling
Published in Nature communications (12-04-2022)“…Although light is a prominent stimulus for smart materials, the application of photoswitches as light-responsive triggers for phase transitions of porous…”
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Br-Induced Suppression of Low-Temperature Phase Transitions in Mixed-Cation Mixed-Halide Perovskites
Published in Chemistry of materials (22-10-2024)“…Mixed-cation mixed-halide lead perovskites have been shown to be excellent candidates for solar energy conversion. However, understanding the structural phases…”
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The effect of crystallite size on pressure amplification in switchable porous solids
Published in Nature communications (20-04-2018)“…Negative gas adsorption (NGA) in ordered mesoporous solids is associated with giant contractive structural transitions traversing through metastable states…”
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Charge-transfer crystallites as molecular electrical dopants
Published in Nature communications (06-10-2015)“…Ground-state integer charge transfer is commonly regarded as the basic mechanism of molecular electrical doping in both, conjugated polymers and oligomers…”
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Indium‐Free Perovskite Solar Cells Enabled by Impermeable Tin‐Oxide Electron Extraction Layers
Published in Advanced materials (Weinheim) (01-07-2017)“…Corrosive precursors used for the preparation of organic–inorganic hybrid perovskite photoactive layers prevent the application of ultrathin metal layers as…”
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Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
Published in Nature communications (12-08-2019)“…Switchable metal-organic frameworks (MOFs) have been proposed for various energy-related storage and separation applications, but the mechanistic understanding…”
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Temperature-Dependent EXAFS Measurements of the Pb L3-Edge Allow Quantification of the Anharmonicity of the Lead–Halide Bond of Chlorine-Substituted Methylammonium (MA) Lead Triiodide
Published in Journal of physical chemistry. C (31-03-2022)“…This article reports on studies of chlorine-substituted MAPbI3 using combined temperature-dependent X-ray diffraction (XRD) synchrotron and Pb-L3 edge extended…”
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13
Massive Pressure Amplification by Stimulated Contraction of Mesoporous Frameworks
Published in Angewandte Chemie International Edition (17-05-2021)“…Herein we demonstrate mesoporous frameworks interacting with carbon dioxide leading to stimulated structural contractions and massive out‐of‐equilibrium…”
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Ink Design Enabling Slot‐Die Coated Perovskite Solar Cells with >22% Power Conversion Efficiency, Micro‐Modules, and 1 Year of Outdoor Performance Evaluation
Published in Advanced energy materials (01-09-2023)“…The next technological step in the exploration of metal‐halide perovskite solar cells is the demonstration of larger‐area device prototypes under outdoor…”
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Cu/Zn disorder in stoichiometric Cu2ZnSn(S1-xSex)4 semiconductors: A complementary neutron and anomalous X-ray diffraction study
Published in Journal of alloys and compounds (15-12-2020)“…The quaternary compound semiconductor Cu2ZnSn(S1-xSex)4 (CZTSSe) which crystallizes in the kesterite-type structure, is a promising material to be used as…”
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16
Lattice instability and competing spin structures in the double perovskite insulator Sr2FeOsO6
Published in Physical review letters (18-10-2013)“…The semiconductor Sr2FeOsO6, depending on temperature, adopts two types of spin structures that differ in the spin sequence of ferrimagnetic iron-osmium layers…”
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Thickness dependence of the electro-mechanical response of sputter-deposited Mo thin films on polyimide: Insights from in situ synchrotron diffraction tensile tests
Published in Materials science & engineering. A, Structural materials : properties, microstructure and processing (14-06-2017)“…The in situ characterization of the deformation and fracture behavior of brittle metal films is of great technological interest for many modern applications. A…”
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In Situ Observation of Gating Phenomena in the Flexible Porous Coordination Polymer Zn2(BPnDC)2(bpy) (SNU-9) in a Combined Diffraction and Gas Adsorption Experiment
Published in Inorganic chemistry (03-02-2014)“…The intrinsic structural dynamic during the adsorption of CO2 at 195 K and N2 at 77 K on flexible porous coordination polymer Zn2(BPnDC)2(bpy) (SNU-9) was…”
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The influence of deuteration on the crystal structure of hybrid halide perovskites: a temperature‐dependent neutron diffraction study of FAPbBr3
Published in Acta crystallographica Section B, Structural science, crystal engineering and materials (01-04-2020)“…This paper discusses the full structural solution of the hybrid perovskite formamidinium lead tribromide (FAPbBr3) and its temperature‐dependent phase…”
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Engineering micromechanics of soft porous crystals for negative gas adsorption
Published in Chemical science (Cambridge) (24-08-2020)“…Framework materials at the molecular level, such as metal-organic frameworks (MOF), were recently found to exhibit exotic and counterintuitive micromechanical…”
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