Search Results - "Sweeny, Brendan C"
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Surface Plasmon-Driven Water Reduction: Gold Nanoparticle Size Matters
Published in Journal of the American Chemical Society (16-07-2014)“…Water reduction under two different visible-light ranges (λ > 400 nm and λ > 435 nm) was investigated in gold-loaded titanium dioxide (Au-TiO2)…”
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Inconsistent kinetic isotope effect in ammonia charge exchange reaction measured in a Coulomb crystal and in a selected-ion flow tube
Published in Nature communications (09-06-2022)Get full text
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Prolonged Hot Electron Dynamics in Plasmonic-Metal/Semiconductor Heterostructures with Implications for Solar Photocatalysis
Published in Angewandte Chemie International Edition (21-07-2014)“…Ideal solar‐to‐fuel photocatalysts must effectively harvest sunlight to generate significant quantities of long‐lived charge carriers necessary for chemical…”
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Reaction of Mass-Selected, Thermalized V nO m+ Clusters with CCl4
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (13-06-2019)“…The kinetics of V nO m+ + CCl4 ( n, m = 2, 5; 3, 6-8; 4, 9-11; 5, 12-13) have been measured under thermal conditions using a selected-ion flow tube equipped…”
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A Common Bottleneck for Metal Oxidation by Molecular Oxygen Across Size Regimes: Kinetics of Atomic Lanthanide Cations (La+–Lu+) with O2
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-07-2024)“…Kinetics of the lanthanide cations (Ln+ = La+–Lu+ excluding Pm +) reacting with molecular oxygen were measured in a selected-ion flow tube apparatus from 300…”
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A Common Bottleneck for Metal Oxidation by Molecular Oxygen Across Size Regimes: Kinetics of Atomic Lanthanide Cations (La + -Lu + ) with O 2
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-07-2024)“…Kinetics of the lanthanide cations (Ln = La -Lu excluding ) reacting with molecular oxygen were measured in a selected-ion flow tube apparatus from 300 to 600…”
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Electron withdrawing ligands inhibit oxygen transport by Al+: temperature-dependent kinetics of AlO+/(O2)AlO+ + H2/CH4
Published in Molecular physics (17-01-2024)“…Al + has been shown to enable the oxygen atom transfer (OAT) to convert methane to methanol at thermal energies through a unique, barrierless mechanism…”
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Temperature-Dependent Kinetics for the Reactions of Fe n - ( n = 2-17) and Fe x Ni y - ( x + y = 3-9) with O 2 : Comparison of Pure and Mixed Metal Clusters with Relevance to Meteor Radio Afterglows and Surface Oxidation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-01-2024)“…Rate constants and product branching fractions were measured from 300-600 K for Fe + O ( = 2-17) and for 300-500 K for Fe Ni + O ( + = 3-9) using a…”
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Temperature-Dependent Kinetics for the Reactions of Fen- (n = 2-17) and FexNiy- (x + y = 3-9) with O2: Comparison of Pure and Mixed Metal Clusters with Relevance to Meteor Radio Afterglows and Surface Oxidation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-01-2024)“…Rate constants and product branching fractions were measured from 300-600 K for Fen- + O2 (n = 2-17) and for 300-500 K for FexNiy- + O2 (x + y = 3-9) using a…”
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Cyclotrimerization of Acetylene under Thermal Conditions: Gas-Phase Kinetics of V+ and Fe+ + C2H2
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (28-10-2021)“…The kinetics of successive reactions of acetylene (C2H2) initiated on either vanadium or iron atomic cations have been investigated under thermal conditions…”
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Activation of Methane by Zr+: A Deep-Dive into the Potential Surface via Pressure- and Temperature-Dependent Kinetics with Statistical Modeling
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-03-2023)“…The kinetics of Zr+ + CH4 are measured using a selected-ion flow tube apparatus over the temperature range 300–600 K and the pressure range 0.25–0.60 Torr…”
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Gas-Phase Reactivity of Ozone with Lanthanide Ions (Sm+, Nd+) and Their Higher Oxides
Published in Journal of the American Society for Mass Spectrometry (03-08-2022)“…The kinetics of SmO n + (n = 0–2) and NdO n + (n = 0–2) with O3 are measured using a selected-ion flow tube. Reaction of Nd+ to yield NdO+ + O2 occurs rapidly,…”
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Structures and Electron Affinities of Aluminum Hydride Clusters Al n H (n = 3–13)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-03-2022)“…Low-energy structures and electron affinities (EAs) for aluminum hydride clusters Al n H (n = 3–13) have been calculated using ab initio and density functional…”
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Gas-Phase Anionic Metal Clusters are Model Systems for Surface Oxidation: Kinetics of the Reactions of M n - with O 2 (M = V, Cr, Co, Ni; n = 1-15)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-03-2021)“…The reactions of anionic metal clusters with O (M = V ( = 1-15), Cr ( = 1-15), Co ( = 1-12), and Ni ( = 1-14)) are investigated from 300 to 600 K using a…”
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Methane Adducts of Gold Dimer Cations: Thermochemistry and Structure from Collision-Induced Dissociation and Association Kinetics
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (30-04-2020)“…The bond dissociation energies at 0 K (BDE) of Au2 +–CH4 and Au2CH4 +–CH4 have been determined using two separate experimental methods. Analyses of…”
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Effect of Intersystem Crossings on the Kinetics of Thermal Ion-Molecule Reactions: Ti + + O 2 , CO 2 , and N 2 O
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-02-2022)“…A selected-ion flow tube apparatus has been used to measure rate constants and product branching fractions of Ti reacting with O , CO , and N O over the range…”
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Kinetics of O3 with Ca+ and Its Higher Oxides CaOn+ (n = 1-3) and Updates to a Model of Meteoric Calcium in the Mesosphere and Lower Thermosphere
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (11-05-2023)Get full text
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