Search Results - "Sun, Taoxiang"
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Selective Separation and Complexation of Trivalent Actinide and Lanthanide by a Tetradentate Soft–Hard Donor Ligand: Solvent Extraction, Spectroscopy, and DFT Calculations
Published in Inorganic chemistry (01-04-2019)“…Recently, phenanthroline-based ligands have received increasing attention due to their excellent separation capabilities for trivalent actinides over…”
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Visualization of Adsorption: Luminescent Mesoporous Silica-Carbon Dots Composite for Rapid and Selective Removal of U(VI) and in Situ Monitoring the Adsorption Behavior
Published in ACS applied materials & interfaces (01-03-2017)“…The removal and separation of uranium from aqueous solutions are quite important for resource reclamation and environmental protection. Being one of the most…”
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Improvement of the cloud point extraction of uranyl ions by the addition of ionic liquids
Published in Journal of hazardous materials (15-12-2013)“…•CnmimNTf2 improves cloud point extraction of UO22+ with neutral extractant.•The extraction efficiency keeps high at both nearly neutral and acidic…”
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Involvement of 5f Orbitals in the Covalent Bonding between the Uranyl Ion and Trialkyl Phosphine Oxide: Unraveled by Oxygen K‑Edge X‑ray Absorption Spectroscopy and Density Functional Theory
Published in Inorganic chemistry (10-01-2022)“…Monodentate organophosphorus ligands have been used for the extraction of the uranyl ion (UO2 2+) for over half a century and have exhibited exceptional…”
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Covalency between the uranyl ion and dithiophosphinate by sulfur K‐edge X‐ray absorption spectroscopy and density functional theory
Published in Journal of synchrotron radiation (01-01-2022)“…The dithiophosphinic acids (HS2PR2) have been used for the selective separation of trivalent actinides (AnIII) from lanthanides (LnIII) over the past decades…”
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Structure and aggregation behavior of pertechnetate/perrhenate in organic phase in the extraction by tributyl phosphate
Published in Journal of radioanalytical and nuclear chemistry (01-06-2023)“…The extraction of pertechnetate (TcO 4 − ) and perrhenate (ReO 4 − ) by tributyl phosphate (TBP) has been extensively studied, but the structure of the…”
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Quantum Chemistry Study on the Extraction of Trivalent Lanthanide Series by Cyanex301: Insights from Formation of Inner- and Outer-Sphere Complexes
Published in ACS omega (30-04-2018)“…The extraction of lanthanide series by Cyanex301, i.e., bis(2,4,4-trimethylpentyl)dithiophosphinic acid (HC301), has been modeled by density functional…”
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Crystallization of cesium complex containing bis(2-propyloxy)calix[4]crown-6 and bis[(trifluoromethyl)sulfonyl]imide
Published in Inorganica Chimica Acta (15-07-2012)“…To provide an insight into the extraction mechanism in ionic liquids systems, a complex of Cs+ with a calixcrown bis(2-propyloxy)calix[4]crown-6 (BPC6) and…”
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A further understanding of the cation exchange mechanism for the extraction of Sr2+ and Cs+ by ionic liquid
Published in Science China. Chemistry (01-06-2013)“…The cation exchange mechanism was further investigated during the extraction of Sr2+ and Cs+ using the extractant dicyclo- hexano-18-crown-6 (DCH18C6) in an…”
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10
Performance and Mechanism of Uranium Adsorption from Seawater to Poly(dopamine)-Inspired Sorbents
Published in Environmental science & technology (18-04-2017)“…Developing facile and robust technologies for effective enrichment of uranium from seawater is of great significance for resource sustainability and…”
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Effects of the Structure, Operation, and Physical Parameters on the Actual Phase Ratio and Interface Radius in the Separation Zone of an Annular Centrifugal Contactor
Published in Industrial & engineering chemistry research (11-01-2023)“…The annular centrifugal contactor (ACC) is highly efficient solvent extraction equipment and has been successfully used in many industrial fields. The phase…”
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12
Interactions of Bis(2,4,4-trimethylpentyl)dithiophosphinate with Trivalent Lanthanides in a Homogeneous Medium: Thermodynamics and Coordination Modes
Published in Inorganic chemistry (06-03-2017)“…Complexation of trivalent lanthanides with a sulfur-bearing ligand, bis(2,4,4-trimethylpentyl) dithiophosphinate, was studied in ethanol under identical…”
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13
Microplasma electrochemistry controlled rapid preparation of fluorescent polydopamine nanoparticles and their application in uranium detection
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-07-2018)“…With the assistant of microplasma anode, the uniform fluorescent polydopamine nanoparticles (FPD) could be prepared continuously and the FPD can be applied for…”
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Substituent Effect on the Selective Separation and Complexation of Trivalent Americium and Lanthanides by N,O-Hybrid 2,9-Diamide-1,10-phenanthroline Ligands in Ionic Liquid
Published in Inorganic chemistry (05-04-2021)“…The extraction and complexation of trivalent americium (Am) and lanthanides (Ln) by four 2,9-diamide-1,10-phenanthroline (DAPhen) ligands with different alkyl…”
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Performance and Mechanism for the Selective Separation of Trivalent Americium from Lanthanides by a Tetradentate Phenanthroline Ligand in Ionic Liquid
Published in Inorganic chemistry (16-03-2020)“…The selective separation of trivalent americium from lanthanides in a nitric acid medium by a tetradentate ligand,…”
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Evolution of the chemical form of zirconium in aqueous solution during denitration and its influence on extraction by TRPO
Published in Separation and purification technology (15-01-2024)“…Zr(IV) is present in solutions with different forms such as the tetramers of Zr4(OH)8(NO3)8 and Zr4(OH)8(HCOO)8 and their aggregates, depending on the…”
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Are 4f-Orbitals Engaged in Covalent Bonding Between Lanthanides and Triphenylphosphine Oxide? An Oxygen K‑Edge X‑ray Absorption Spectroscopy and Density Functional Theory Study
Published in Inorganic chemistry (05-02-2024)“…The bonding covalency between trivalent lanthanides (Ln = La, Pr, Nd, Eu, Gd) and triphenylphosphine oxide (TPPO) is studied by X-ray absorption spectra (XAS)…”
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Thermodynamic Insight into the Solvation and Complexation Behavior of U(VI) in Ionic Liquid: Binding of CMPO with U(VI) Studied by Optical Spectroscopy and Calorimetry
Published in Inorganic chemistry (06-03-2017)“…The complexation of U(VI) with octylphenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO, denoted as L) in ionic liquid (IL) C4mimNTf2 was investigated…”
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Synthesis, Structure, and Theoretical Calculations on NpO2Br4 2
Published in Inorganic chemistry (28-08-2023)“…The actinide–halogen complexes (AnO2X4 2–, X = Cl, Br, and I) are the simplest and most representative compounds for studying the bonding nature of actinides…”
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Synthesis, Structure, and Theoretical Calculations on NpO 2 Br 4 2
Published in Inorganic chemistry (28-08-2023)Get full text
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