Search Results - "Sukulova, V.V."

Kinetic features of ethylene copolymerization with 1-hexene over titanium-magnesium Ziegler–Natta catalysts: Effect of comonomer on the number of active centers and the propagation rate constant by Sukulova, V.V., Barabanov, A.A., Matsko, M.A., Zakharov, V.A., Mikenas, T.B.

“…[Display omitted] •Comonomer effect was studied based on the data on the active sites number.•The number of active sites remains constant at comonomer…”
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Propylene Polymerization over Titanium-Magnesium Catalyst: Effect of Hydrogen on the Content of Active Centers with Different Stereospecificity and Their Reactivity in Propagation Reaction by Sukulova, V.V., Barabanov, A.A., Matsko, M.A., Zakharov, V.A.

“…[Display omitted] •The number of active centers (CPi) with different stereospecificity was found.•Propagation rate constants for such centers (kPi) were…”
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The Kinetic Study of Ethylene Polymerization over Titanium–Magnesium Catalysts in the Presence of Hydrogen: The Number and Reactivity of Active Centers by Sukulova, V. V., Barabanov, A. A., Mikenas, T. B., Matsko, M. A., Zakharov, V. A.

“…Using the inhibition of polymerization by radioactive carbon monoxide 14 СО, the effect of hydrogen (chain transfer agent) on the number of active centers and…”
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Effect of hydrogen on the number of active centers and the propagation rate constant at ethylene polymerization over titanium-magnesium Ziegler-Natta catalysts by Sukulova, V.V., Barabanov, A.A., Mikenas, T.B., Matsko, M.A., Zakharov, V.A.

“…[Display omitted] •Addition of hydrogen reduces the polymerization rate by decreasing the calculated propagation rate constant.•The propagation rate constant…”
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