Search Results - "Suarez, Jorge Meijide"
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Confinement of Metal–N‐Heterocyclic Carbene Complexes to Control Reactivity in Catalytic Reactions
Published in Chemistry : a European journal (27-08-2018)“…Confinement of a metal complex is a promising way to induce reactivity modulation and selectivity. Combining this principle with the properties of…”
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Cyclodextrin Cavity‐Induced Mechanistic Switch in Copper‐Catalyzed Hydroboration
Published in Angewandte Chemie International Edition (28-08-2017)“…N‐heterocyclic carbene‐capped cyclodextrin (ICyD) ligands, α‐ICyD and β‐ICyD derived from α‐ and β‐cyclodextrin, respectively give opposite regioselectivities…”
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β‑Cyclodextrin–NHC–Gold(I) Complex (β-ICyD)AuCl: A Chiral Nanoreactor for Enantioselective and Substrate-Selective Alkoxycyclization Reactions
Published in ACS catalysis (05-06-2020)“…NHC-capped β-cyclodextrin (β-ICyD) was used as a ligand for gold-catalyzed alkoxycyclization reactions. The cavity was found to be responsible for a triple…”
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Frontispiece: Confinement of Metal–N‐Heterocyclic Carbene Complexes to Control Reactivity in Catalytic Reactions
Published in Chemistry : a European journal (27-08-2018)“…Caging N‐heterocyclic carbene (NHC)–metal complexes in molecular or polymeric structures can confer them with interesting properties. In their Minireview on…”
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A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes
Published in Nature chemistry (01-02-2022)“…Rotaxanes can display molecular chirality solely due to the mechanical bond between the axle and encircling macrocycle without the presence of covalent…”
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Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond
Published in Nature reviews. Chemistry (01-03-2022)“…Mechanically interlocked molecules, such as rotaxanes and catenanes, are receiving increased attention as scaffolds for the development of new catalysts,…”
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Cavity‐Controlled Coordination of Square Planar Metal Complexes and Substrate Selectivity by NHC‐Capped Cyclodextrins (ICyDs)
Published in ChemCatChem (10-01-2022)“…Encapsulation of a metal center inside the cavity of a cyclodextrin (CD) allows the control of the possible coordination modes for the metal depending on the…”
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Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones
Published in Angewandte Chemie International Edition (04-05-2020)“…The encapsulation of copper inside a cyclodextrin capped with an N‐heterocyclic carbene (ICyD) allowed both to catch the elusive monomeric (L)CuH and a…”
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Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones
Published in Angewandte Chemie (04-05-2020)“…The encapsulation of copper inside a cyclodextrin capped with an N‐heterocyclic carbene (ICyD) allowed both to catch the elusive monomeric (L)CuH and a…”
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Author Correction: A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes
Published in Nature chemistry (01-02-2022)Get full text
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Cyclodextrin Cavity‐Induced Mechanistic Switch in Copper‐Catalyzed Hydroboration
Published in Angewandte Chemie (28-08-2017)“…N‐heterocyclic carbene‐capped cyclodextrin (ICyD) ligands, α‐ICyD and β‐ICyD derived from α‐ and β‐cyclodextrin, respectively give opposite regioselectivities…”
Get full text
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