Search Results - "Studer, Armido"

A "Renaissance" in Radical Trifluoromethylation by Studer, Armido

“…This Minireview highlights recent developments in radical trifluoromethylation reactions. The trifluoromethyl group belongs to the privileged moieties in…”
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The Persistent Radical Effect in Organic Synthesis by Leifert, Dirk, Studer, Armido

“…Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the selective cross‐coupling of two different radicals is challenging…”
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Recent advances in the synthesis of nitrogen heterocycles via radical cascade reactions using isonitriles as radical acceptors by Zhang, Bo, Studer, Armido

“…Nitrogen heterocycles belong to a highly important class of compounds which are found in various natural products, biologically active structures, and…”
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Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration by Tang, Xinjun, Studer, Armido

“…Transition‐metal‐free radical α‐perfluoroalkylation with the accompanying vicinal β‐alkenylation of unactivated alkenes is presented. These radical cascades…”
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Catalysis of Radical Reactions: A Radical Chemistry Perspective by Studer, Armido, Curran, Dennis P.

“…The area of catalysis of radical reactions has recently flourished. Various reaction conditions have been discovered and explained in terms of catalytic…”
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Nitroxides: Applications in Synthesis and in Polymer Chemistry by Tebben, Ludger, Studer, Armido

“…This Review describes the application of nitroxides to synthesis and polymer chemistry. The synthesis and physical properties of nitroxides are discussed…”
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Benzylic C−H acylation by cooperative NHC and photoredox catalysis by Meng, Qing-Yuan, Lezius, Lena, Studer, Armido

“…Methods that enable site selective acylation of sp 3 C-H bonds in complex organic molecules are not well explored, particularly if compared with analogous…”
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Decatungstate-catalyzed radical disulfuration through direct C-H functionalization for the preparation of unsymmetrical disulfides by Zhang, Jingjing, Studer, Armido

“…Unsymmetrical disulfides are widely found in the areas of food chemistry, pharmaceutical industry, chemical biology and polymer science. Due the importance of…”
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Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes by Li, Yi, Studer, Armido

“…No transition metal! Fluorinated hypervalent‐iodine reagents react with TEMPONa in the presence of an alkene under mild conditions to give the corresponding…”
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Deoxygenative Borylation of Secondary and Tertiary Alcohols by Friese, Florian W., Studer, Armido

“…Two different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed…”
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Transition‐Metal‐Free Oxidative Cross‐Coupling of Tetraarylborates to Biaryls Using Organic Oxidants by Gerleve, Carolin, Studer, Armido

“…Readily prepared tetraarylborates undergo selective (cross)‐coupling through oxidation with Bobbitt's salt to give symmetric and unsymmetric biaryls. The…”
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Diversity‐Oriented Desulfonylative Functionalization of Alkyl Allyl Sulfones by Xia, Yong, Studer, Armido

“…The diversity‐oriented desulfonylative functionalization of alkyl allyl sulfones with various sulfone‐type reagents by radical chemistry has been developed…”
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Site‐Selective Remote Radical C−H Functionalization of Unactivated C−H Bonds in Amides Using Sulfone Reagents by Xia, Yong, Wang, Lin, Studer, Armido

“…A general and practical strategy for remote site‐selective functionalization of unactivated aliphatic C−H bonds in various amides by radical chemistry is…”
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Visible‐Light Mediated Tryptophan Modification in Oligopeptides Employing Acylsilanes by Reimler, Jannik, Studer, Armido

“…A method for the selective tryptophan modification and labelling of tryptophan‐containing peptides is described. Photoirradiation of acylsilanes generates…”
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6‑Perfluoroalkylated Phenanthridines via Radical Perfluoroalkylation of Isonitriles by Zhang, Bo, Studer, Armido

“…A simple and efficient approach to 6-perfluoroalkylated phenanthridines starting with readily prepared isonitriles and commercially available cheap…”
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2‑Trifluoromethylated Indoles via Radical Trifluoromethylation of Isonitriles by Zhang, Bo, Studer, Armido

“…Either two or three C–C bonds are formed in the synthesis of 2-trifluoromethylindoles starting with readily prepared isonitriles and the Togni reagent as CF3…”
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Metal‐Free Radical Borylation of Alkyl and Aryl Iodides by Cheng, Ying, Mück‐Lichtenfeld, Christian, Studer, Armido

“…A metal‐free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B2cat2) as the boron source under mild conditions is introduced. The…”
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Covalent‐Bond Formation via On‐Surface Chemistry by Held, Philipp Alexander, Fuchs, Harald, Studer, Armido

“…In this Review article pioneering work and recent achievements in the emerging research area of on‐surface chemistry is discussed. On‐surface chemistry,…”
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Oligosilanes as Silyl Radical Precursors through Oxidative Si−Si Bond Cleavage Using Redox Catalysis by Yu, Xiaoye, Lübbesmeyer, Maximilian, Studer, Armido

“…Oligosilanes are of great interest in the fields of organic photonics and electronics. In this communication, a highly efficient visible‐light‐mediated…”
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Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration by You, Cai, Studer, Armido

“…A general and efficient approach for the preparation of 1,3‐bis‐(boryl)alkanes is introduced. It is shown that readily generated vinylboron ate complexes react…”
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