Search Results - "Struch, Niklas"
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Stepwise Construction of Heterobimetallic Cages by an Extended Molecular Library Approach
Published in Inorganic chemistry (02-04-2018)“…Two novel heterobimetallic complexes, a trigonal-bipyramidal and a cubic one, have been synthesized and characterized using the same C 3-symmetric…”
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An Octanuclear Metallosupramolecular Cage Designed To Exhibit Spin‐Crossover Behavior
Published in Angewandte Chemie International Edition (24-04-2017)“…By employing the subcomponent self‐assembly approach utilizing 5,10,15,20‐tetrakis(4‐aminophenyl)porphyrin or its zinc(II) complex, 1H‐4‐imidazolecarbaldehyde,…”
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3
Influencing the Self‐Sorting Behavior of [2.2]Paracyclophane‐Based Ligands by Introducing Isostructural Binding Motifs
Published in Chemistry : a European journal (12-03-2020)“…Two isostructural ligands with either nitrile (Lnit) or isonitrile (Liso) moieties directly connected to a [2.2]paracyclophane backbone with pseudo‐meta…”
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4
Diastereoselective Formation of Homochiral Helicates through Subcomponent Self‐Assembly
Published in European journal of organic chemistry (08-09-2017)“…Homochiral helicates were prepared through subcomponent self‐assembly with a C2‐symmetric chiral building block based on a 6,6′‐substituted 1,1′‐bi‐2‐naphthol…”
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5
Self-Sorting Effects in the Self-Assembly of Metallosupramolecular Rhombi from Chiral BINOL-Derived Bis(pyridine) Ligands
Published in European journal of organic chemistry (01-01-2014)“…Four BINOL‐based bis(4‐pyridyl) ligands were synthesised in enantiopure and racemic form. These ligands form metallosupramolecular [(dppp)2M2L2] rhombi with…”
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6
Dynamic Complex‐to‐Complex Transformations of Heterobimetallic Systems Influence the Cage Structure or Spin State of Iron(II) Ions
Published in Angewandte Chemie International Edition (17-02-2020)“…Two new heterobimetallic cages, a trigonal‐bipyramidal and a cubic one, were assembled from the same mononuclear metalloligand by adopting the molecular…”
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7
A Family of Heterobimetallic Cubes Shows Spin‐Crossover Behaviour Near Room Temperature
Published in Angewandte Chemie International Edition (04-10-2021)“…Using 4‐(4′‐pyridyl)aniline as a simple organic building block in combination with three different aldehyde components together with metal(II) salts gave three…”
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8
Subcomponent self-assembly of circular helical Dy6(L)6 and bipyramid Dy12(L)8 architectures directed via second-order template effects
Published in Chemical science (Cambridge) (31-08-2022)“…In situ metal-templated (hydrazone) condensation also called subcomponent self-assembly of 4,6-dihydrazino-pyrimidine, o -vanillin and dysprosium ions resulted…”
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9
Influencing the Self-Sorting Behavior of 2.2Paracyclophane-Based Ligands by Introducing Isostructural Binding Motifs
Published in Chemistry : a European journal (12-03-2020)“…Two isostructural ligands with either nitrile (Lnit ) or isonitrile (Liso ) moieties directly connected to a [2.2]paracyclophane backbone with pseudo-meta…”
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10
Electron-Deficient Pyridylimines: Versatile Building Blocks for Functional Metallosupramolecular Chemistry
Published in Inorganic chemistry (02-01-2018)“…Metallosupramolecular systems heavily rely on the correct choice of ligands to obtain materials with desired properties. Engaging this problem, we present…”
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11
Enantiomerically Pure Trinuclear Helicates via Diastereoselective Self-Assembly and Characterization of Their Redox Chemistry
Published in Journal of the American Chemical Society (20-08-2014)“…A tris(bipyridine) ligand 1 with two BINOL (BINOL = 2,2′-dihydroxy-1,1′-binaphthyl) groups has been prepared in two enantiomerically pure forms. This ligand…”
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12
A Case Study of Mechanical Strain in Supramolecular Complexes to Manipulate the Spin State of Iron(II) Centres
Published in European journal of inorganic chemistry (01-11-2015)“…Two novel supramolecular meso‐helicates have been synthesized and characterized by single‐crystal X‐ray diffraction, variable‐temperature magnetic…”
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13
A novel crystal structure of {tris[4‐(1H‐pyrazol‐3‐yl‐κN2)‐3‐azabut‐3‐enyl]amine‐κN}iron(II) bis(tetrafluoridoborate) methanol monosolvate featuring a low‐spin configuration
Published in Acta crystallographica. Section C, Crystal structure communications (01-12-2015)“…Mononuclear complexes are good model systems for evaluating the effects of different ligand systems on the magnetic properties of iron(II) centres. A novel…”
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14
Frontispiece: An Octanuclear Metallosupramolecular Cage Designed To Exhibit Spin‐Crossover Behavior
Published in Angewandte Chemie International Edition (24-04-2017)“…Metallosupramolecular ChemistryThe synthesis and properties of a supramolecular octanuclear cage exhibiting spin‐crossover behavior in solution are…”
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15
Eine Familie von Heterobimetallischen Würfeln zeigt Spin‐Crossover‐Verhalten nahe Raumtemperatur
Published in Angewandte Chemie (04-10-2021)“…Durch die Verwendung von 4‐(4′‐Pyridyl)anilin als einfachen organischen Baustein in Kombination mit drei verschiedenen Aldehydkomponenten und Metall(II)salzen…”
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16
Dynamische Komplex‐zu‐Komplex‐Umwandlungen von heterobimetallischen Systemen und ihr Einfluss auf die Käfigstruktur oder den Spinzustand von Eisen(II)‐Ionen
Published in Angewandte Chemie (17-02-2020)“…Ein trigonal‐bipyramidaler und ein kubischer heterobimetallischer Käfig wurden mit Eisen(II)‐ und Palladium(II)‐Bausteinen gemäß dem Molecular‐Library‐Ansatz…”
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17
Subcomponent self-assembly of circular helical and bipyramid architectures directed second-order template effects
Published in Chemical science (Cambridge) (31-08-2022)“…In situ metal-templated (hydrazone) condensation also called subcomponent self-assembly of 4,6-dihydrazino-pyrimidine, o -vanillin and dysprosium ions resulted…”
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18
Eine Familie von Heterobimetallischen Würfeln zeigt Spin‐Crossover‐Verhalten nahe Raumtemperatur
Published in Angewandte Chemie (04-10-2021)“…Abstract Durch die Verwendung von 4‐(4′‐Pyridyl)anilin als einfachen organischen Baustein in Kombination mit drei verschiedenen Aldehydkomponenten und…”
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19
Frontispiz: Ein achtkerniger metallosupramolekularer Würfel mit Spin‐Crossover‐Eigenschaften
Published in Angewandte Chemie (24-04-2017)“…Metallosupramolekulare ChemieA. Lützen und Mitarbeiter beschreiben in ihrer Zuschrift auf S. 5012 die Synthese und Eigenschaften eines achtkernigen…”
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20
Ein achtkerniger metallosupramolekularer Würfel mit Spin‐Crossover‐Eigenschaften
Published in Angewandte Chemie (24-04-2017)“…Nach dem Ansatz der Subkomponenten‐Selbstorganisation lassen sich aus 5,10,15,20‐Tetrakis(4‐aminophenyl)porphyrin oder dessen Zink(II)‐Komplex,…”
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