Search Results - "Straub, F."
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Advancements in the mechanistic understanding of the copper-catalyzed azide-alkyne cycloaddition
Published in Beilstein journal of organic chemistry (02-12-2013)“…The copper-catalyzed azide-alkyne cycloaddition (CuAAC) is one of the most broadly applicable and easy-to-handle reactions in the arsenal of organic chemistry…”
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In Situ Mass Spectrometric and Kinetic Investigations of Soai's Asymmetric Autocatalysis
Published in Chemistry : a European journal (04-12-2020)“…Chemical reactions that lead to a spontaneous symmetry breaking or amplification of the enantiomeric excess are of fundamental interest in explaining the…”
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A Fluxional Copper Acetylide Cluster in CuAAC Catalysis
Published in Angewandte Chemie International Edition (15-06-2015)“…A molecularly defined copper acetylide cluster with ancillary N‐heterocyclic carbene (NHC) ligands was prepared under acidic reaction conditions. This cluster…”
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Isolation of a Copper(I) Triazolide: A "Click" Intermediate
Published in Angewandte Chemie International Edition (01-01-2007)“…Click snapshot: In an aprotic medium, a copper(I) triazolide complex is synthesized from a sterically hindered copper acetylide and an organoazide (see scheme:…”
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5
Isolation of a Non-Heteroatom-Stabilized Gold-Carbene Complex
Published in Angewandte Chemie International Edition (25-08-2014)“…Gold–carbene complexes are essential intermediates in many gold‐catalyzed organic‐synthetic transformations. While gold–carbene complexes with direct,…”
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6
Origin of the High Activity of Second-Generation Grubbs Catalysts
Published in Angewandte Chemie International Edition (19-09-2005)“…Green light for alkene metathesis: A strong σ‐donor ligand L favors the active conformation (green in the scheme) of the carbene ligand in the ruthenium…”
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Highly Efficient Reagents for Br/Mg Exchange
Published in Angewandte Chemie International Edition (16-12-2005)“…The conversion of electron‐rich aryl bromides into the corresponding Grignard compounds proceeds within 2 h at 25 °C in the presence of 0.55 equivalents of the…”
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Electrically Assisted Magnetic Recording in Multiferroic Nanostructures
Published in Nano letters (01-06-2007)“…We demonstrate the room-temperature control of magnetization reversal with an electric field in an epitaxial nanostructure consisting of ferrimagnetic…”
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Copper and Silver Carbene Complexes without Heteroatom-Stabilization: Structure, Spectroscopy, and Relativistic Effects
Published in Angewandte Chemie International Edition (24-08-2015)“…Salts of a copper and a silver carbene complex were prepared from dimesityl diazomethane, made possible by the steric shielding of the N‐heterocyclic carbene…”
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Highly Diastereoselective Arylations of Substituted Piperidines
Published in Journal of the American Chemical Society (06-04-2011)“…A highly diastereoselective methodology for the preparation of various substituted piperidines via Negishi cross-couplings with (hetero)aryl iodides was…”
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Ligand Influence on Metathesis Activity of Ruthenium Carbene Catalysts: A DFT Study
Published in Advanced synthesis & catalysis (08-01-2007)“…A survey of the concept of active and inactive ligand conformations in ruthenium alkene carbene complexes of the Grubbs catalyst type is presented. This…”
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Iodocyclization of o‑Alkynylbenzamides Revisited: Formation of Isobenzofuran-1(3H)‑imines and 1H‑Isochromen-1-imines Instead of Lactams
Published in Journal of organic chemistry (16-11-2012)“…The iodocyclization of o-alkynylbenzamides with various electrophiles has been reported to yield five- or six-membered lactams by nucleophilic attack of the…”
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13
In Situ Mass Spectrometric and Kinetic Investigations of Soai's Asymmetric Autocatalysis
Published in Chemistry : a European journal (04-12-2020)“…Invited for the cover of this issue is Oliver Trapp and his co‐workers at Ludwig‐Maximilians‐Universität München, the Max‐Planck‐Institute for Astronomy and…”
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14
Real Time Imaging of Deuterium in a Duplex Stainless Steel Microstructure by Time-of-Flight SIMS
Published in Scientific reports (02-02-2016)“…For more than one century, hydrogen assisted degradation of metallic microstructures has been identified as origin for severe technical component failures but…”
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15
Mechanism of Enyne Metathesis Catalyzed by Grubbs Ruthenium−Carbene Complexes: A DFT Study
Published in Journal of the American Chemical Society (25-05-2005)“…The complete catalytic cycle of the reaction of alkenes and alkynes to dienes by Grubbs ruthenium carbene complexes has been modeled at the…”
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Reducing the Individual Carbon Impact of Video Streaming: A Seven-Week Intervention Using Information, Goal Setting, and Feedback
Published in Journal of consumer policy (01-06-2023)“…This online intervention study examined whether system- and action-related information alone, together with goal setting, or together with goal setting and…”
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Self-Assembled Growth of BiFeO3-CoFe2O4 Nanostructures
Published in Advanced materials (Weinheim) (17-10-2006)“…3D heteroepitaxial growth of BiFeO3‐CoFe2O4 nanostructures leads to unique morphological patterns depending on the substrate orientations. The morphologies of…”
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Dinuclear thiazolylidene copper complex as highly active catalyst for azid-alkyne cycloadditions
Published in Beilstein journal of organic chemistry (21-07-2016)“…A dinuclear N-heterocyclic carbene (NHC) copper complex efficiently catalyzes azide-alkyne cycloaddition (CuAAC) "click" reactions. The ancillary ligand…”
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The Mechanism of Hydroamination of Allenes, Alkynes, and Alkenes Catalyzed by Cyclopentadienyltitanium-Imido Complexes: A Density Functional Study
Published in Angewandte Chemie International Edition (17-12-2001)“…Proton transfer from ammine or amide ligands to vinylamine‐type π systems in intermediary titanacycles (see picture) of allene and alkyne hydroamination…”
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Isolated Silver Intermediate of Gold Precatalyst Activation
Published in European journal of inorganic chemistry (01-06-2012)“…The silver chloride and gold chloride complex of the extremely sterically shielding N‐heterocyclic carbene ligand IPr** have been synthesized and…”
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