Search Results - "Stewart, Scott G"
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Enantioselective Synthesis of anti-1,2-Oxaborinan-3-enes from Aldehydes and 1,1-Di(boryl)alk-3-enes Using Ruthenium and Chiral Phosphoric Acid Catalysts
Published in Journal of the American Chemical Society (09-08-2017)“…A cationic ruthenium(II) complex catalyzes double-bond transposition of 1,1-di(boryl)alk-3-enes to generate in situ 1,1-di(boryl)alk-2-enes, which then…”
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2
Synthesis of Enantiopure C3‐Symmetric Triangular Molecules
Published in Angewandte Chemie International Edition (13-03-2017)“…An asymmetric synthesis of C3‐symmetric triangular macrocycles is reported. 1‐Methylsulfonyl‐4‐(4‐vinylphenyl)‐1,2,3‐triazole undergoes a rhodium(II)‐catalyzed…”
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3
An Air-Stable Nickel(0) Phosphite Precatalyst for Primary Alkylamine C-N Cross-Coupling Reactions
Published in European journal of organic chemistry (01-09-2015)“…In this report we describe the design and preparation of a new air‐stable nickel phosphite based catalyst for unique C–N bond forming processes. Specifically,…”
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4
Spectrum of antibacterial activity and mode of action of a novel tris-stilbene bacteriostatic compound
Published in Scientific reports (02-05-2018)“…The spectrum of activity and mode of action of a novel antibacterial agent, 135C , was investigated using a range of microbiological and genomic approaches…”
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5
The Development of Domino Reactions Incorporating the Heck Reaction: The Formation of N-Heterocycles
Published in European Journal of Organic Chemistry (01-01-2012)“…The methodological development of a series of domino or cascade reactions affording a series of N‐heterocycles is described. The rapid formation of these ring…”
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Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N‑Sulfonyl-1,2,3-triazoles
Published in Journal of the American Chemical Society (18-09-2013)“…A stereoselective method for synthesis of trans-2,3-disubstituted 2,3-dihydropyrroles is reported. N-Sulfonyl-1,2,3-triazoles prepared from terminal alkynes…”
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7
Sucrose fatty acid esters: synthesis, emulsifying capacities, biological activities and structure-property profiles
Published in Critical reviews in food science and nutrition (28-10-2021)“…The notable physical and chemical properties of sucrose fatty acid esters have prompted their use in the chemical industry, especially as surfactants, since…”
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8
Nickel Phosphite/Phosphine-Catalyzed C–S Cross-Coupling of Aryl Chlorides and Thiols
Published in Organic letters (05-01-2018)“…A method for the coupling of aryl chlorides and thiophenols using an air-stable nickel(0) catalyst is described. This thioetherification procedure can be…”
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9
Strengthening Molecular Glues: Design Strategies for Improving Thalidomide Analogs as Cereblon Effectors and Anticancer Agents
Published in Drug discovery today (01-06-2024)“…•SAR insights on minimum pharmacophore for CRBN binding.•Scaffold alterations improving drug solubility and stability.•Rational approaches: phenotypic…”
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10
Transition Metal-free Methylation of Amines with Formaldehyde as the Reductant and Methyl Source
Published in Chimia (01-01-2015)“…A simple transition metal-free procedure using formal dehyde for the N,N-dimethylation and N-methylation of primary and secondary anilines is reported. The…”
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11
Norcantharidin Analogues: Synthesis, Anticancer Activity and Protein Phosphatase 1 and 2A Inhibition
Published in ChemMedChem (15-12-2008)“…Cantharidin (1) and its derivatives are of significant interest as serine/threonine protein phosphatase 1 and 2A inhibitors. Additionally, compounds of this…”
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12
Overview of the synthetic approaches to lysergic acid as a precursor to the psychedelic LSD
Published in Critical studies in media communication (07-07-2023)“…In this short primer we will discuss the total synthesis of lysergic acid, an important precursor to both lysergic acid diethylamide (LSD) and its derivatives…”
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13
Synthesis of Enantiopure C3‐Symmetric Triangular Molecules
Published in Angewandte Chemie (13-03-2017)“…An asymmetric synthesis of C3‐symmetric triangular macrocycles is reported. 1‐Methylsulfonyl‐4‐(4‐vinylphenyl)‐1,2,3‐triazole undergoes a rhodium(II)‐catalyzed…”
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Journal Article -
14
Synthesis of Enantiopure C 3 -Symmetric Triangular Molecules
Published in Angewandte Chemie International Edition (13-03-2017)“…An asymmetric synthesis of C -symmetric triangular macrocycles is reported. 1-Methylsulfonyl-4-(4-vinylphenyl)-1,2,3-triazole undergoes a rhodium(II)-catalyzed…”
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Journal Article -
15
Heterologous biosynthesis of elsinochrome A sheds light on the formation of the photosensitive perylenequinone system
Published in Chemical science (Cambridge) (07-02-2019)“…Perylenequinones are a class of aromatic polyketides characterised by a highly conjugated pentacyclic core, which confers them with potent light-induced…”
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16
Asymmetric Synthesis and Stereochemical Assignment of 12 C/ 13 C Isotopomers
Published in Journal of the American Chemical Society (28-08-2019)“…A synthesis of chiral hydrocarbons having axis and symmetry, which owe their chirality due to asymmetrical distribution of C/ C isotopes, is reported. Their…”
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17
Dirhodium-Catalyzed Transannulation of N‑Sulfonyl-1,2,3-triazoles to 2,3-Dehydropiperazines
Published in Journal of organic chemistry (18-08-2023)“…The dirhodium(II)-catalyzed synthesis of a range of C2-substituted 2,3-dehydropiperazines using 1-mesyl-1,2,3-triazoles and β-haloalkylcarbamates is reported…”
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The Synthesis and Catalytic Activity of New Mixed NHC-Phosphite Nickel(0) Complexes
Published in Organometallics (13-01-2020)“…Herein we describe the synthesis and isolation of the first low-valent NHC-phosphite nickel complexes of general formula Ni(NHC)[P(OAr)3]2. These…”
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Nickel Phosphite-Catalyzed Tetradehydro-Diels–Alder Reactions of (E)‑3-ene-1,8-diynes
Published in Journal of organic chemistry (05-05-2023)“…A nickel-catalyzed tetradehydro-Diels–Alder reaction of (E)-3-ene-1,8-diynes for the preparation of isoindolines, dihydroisobenzofurans, and…”
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The Right of Confrontation, Ongoing Emergencies, and the Violent-Perpetrator-at-Large Problem
Published in Stanford law review (01-12-2008)“…Recent judicial and scholarly treatment of the Confrontation Clause pays remarkably little attention to confrontation's purposes. This would not be…”
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