Search Results - "Stevanato, Gabriele"
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A Nuclear Singlet Lifetime of More than One Hour in Room-Temperature Solution
Published in Angewandte Chemie International Edition (16-03-2015)“…Nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) are supremely important techniques with numerous applications in almost all branches of…”
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2
Enhanced Intersystem Crossing and Transient Electron Spin Polarization in a Photoexcited Pentacene–Trityl Radical
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (23-07-2020)“…Identifying and characterizing systems that generate well-defined states with large electron spin polarization is of high interest for applications in…”
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3
Alternating Delays Achieve Polarization Transfer (ADAPT) to heteronuclei in PHIP experiments
Published in Journal of magnetic resonance (1997) (01-01-2017)“…[Display omitted] •A new, simple, and fast way to polarize heteronuclei in PHIP experiments.•A recipe for the parameters in the near magnetic equivalence…”
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4
Homonuclear Decoupling in 1H NMR of Solids by Remote Correlation
Published in Angewandte Chemie (06-04-2020)“…The typical linewidths of 1H NMR spectra of powdered organic solids at 111 kHz magic‐angle spinning (MAS) are of the order of a few hundred Hz. While this is…”
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5
A Nuclear Singlet Lifetime of More than One Hour in Room-Temperature Solution
Published in Angewandte Chemie (16-03-2015)“…Nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) are supremely important techniques with numerous applications in almost all branches of…”
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6
Dynamic Nuclear Polarization Enhancement of 200 at 21.15 T Enabled by 65 kHz Magic Angle Spinning
Published in The journal of physical chemistry letters (01-10-2020)“…Solid-state nuclear magnetic resonance under magic angle spinning (MAS) enhanced with dynamic nuclear polarization (DNP) is a powerful approach to characterize…”
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7
A pulse sequence for singlet to heteronuclear magnetization transfer: S2hM
Published in Journal of magnetic resonance (1997) (01-04-2017)“…[Display omitted] •The S2hM pulse sequence converts singlet order into heteronuclear magnetisation.•S2hM is designed to be robust to applied RF field offset…”
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8
Homonuclear ADAPT: A general preparation route to long-lived nuclear singlet order
Published in Journal of magnetic resonance (1997) (01-04-2019)“…[Display omitted] •The homonuclear ADAPT sequence accesses long-lived nuclear singlet order.•The sequence is based on the repeated module of a single hard…”
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9
Real-time cell metabolism assessed repeatedly on the same cells via para-hydrogen induced polarization
Published in Chemical science (Cambridge) (19-07-2023)“…Signal-enhanced or hyperpolarized nuclear magnetic resonance (NMR) spectroscopy stands out as a unique tool to monitor real-time enzymatic reactions in living…”
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10
Real-Time Pyruvate Chemical Conversion Monitoring Enabled by PHIP
Published in Journal of the American Chemical Society (15-03-2023)“…In recent years, parahydrogen-induced polarization side arm hydrogenation (PHIP-SAH) has been applied to hyperpolarize [1-13C]pyruvate and map its metabolic…”
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11
Dynamic Nuclear Polarization of Inorganic Halide Perovskites
Published in Journal of physical chemistry. C (15-06-2023)“…The intrinsic low sensitivity of nuclear magnetic resonance (NMR) experiments limits their utility for structure determination of materials. Dynamic nuclear…”
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12
Observation of Transient Prenucleation Species of Calcium Carbonate by DNP-Enhanced NMR
Published in The journal of physical chemistry letters (08-08-2024)“…Knowledge of the mechanism by which polymorphic inorganic species, such as carbonates, are formed is crucial to understand and guide the selective…”
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13
Real-time cell metabolism assessed repeatedly on the same cells para-hydrogen induced polarization
Published in Chemical science (Cambridge) (19-07-2023)“…Signal-enhanced or hyperpolarized nuclear magnetic resonance (NMR) spectroscopy stands out as a unique tool to monitor real-time enzymatic reactions in living…”
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14
Open and Closed Radicals: Local Geometry around Unpaired Electrons Governs Magic-Angle Spinning Dynamic Nuclear Polarization Performance
Published in Journal of the American Chemical Society (30-09-2020)“…The development of magic-angle spinning dynamic nuclear polarization (MAS DNP) has allowed atomic-level characterization of materials for which conventional…”
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15
Rapid Structure Determination of Molecular Solids Using Chemical Shifts Directed by Unambiguous Prior Constraints
Published in Journal of the American Chemical Society (23-10-2019)“…NMR-based crystallography approaches involving the combination of crystal structure prediction methods, ab initio calculated chemical shifts and solid-state…”
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16
Direct enhancement of nitrogen-15 targets at high-field by fast ADAPT-SABRE
Published in Journal of magnetic resonance (1997) (01-12-2017)“…[Display omitted] •SABRE hyperpolarization is achieved at high field by the ADAPT pulse sequence.•A theoretical description of ADAPT-SABRE is linked to related…”
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17
Metabolic Tumor Imaging with Rapidly Signal‐Enhanced 1‐13C‐Pyruvate‐d3
Published in Chemphyschem (17-01-2023)“…The metabolism of malignant cells differs significantly from that of healthy cells and thus, it is possible to perform metabolic imaging to reveal not only the…”
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18
TinyPols: a family of water-soluble binitroxides tailored for dynamic nuclear polarization enhanced NMR spectroscopy at 18.8 and 21.1 T
Published in Chemical science (Cambridge) (05-02-2020)“…Dynamic Nuclear Polarization (DNP) has recently emerged as a key method to increase the sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning…”
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19
LIGHT-SABRE Hyperpolarizes 1-13C‑Pyruvate Continuously without Magnetic Field Cycling
Published in Journal of physical chemistry. C (13-04-2023)“…Nuclear spin hyperpolarization enables real-time observation of metabolism and intermolecular interactions in vivo. 1-13C-pyruvate is the leading…”
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20
LIGHT-SABRE Hyperpolarizes 1- 13 C-Pyruvate Continuously without Magnetic Field Cycling
Published in Journal of physical chemistry. C (13-04-2023)“…Nuclear spin hyperpolarization enables real-time observation of metabolism and intermolecular interactions . 1- C-pyruvate is the leading hyperpolarized tracer…”
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