Search Results - "Stephen, R. Meech"
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Ultrafast Excimer Formation and Solvent Controlled Symmetry Breaking Charge Separation in the Excitonically Coupled Subphthalocyanine Dimer
Published in Angewandte Chemie International Edition (03-05-2021)“…Knowledge of the factors controlling excited state dynamics in excitonically coupled dimers and higher aggregates is critical for understanding natural and…”
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Ultrafast motion in a third generation photomolecular motor
Published in Nature communications (06-03-2023)“…Controlling molecular translation at the nanoscale is a key objective for development of synthetic molecular machines. Recently developed third generation…”
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3
Low-Frequency Modes of Aqueous Alkali Halide Solutions: Glimpsing the Hydrogen Bonding Vibration
Published in Science (American Association for the Advancement of Science) (12-02-2010)“…The solvation of ions in aqueous media is a fundamental process in biology and chemistry. Here, we report direct time-domain observations of the hydrogen bond…”
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Ultrafast Dynamics in Light-Driven Molecular Rotary Motors Probed by Femtosecond Stimulated Raman Spectroscopy
Published in Journal of the American Chemical Society (31-05-2017)“…Photochemical isomerization in sterically crowded chiral alkenes is the driving force for molecular rotary motors in nanoscale machines. Here the excited-state…”
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Chemically Optimizing Operational Efficiency of Molecular Rotary Motors
Published in Journal of the American Chemical Society (09-07-2014)“…Unidirectional molecular rotary motors that harness photoinduced cis–trans (E–Z) isomerization are promising tools for the conversion of light energy to…”
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Ultrafast dynamics in the power stroke of a molecular rotary motor
Published in Nature chemistry (06-05-2012)“…Light-driven molecular motors convert light into mechanical energy through excited-state reactions. Unidirectional rotary molecular motors based on chiral…”
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A new twist in the photophysics of the GFP chromophore: a volume-conserving molecular torsion couple
Published in Chemical science (Cambridge) (21-02-2018)“…The simple structure of the chromophore of the green fluorescent protein (GFP), a phenol and an imidazolone ring linked by a methyne bridge, supports an…”
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Photoactivation of the BLUF Protein PixD Probed by the Site-Specific Incorporation of Fluorotyrosine Residues
Published in Journal of the American Chemical Society (18-10-2017)“…The flavin chromophore in blue-light-using FAD (BLUF) photoreceptors is surrounded by a hydrogen bond network that senses and responds to changes in the…”
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THz Spectra and Dynamics of Aqueous Solutions Studied by the Ultrafast Optical Kerr Effect
Published in The journal of physical chemistry. B (24-03-2011)“…The nature and extent of the effects that hydrophilic and hydrophobic solutes have on the dynamics of water molecules continues to be an area of intense…”
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Proteins in Action: Femtosecond to Millisecond Structural Dynamics of a Photoactive Flavoprotein
Published in Journal of the American Chemical Society (30-10-2013)“…Living systems are fundamentally dependent on the ability of proteins to respond to external stimuli. The mechanism, the underlying structural dynamics, and…”
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Water Dynamics at Protein Interfaces: Ultrafast Optical Kerr Effect Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (22-03-2012)“…The behavior of water molecules surrounding a protein can have an important bearing on its structure and function. Consequently, a great deal of attention has…”
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Ultrafast dynamics in complex fluids observed through the ultrafast optically-heterodyne-detected optical-Kerr-effect (OHD-OKE)
Published in Physical chemistry chemical physics : PCCP (01-01-2007)“…The ultrafast molecular dynamics of complex fluids have been recorded using the optically-heterodyne-detected optical-Kerr-effect (OHD-OKE). The OHD-OKE method…”
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Ultrafast Excited State Dynamics in Molecular Motors: Coupling of Motor Length to Medium Viscosity
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-03-2017)“…Photochemically driven molecular motors convert the energy of incident radiation to intramolecular rotational motion. The motor molecules considered here…”
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Reactive Dynamics in Confined Liquids: Ultrafast Torsional Dynamics of Auramine O in Nanoconfined Water in Aerosol OT Reverse Micelles
Published in The journal of physical chemistry. B (12-02-2009)“…The effects of confinement on the ultrafast torsional reaction of auramine O in aqueous solution are investigated through ultrafast fluorescence up-conversion…”
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15
Functional dynamics of a single tryptophan residue in a BLUF protein revealed by fluorescence spectroscopy
Published in Scientific reports (06-02-2020)“…Blue Light Using Flavin (BLUF) domains are increasingly being adopted for use in optogenetic constructs. Despite this, much remains to be resolved on the…”
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Time-Resolved Twisting Dynamics in a Porphyrin Dimer Characterized by Two-Dimensional Electronic Spectroscopy
Published in The journal of physical chemistry. B (19-11-2015)“…Molecular conformational changes in electronic excited states play a key role in numerous light-activated processes. In the case of porphyrin oligomers…”
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Excited state reactions in fluorescent proteins
Published in Chemical Society reviews (01-10-2009)“…The green fluorescent protein is a key technology in bioimaging. In this critical review, we consider how its various applications can be tailored from…”
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Complete Proton Transfer Cycle in GFP and Its T203V and S205V Mutants
Published in Angewandte Chemie International Edition (03-08-2015)“…Proton transfer is critical in many important biochemical reactions. The unique three‐step excited‐state proton transfer in avGFP allows observations of…”
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Excited-State Dynamics in the Green Fluorescent Protein Chromophore
Published in The journal of physical chemistry. B (22-01-2004)“…The remarkable suppression of radiationless decay by the green fluorescent protein (GFP) is investigated through ultrafast fluorescence spectroscopy of its…”
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Full Characterization of Vibrational Coherence in a Porphyrin Chromophore by Two-Dimensional Electronic Spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (08-01-2015)“…In this work we present experimental and calculated two-dimensional electronic spectra for a 5,15-bisalkynyl porphyrin chromophore. The lowest energy…”
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