Search Results - "Steglich, Wolfgang"
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1
The DMAP-Catalyzed Acetylation of Alcohols-A Mechanistic Study (DMAP=4-(Dimethylamino)pyridine)
Published in Chemistry : a European journal (05-08-2005)“…The acetylation of tert‐butanol with acetic anhydride catalyzed by 4‐(dimethylamino)pyridine (DMAP) has been studied at the Becke3 LYP/6‐311+G(d,p)//Becke3…”
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2
Strobilurins: Evolution of a New Class of Active Substances
Published in Angewandte Chemie International Edition (17-05-1999)“…A fungus that grows on pinecones yields a compound with antifungal activity that has become the natural model for a significant innovation in crop protection…”
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3
Enhancing the Catalytic Activity of 4-(Dialkylamino)pyridines by Conformational Fixation
Published in Angewandte Chemie International Edition (13-10-2003)“…Six times more active than DMAP (1), the tricyclic DMAP analogue 2 catalyzes the acetylation of a tertiary alcohol with acetic anhydride. The experimental…”
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4
New Pulvinic Acid and Phenylalaninol Derivatives from the Mushrooms Retiboletus griseus and R. nigerrimus
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (01-06-2013)“…The close genetic relationship of the mushrooms Retiboletus griseus and R. nigerrimus is supported by the occurrence of the orange-yellow retiboletic acid,…”
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5
Chromogenic Meroterpenoids from the Mushrooms Russula ochroleuca and R. viscida
Published in European Journal of Organic Chemistry (01-02-2006)“…The spirodioxolactone ochroleucin A1 (1) is responsible for the red colour produced when the stalk base of Russula ochroleuca and R. viscida is treated with…”
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6
Studies on the Structure and Biosynthesis of Tridentoquinone and Related Meroterpenoids from the Mushroom Suillus tridentinus (Boletales)
Published in European Journal of Organic Chemistry (01-02-2008)“…Tridentoquinone (1), the main pigment of Suillus tridentinus, is accompanied by the known meroterpenoid bolegrevilol (3) and a dimer, tridentorubin (5). The…”
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7
New Tryptophan Metabolites from Cultures of the Lipophilic Yeast Malassezia furfur
Published in Helvetica chimica acta (01-06-2005)“…Eleven new indole alkaloids were isolated from cultures of the human pathogenic yeast Malassezia furfur after addition of L‐tryptophan as the sole N‐source:…”
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Malassezin, a Novel Agonist of the Aryl Hydrocarbon Receptor from the Yeast Malassezia furfur, Induces Apoptosis in Primary Human Melanocytes
Published in Chembiochem : a European journal of chemical biology (01-05-2005)“…Pityriasis versicolor is the most common skin mycosis in humans worldwide. Yeasts of the genus Malassezia, particularly M. furfur, a saprophyte occurring…”
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9
Total Syntheses of the Marine Pyrrole Alkaloids Polycitone A and B
Published in Organic letters (19-09-2002)“…Polycitone B (2) was obtained in four steps from pyrrole dicarboxylic acid 3, including Friedel−Crafts reaction of the corresponding acid chloride with…”
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10
Total synthesis of the marine alkaloid halitulin
Published in Tetrahedron (10-11-2003)“…The structure of the strongly cytotoxic marine alkaloid halitulin ( 1 ) has been confirmed by total synthesis and its absolute configuration determined as (15…”
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11
Unusual Pulvinic Acid Dimers from the Common Fungi Scleroderma citrinum (Common Earthball) and Chalciporus piperatus (Peppery Bolete)
Published in Angewandte Chemie International Edition (26-03-2004)“…What do some fungi have in common with chemists? Common earthballs (see picture) and peppery boletes are true artists in natural product synthesis. In few…”
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12
First total synthesis of the marine alkaloids purpurone and ningalin C
Published in Tetrahedron letters (02-12-2000)“…Purpurone is obtained from 3-(3,4-dimethoxyphenyl)pyruvic acid, 2-(4-methoxyphenyl)ethylamine and 2′,2′,2′-trichloroethyl…”
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13
Retipolides - Unusual Spiromacrolactones from the Mushrooms Retiboletus retipes and R. ornatipes
Published in European Journal of Organic Chemistry (01-11-2007)“…Mushrooms of the genus Retiboletus contain the retipolides A–D (1, 6–8), unusual 14‐membered spiromacrolides with a biphenyl ether linkage. The structures of…”
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14
Pityriacitrin: an ultraviolet-absorbing indole alkaloid from the yeast Malassezia furfur
Published in Archives of Dermatological Research (01-05-2002)“…As the main nitrogen source in Malassezia furfur, tryptophan induces the formation of fluorochromes and pigments, which make the yeast less sensitive to UV…”
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15
Biosynthesis and Stereochemistry of Phlegmacin-Type Fungal Pigments
Published in European journal of organic chemistry (01-12-2004)“…The absolute stereostructures of phlegmacins A1 (3a) and B1 (3b) were determined by biosynthetic studies, quantum chemical CD calculations, and NOE…”
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16
Malassezin—a novel agonist of the Arylhydrocarbon receptor from the yeast Malassezia furfur
Published in Bioorganic & medicinal chemistry (01-04-2001)“…The yeast Malassezia furfur converts tryptophan into several indole compounds. One of these, malassezin, was identified as…”
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17
Alkaloids from marine organisms. Part 8: Isolation of bisdemethylaaptamine and bisdemethylaaptamine-9- O-sulfate from an Indonesian Aaptos sp. marine sponge
Published in Tetrahedron (12-07-2004)“…Bisdemethylaaptamine ( 6 ), a proposed biosynthetic precursor of the aaptamines has been isolated from an Aaptos sp. marine sponge harvested off the Indonesian…”
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18
Enzymatic Formation of Rufoschweinitzin, a Binaphthalene from the Basidiomycete Cortinarius rufoolivaceus
Published in Chembiochem : a European journal of chemical biology (15-05-2020)“…Dimeric polyketides are widespread fungal secondary metabolites. They occur in both ascomycetes and basidiomycetes and, therefore, across fungal phyla. Here we…”
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19
Synthesis and cyclisation of didemnimide C and its imidazol-1-yl isomer
Published in Tetrahedron (26-02-1998)“…A key step in the synthesis of the marine alkaloid didemnimide C ( 1c) is the Stille coupling between the urethane protected…”
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20
A concise synthesis of storniamide A nonamethyl ether [1]
Published in Tetrahedron letters (01-12-1998)“…(E,E)-Storniamide A nonamethyl ether is obtained from 3-(3,4,5-trimethoxyphenyl)-pyruvic acid and 2-(4-hydroxyphenyl)ethylamine in three steps with an overall…”
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