Search Results - "Starý, Ivo"

Helically Chiral Aromatics: The Synthesis of Helicenes by [2 + 2 + 2] Cycloisomerization of π‑Electron Systems by Stará, Irena G, Starý, Ivo

“…Conspectus Advanced molecular nanocarbons are now in the spotlight reflecting the basic discoveries of fullerenes, carbon nanotubes, and graphene. This…”
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An Ultimate Stereocontrol in Asymmetric Synthesis of Optically Pure Fully Aromatic Helicenes by Šámal, Michal, Chercheja, Serghei, Rybáček, Jiří, Vacek Chocholoušová, Jana, Vacek, Jaroslav, Bednárová, Lucie, Šaman, David, Stará, Irena G, Starý, Ivo

“…The role of the helicity of small molecules in enantioselective catalysis, molecular recognition, self-assembly, material science, biology, and nanoscience is…”
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From helical to planar chirality by on-surface chemistry by Stetsovych, Oleksandr, Švec, Martin, Vacek, Jaroslav, Chocholoušová, Jana Vacek, Jančařík, Andrej, Rybáček, Jiří, Kosmider, Krzysztof, Stará, Irena G., Jelínek, Pavel, Starý, Ivo

“…The chirality of molecular structures is paramount in many phenomena, including enantioselective reactions, molecular self-assembly, biological processes and…”
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Towards dielectric relaxation at a single molecule scale by Stetsovych, Vitalii, Feigl, Simon, Vranik, Radovan, Wit, Bareld, Rauls, Eva, Nejedlý, Jindřich, Šámal, Michal, Starý, Ivo, Müllegger, Stefan

“…Dielectric relaxation lies at the heart of well-established techniques of dielectric spectroscopy essential to diverse fields of research and technology. We…”
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Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy by Berger, Jan, Ondráček, Martin, Stetsovych, Oleksandr, Malý, Pavel, Holý, Petr, Rybáček, Jiří, Švec, Martin, Stará, Irena G., Mančal, Tomáš, Starý, Ivo, Jelínek, Pavel

“…Intramolecular charge transfer processes play an important role in many biological, chemical and physical processes including photosynthesis, redox chemical…”
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Asymmetric Synthesis of Nonracemic 2‑Amino[6]helicenes and Their Self-Assembly into Langmuir Films by Karras, Manfred, Holec, Jan, Bednárová, Lucie, Pohl, Radek, Schmidt, Bernd, Stará, Irena G, Starý, Ivo

“…Alternative ways of preparing nonracemic 2-amino[6]­helicene derivatives were explored. The enantioselective [2 + 2 + 2] cycloisomerization of a nonchiral…”
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Cycloiridated Helicenes as Chiral Catalysts in the Asymmetric Transfer Hydrogenation of Imines by Sakamoto, Daisuke, Gay Sánchez, Isabel, Rybáček, Jiří, Vacek, Jaroslav, Bednárová, Lucie, Pazderková, Markéta, Pohl, Radek, Císařová, Ivana, Stará, Irena G., Starý, Ivo

“…The asymmetric synthesis of optically pure and conformationally locked oxabenzo[5]­helicenes bearing pyridin-2-yl or isoquinolin-3-yl substituents and their…”
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Synthesis of Long Oxahelicenes by Polycyclization in a Flow Reactor by Nejedlý, Jindřich, Šámal, Michal, Rybáček, Jiří, Tobrmanová, Miroslava, Szydlo, Florence, Coudret, Christophe, Neumeier, Maria, Vacek, Jaroslav, Vacek Chocholoušová, Jana, Buděšínský, Miloš, Šaman, David, Bednárová, Lucie, Sieger, Ladislav, Stará, Irena G., Starý, Ivo

“…A series of oxahelicenes composed of ortho/meta‐annulated benzene/pyridine and 2H‐pyran rings were synthesized on the basis of the cobalt(I)‐mediated (or…”
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Stereocontrolled Synthesis of Chiral Helicene-Indenido ansa- and Half-Sandwich Metal Complexes and Their Use in Catalysis by Stary, Ivo, Edlová, Tereza, Rybáček, Jiří, Cattey, Hélène, Vacek, Jaroslav, Bednárová, Lucie, Le Gendre, Pierre, Normand, Adrien T, Stará, Irena G

“…Despite recent tremendous progress in the synthesis of nonplanar chiral aromatics, and helicenes in particular, their conversion to half-sandwich or sandwich…”
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Large Converse Piezoelectric Effect Measured on a Single Molecule on a Metallic Surface by Stetsovych, Oleksandr, Mutombo, Pingo, Švec, Martin, Šámal, Michal, Nejedlý, Jindřich, Císařová, Ivana, Vázquez, Héctor, Moro-Lagares, María, Berger, Jan, Vacek, Jaroslav, Stará, Irena G, Starý, Ivo, Jelínek, Pavel

“…The converse piezoelectric effect is a phenomenon in which mechanical strain is generated in a material due to an applied electrical field. In this work, we…”
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Electrochemistry of Tetrathiafulvalene Ligands Assembled on the Surface of Gold Nanoparticles by Janoušek, Jiří, Rybáček, Jiří, Buděšínský, Miloš, Pospíšil, Lubomír, Stará, Irena G., Starý, Ivo

“…The synthesis of a tetrathiafulvalene (TTF) derivative, S-[4-({4-[(2,2′-bi-1,3-dithiol-4-ylmethoxy)methyl] phenyl}ethynyl)phenyl] ethanethioate, suitable for…”
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Chimerical Pyrene-Based [7]Helicenes as Twisted Polycondensed Aromatics by Buchta, Michal, Rybáček, Jiří, Jančařík, Andrej, Kudale, Amit A., Buděšínský, Miloš, Chocholoušová, Jana Vacek, Vacek, Jaroslav, Bednárová, Lucie, Císařová, Ivana, Bodwell, Graham J., Starý, Ivo, Stará, Irena G.

“…Chimerical pyrene‐based dibenzo[7]helicene rac‐1 and 2H‐pyran[7]helicene (M,R,R)‐(−)‐2, in which two pyrene subunits are fused to the…”
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Synthesis of Racemic, Diastereopure, and Enantiopure Carba- or Oxa[5]‑, [6]‑, [7]‑, and -[19]helicene (Di)thiol Derivatives by Nejedlý, Jindřich, Šámal, Michal, Rybáček, Jiří, Sánchez, Isabel Gay, Houska, Václav, Warzecha, Tomáš, Vacek, Jaroslav, Sieger, Ladislav, Buděšínský, Miloš, Bednárová, Lucie, Fiedler, Pavel, Císařová, Ivana, Starý, Ivo, Stará, Irena G

“…A series of carba- or oxa[5]-, [6]-, [7]-, and -[19]­helicene (di)­thiols was prepared. The Miyazaki–Newman–Kwart rearrangement of (dimethylcarbamothioyl)­oxy…”
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Asymmetric Synthesis of Diastereo‐ and Enantiopure Bioxahelicene 2,2′‐Bipyridines by Klívar, Jiří, Šámal, Michal, Jančařík, Andrej, Vacek, Jaroslav, Bednárová, Lucie, Buděšínský, Miloš, Fiedler, Pavel, Starý, Ivo, Stará, Irena G.

“…A versatile asymmetric synthesis of five C2 symmetric enantio‐ and diastereopure bioxa[5]‐ and bioxa[6]helicene 2,2′‐bipyridines was developed. It relied…”
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Rapid Access to Dibenzohelicenes and their Functionalized Derivatives by Jančařík, Andrej, Rybáček, Jiří, Cocq, Kevin, Vacek Chocholoušová, Jana, Vacek, Jaroslav, Pohl, Radek, Bednárová, Lucie, Fiedler, Pavel, Císařová, Ivana, Stará, Irena G., Starý, Ivo

“…Spiraling up: Easy access to dibenzo[5]‐, dibenzo[6]‐, and dibenzo[7]helicenes (see picture) as well as their functionalized derivatives includes Sonogashira…”
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Helicenes as Chirality‐Inducing Groups in Transition‐Metal Catalysis: The First Helically Chiral Olefin Metathesis Catalyst by Karras, Manfred, Dąbrowski, Michał, Pohl, Radek, Rybáček, Jiří, Vacek, Jaroslav, Bednárová, Lucie, Grela, Karol, Starý, Ivo, Stará, Irena G., Schmidt, Bernd

“…Helical chirality is a novel enantioselectivity‐inducing property in transition‐metal‐catalyzed transformations. The principle is illustrated herein for the…”
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Aromatic Azide Transformation on the Ag(111) Surface Studied by Scanning Probe Microscopy by Hellerstedt, Jack, Cahlík, Aleš, Stetsovych, Oleksander, Švec, Martin, Shimizu, Tomoko K., Mutombo, Pingo, Klívar, Jiří, Stará, Irena G., Jelínek, Pavel, Starý, Ivo

“…Chemical transformation of 9‐azidophenanthrene on the Ag(111) surface was studied by nc‐AFM in UHV. High‐resolution imaging supported by first‐principle…”
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Tailored Formation of N‑Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)Dehydrogenation of Heteroaromatics by Pinardi, Anna Lisa, Otero-Irurueta, Gonzalo, Palacio, Irene, Martinez, Jose Ignacio, Sanchez-Sanchez, Carlos, Tello, Marta, Rogero, Celia, Cossaro, Albano, Preobrajenski, Alexei, Gómez-Lor, Berta, Jancarik, Andrej, Stará, Irena G, Starý, Ivo, Lopez, M. Francisca, Méndez, Javier, Martin-Gago, Jose Angel

“…Surface-assisted cyclodehydrogenation and dehydrogenative polymerization of polycyclic (hetero)aromatic hydrocarbons (PAH) are among the most important…”
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Straightforward Route to Helically Chiral N-Heteroaromatic Compounds: Practical Synthesis of Racemic 1,14-Diaza[5]helicene and Optically Pure 1- and 2-Aza[6]helicenes by Mísek, Jirí, Teplý, Filip, Stará, Irena G, Tichý, Milos, Saman, David, Císarová, Ivana, Vojtísek, Pavel, Starý, Ivo

“…The taming of the screw: The CoI‐catalyzed cyclotrimerization of triynes and microwave (MW) assisted aromatization with MnO2 are central to the practical…”
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On‐Surface Synthesis of Helicene Oligomers by Pinar Solé, Andrés, Klívar, Jiří, Šámal, Michal, Stará, Irena G., Starý, Ivo, Mendieta‐Moreno, Jesús I., Ernst, Karl‐Heinz, Jelínek, Pavel, Stetsovych, Oleksandr

“…We report on‐surface synthesis of heterochiral 1D heptahelicene oligomers after deposition of a racemic heptahelicene monomer on an Au(111) surface followed by…”
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