Search Results - "Stanley, Robert J"
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Time-resolved THz Stark spectroscopy of molecules in solution
Published in Nature communications (17-05-2024)“…For decades, it was considered all but impossible to perform Stark spectroscopy on molecules in a liquid solution, because their concomitant orientation to the…”
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Coexistence of Different Electron-Transfer Mechanisms in the DNA Repair Process by Photolyase
Published in Chemistry : a European journal (01-08-2016)“…DNA photolyase has been the topic of extensive studies due to its important role of repairing photodamaged DNA, and its unique feature of using light as an…”
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Determinants of Photolyase’s DNA Repair Mechanism in Mesophiles and Extremophiles
Published in Journal of the American Chemical Society (28-02-2018)“…Light-driven DNA repair by extremophilic photolyases is of tremendous importance for understanding the early development of life on Earth. The mechanism for…”
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Charge Redistribution in Oxidized and Semiquinone E. coli DNA Photolyase upon Photoexcitation: Stark Spectroscopy Reveals a Rationale for the Position of Trp382
Published in Journal of the American Chemical Society (08-04-2009)“…The electronic structure of the two lowest excited electronic states of FAD and FADH• in folate-depleted E. coli DNA photolyase (PLOX and PLSQ, respectively)…”
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Screening for Novel Fluorescent Nucleobase Analogues Using Computational and Experimental Methods: 2‑Amino-6-chloro-8-vinylpurine (2A6Cl8VP) as a Case Study
Published in The journal of physical chemistry. B (21-09-2023)“…Novel fluorescent nucleic acid base analogues (FBAs) with improved optical properties are needed in a variety of biological applications…”
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An upper limit to the fluorescence quantum yield for reduced flavins – a spectroscopic approach to better understand photoflavoproteins
Published in The FASEB journal (01-05-2022)“…Flavins are blue‐light absorbing chromophores with rich redox activity, found in oxidized, one electron‐ and two electron‐reduced forms. Some, namely flavin…”
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Stark Spectroscopy of Lumichrome: A Possible Candidate for Stand-Off Detection of Bacterial Quorum Sensing
Published in The journal of physical chemistry. B (31-12-2020)“…Lumichrome (7,8-dimethylalloxazine, LC) is a natural photodegradation product and catabolite of flavin coenzymes. Although not a coenzyme itself, LC is used…”
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2-Aminopurine Excited State Electronic Structure Measured by Stark Spectroscopy
Published in The journal of physical chemistry. B (14-02-2008)“…2-Aminopurine (2AP) is an adenine analogue that has a high fluorescence quantum yield. Its fluorescence yield decreases significantly when the base is…”
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9
Human Histologic Verification of Gingival Uniformity Pinkening via Selective Radiofrequency Ablative Deepithelization
Published in The International journal of periodontics & restorative dentistry (01-01-2023)“…Various gingival depigmentation techniques have been introduced to realize esthetic gingival color enhancement. Unfortunately, many of these procedures have…”
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10
Reduced Flavin in Aqueous Solution Is Nonfluorescent
Published in Biochemistry (Easton) (07-02-2023)“…Flavins are blue-light-absorbing chromophores with rich redox activity. Biologically, the most important are riboflavin (vitamin B2), flavin mononucleotide,…”
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Flavin Charge Redistribution upon Optical Excitation Is Independent of Solvent Polarity
Published in The journal of physical chemistry. B (26-01-2023)“…Flavin absorption spectra encode molecular details of the flavin’s local environment through coupling of local electric fields with the chromophore’s charge…”
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12
Adenine Fine-Tunes DNA Photolyase’s Repair Mechanism
Published in The journal of physical chemistry. B (06-04-2023)“…The comparative study of DNA repair by mesophilic and extremophilic photolyases helps us understand the evolution of these enzymes and their role in preserving…”
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13
Commentary: Recollections From the Early Days of Computed Tomography
Published in Journal of computer assisted tomography (01-11-2021)Get full text
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14
Measuring electronic structure properties of flavins and flavoproteins by electronic Stark spectroscopy
Published in Methods in enzymology (2019)“…The optical spectrum of a flavoprotein is one of its signature properties. No two flavoprotein absorption spectra are exactly alike as each encodes the details…”
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15
Characterization of a cold-adapted DNA photolyase from C. psychrerythraea 34H
Published in Extremophiles : life under extreme conditions (01-09-2017)“…The phrB gene encoding a putative cold-adapted DNA photolyase was cloned from the bacterial genomic DNA of Colwellia psychrerythraea 34H, a psychrophilic…”
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Ultrafast Excited State Dynamics of Oxidized Flavins: Direct Observations of Quenching by Purines
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (03-08-2000)“…We have measured the excited-state dynamics and spectral evolution of oxidized flavin−adenine dinucleotide (FADox) and flavin mononucleotide (FMNox) in simple…”
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Cyclobutylpyrimidine Dimer Base Flipping by DNA Photolyase
Published in The Journal of biological chemistry (11-10-2002)“…DNA Photolyase is a flavoprotein that uses light to repair cyclobutylpyrimidine dimers in DNA. From considerations of the crystal structure of the protein, it…”
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18
Optically Controlled Electron Transfer in a Re I Complex
Published in Chemistry : a European journal (22-03-2021)“…Ultrafast optical control of intramolecular charge flow was demonstrated, which paves the way for photocurrent modulation and switching with a highly…”
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19
Optically Controlled Electron Transfer in a Re(I) Complex
Published in Chemistry : a European journal (22-03-2021)“…Ultrafast optical control of intramolecular charge flow was demonstrated, which paves the way for photocurrent modulation and switching with a highly…”
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20
Ultrafast flavin/tryptophan radical pair kinetics in a magnetically sensitive artificial protein
Published in Physical chemistry chemical physics : PCCP (26-06-2019)“…Radical pair formation and decay are implicated in a wide range of biological processes including avian magnetoreception. However, studying such biological…”
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