Search Results - "Stanley, Levi"
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Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution
Published in Accounts of chemical research (21-12-2010)“…Enantioselective allylic substitution reactions comprise some of the most versatile methods for preparing enantiomerically enriched materials. These reactions…”
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2
Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions
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3
Ni-Catalyzed Three-Component Alkene Carboacylation Initiated by Amide C–N Bond Activation
Published in ACS catalysis (07-06-2019)“…The nickel-catalyzed intermolecular carboacylation of alkenes with amides and tetraarylborates is presented. Bicyclic alkenes are readily functionalized with a…”
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4
Nickel-Catalyzed Enantioselective Hydroboration of Vinylarenes
Published in Organic letters (14-01-2022)“…The enantioselective hydroboration of vinylarenes catalyzed by a chiral, nonracemic nickel catalyst is presented as a facile method for generating chiral…”
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5
Nickel-Catalyzed Formation of α‑Substituted γ‑Amino Ketones via Alkene Carboacylation
Published in Organic letters (16-12-2022)“…Herein, we report Ni-catalyzed intramolecular carboacylation of imides containing a tethered alkene and tetraarylborate nucleophiles. Using a nickel-phosphine…”
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6
Synthesis of Highly Substituted Oxaboroles from Oxaboranes via a Selective Petasis Borono–Mannich Reaction
Published in Organic letters (06-09-2024)“…We present a novel and efficient method for the synthesis of highly substituted non-benzofused oxaboroles. Reactions of oxaboranes, morpholine, and…”
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Catalytic, Enantioselective Synthesis of Polycyclic Nitrogen, Oxygen, and Sulfur Heterocycles via Rh-Catalyzed Alkene Hydroacylation
Published in Organic letters (06-10-2017)“…Enantioselective synthesis of polycyclic nitrogen, oxygen, and sulfur heterocycles by rhodium-catalyzed intramolecular alkene hydroacylation is reported. The…”
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Tandem Alkyne Hydroacylation and Oxo-Michael Addition: Diastereoselective Synthesis of 2,3-Disubstituted Chroman-4-ones and Fluorinated Derivatives
Published in Organic letters (02-07-2015)“…Tandem reactions involving Rh-catalyzed intermolecular hydroacylations of alkynes with salicylaldehydes followed by intramolecular oxo-Michael additions are…”
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9
General Strategy for Incorporation of Functional Group Handles into Covalent Organic Frameworks via the Ugi Reaction
Published in Journal of the American Chemical Society (22-03-2023)“…The library of imine-linked covalent organic frameworks (COFs) has grown significantly over the last two decades, featuring a variety of morphologies, pore…”
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10
Nickel-Catalyzed Isomerization of Homoallylic Alcohols
Published in Organic letters (19-05-2023)“…Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a…”
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11
Ni-Catalyzed Intermolecular Carboacylation of Internal Alkynes via Amide C–N Bond Activation
Published in Organic letters (07-08-2020)“…The Ni-catalyzed carboacylation of alkynes with amide electrophiles and triarylboroxines is presented. The reaction generates all-carbon tetrasubstituted…”
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12
Efficient Capture and Release of the Rare-Earth Element Neodymium in Aqueous Solution by Recyclable Covalent Organic Frameworks
Published in Journal of the American Chemical Society (24-07-2024)“…Rare-earth elements (REEs) are present in a broad range of critical materials. The development of solid adsorbents for REE capture could enable the…”
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13
Nickel-Catalyzed Asymmetric Hydroarylation of Vinylarenes: Direct Enantioselective Synthesis of Chiral 1,1-Diarylethanes
Published in Journal of organic chemistry (05-03-2021)“…The enantioselective hydroarylation of vinylarenes catalyzed by a chiral, non-racemic nickel catalyst is presented as a facile method to generate chiral…”
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14
Iridium-Catalyzed Regio- and Enantioselective N-Allylation of Indoles
Published in Angewandte Chemie (International ed.) (01-01-2009)“…Iridium is blind to C: Highly regio‐ and enantioselective, iridium‐catalyzed N‐allylations of indoles, which complement the more common reactivity of indoles…”
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15
Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation
Published in Journal of the American Chemical Society (23-02-2011)“…We report a concise, enantioselective total synthesis of (−)-taiwaniaquinone H and the first enantioselective total synthesis of (−)-taiwaniaquinol B by a…”
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16
Regio- and Enantioselective N-Allylations of Imidazole, Benzimidazole, and Purine Heterocycles Catalyzed by Single-Component Metallacyclic Iridium Complexes
Published in Journal of the American Chemical Society (01-07-2009)“…Highly regio- and enantioselective iridium-catalyzed N-allylations of benzimidazoles, imidazoles, and purines have been developed. N-Allylated benzimidazoles…”
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17
Cooperative Multifunctional Catalysts for Nitrone Synthesis: Platinum Nanoclusters in Amine‐Functionalized Metal–Organic Frameworks
Published in Angewandte Chemie International Edition (18-12-2017)“…Nitrones are key intermediates in organic synthesis and the pharmaceutical industry. The heterogeneous synthesis of nitrones with multifunctional catalysts is…”
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18
Palladium-Catalyzed Intermolecular Alkene Carboacylation via Ester C–O Bond Activation
Published in Organic letters (07-05-2021)“…We report palladium-catalyzed intermolecular carboacylation of alkenes with ester electrophiles and tetraarylborate nucleophiles. Bicyclic alkenes react with a…”
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19
Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β,β-Disubstituted Enones in Aqueous Media: Formation of Bis-benzylic and ortho-Substituted Benzylic Quaternary Centers
Published in ACS catalysis (04-09-2015)“…Palladium-catalyzed conjugate addition of arylboronic acids to β,β-disubstituted enones in aqueous media is reported. Additions of a wide range of arylboronic…”
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Enantioselective Synthesis of Polycyclic Nitrogen Heterocycles by Rh-Catalyzed Alkene Hydroacylation: Constructing Six-Membered Rings in the Absence of Chelation Assistance
Published in Organic letters (01-08-2014)“…Catalytic, enantioselective hydroacylations of N-allylindole-2-carboxaldehydes and N-allylpyrrole-2-carboxaldehydes are reported. In contrast to many alkene…”
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