Search Results - "Stöckl, Yannick"
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Synthesis and Functionalization of Tertiary Propargylic Boronic Esters by Alkynyllithium-Mediated 1,2-Metalate Rearrangement of Borylated Cyclopropanes
Published in Organic letters (09-12-2022)“…Implementing the use of alkynyllithium reagents in a stereospecific 1,2-metalate rearrangement-mediated ring opening of polysubstituted cyclopropyl boronic…”
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Synthesis of Highly Functionalized Hydrindanes via Sequential Organocatalytic Michael/Mukaiyama Aldol Addition and Telescoped Hydrozirconation/Cross-Coupling as Key Steps: En Route to the AB System of Clifednamides
Published in Journal of organic chemistry (04-06-2021)“…The AB ring systems of the clifednamide family, polycyclic tetramate macrolactames (PoTeMs), were prepared by a new, convergent approach employing an…”
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Deoxycyanamidation of Alcohols with N‑Cyano‑N‑phenyl-p-methylbenzenesulfonamide (NCTS)
Published in Organic letters (21-07-2017)“…The first one-pot deoxycyanamidation of alcohols has been developed using N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) as both a sulfonyl transfer…”
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Chirality Transfer of Stereogenic Boron Centers Enabled by a SN2‑Type Mechanism
Published in Organometallics (12-02-2024)“…Enantioenriched boron chelates show promising synthetic and luminescent properties; however, the challenging synthesis makes these compounds scarce. In our…”
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Enantioenriched Boron C,N‐Chelates via Chirality Transfer
Published in Chemistry : a European journal (20-07-2023)“…Molecules stereogenic only at tetrahedral boron atoms show great promise for applications, for example as chiroptical materials, but are scarcely investigated…”
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Chirality Transfer of Stereogenic Boron Centers Enabled by a S N 2-Type Mechanism
Published in Organometallics (12-02-2024)Get full text
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Chasing Polycyclic Natural Products: 5/6/5‐ or 5/6/6‐Carbotricyclic Scaffold Construction via Stereodivergent Diels‐Alder Reaction of Chiral Hydrindanes and Their Boron Complexes
Published in European journal of organic chemistry (14-07-2022)“…Chiral trans‐hydrindanes (bicyclo[4.3.0]nonanes) are important building blocks of polycyclic natural products. In order to access 5/6/5‐ and…”
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Fluorophobic Effect Promoting Lamellar Self‐Assembly of Donor Acceptor Dyes
Published in Chemphyschem (19-10-2018)“…To combine liquid crystalline and linear optical properties in the same molecule, the fluorophobic effect was probed for the first time in donor acceptor dyes…”
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Cover Feature: Large Electro‐Optic Kerr Effect in Ionic Liquid Crystals: Connecting Features of Liquid Crystals and Polyelectrolytes (ChemPhysChem 18/2018)
Published in Chemphyschem (18-09-2018)“…The Cover Feature shows an ionic liquid crystal (ILC, see molecular model) on interdigitating platinum‐electrodes (background) which were used to measure the…”
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Large Electro‐Optic Kerr Effect in Ionic Liquid Crystals: Connecting Features of Liquid Crystals and Polyelectrolytes
Published in Chemphyschem (18-09-2018)“…The electro‐optic Kerr effect in simple dipolar fluids such as nitrobenzene has been widely applied in electro‐optical phase modulators and light shutters. In…”
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