Search Results - "Space, Brian"

Synergistic sorbent separation for one-step ethylene purification from a four-component mixture by Chen, Kai-Jie, Madden, David G, Mukherjee, Soumya, Pham, Tony, Forrest, Katherine A, Kumar, Amrit, Space, Brian, Kong, Jie, Zhang, Qiu-Yu, Zaworotko, Michael J

“…Purification of ethylene (C H ), the largest-volume product of the chemical industry, currently involves energy-intensive processes such as chemisorption (CO…”
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A Stable Metal–Organic Framework Featuring a Local Buffer Environment for Carbon Dioxide Fixation by He, Hongming, Sun, Qi, Gao, Wenyang, Perman, Jason A., Sun, Fuxing, Zhu, Guangshan, Aguila, Briana, Forrest, Katherine, Space, Brian, Ma, Shengqian

“…A majority of metal–organic frameworks (MOFs) fail to preserve their physical and chemical properties after exposure to acidic, neutral, or alkaline aqueous…”
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A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane by Niu, Zheng, Cui, Xili, Pham, Tony, Lan, Pui Ching, Xing, Huabin, Forrest, Katherine A., Wojtas, Lukasz, Space, Brian, Ma, Shengqian

“…As a major greenhouse gas, methane, which is directly vented from the coal‐mine to the atmosphere, has not yet drawn sufficient attention. To address this…”
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A MOF‐based Ultra‐Strong Acetylene Nano‐trap for Highly Efficient C2H2/CO2 Separation by Niu, Zheng, Cui, Xili, Pham, Tony, Verma, Gaurav, Lan, Pui Ching, Shan, Chuan, Xing, Huabin, Forrest, Katherine A., Suepaul, Shanelle, Space, Brian, Nafady, Ayman, Al‐Enizi, Abdullah M., Ma, Shengqian

“…Porous materials with open metal sites have been investigated to separate various gas mixtures. However, open metal sites show the limitation in the separation…”
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Enhanced Gas Uptake in a Microporous Metal–Organic Framework via a Sorbate Induced-Fit Mechanism by Yu, Mei-Hui, Space, Brian, Franz, Douglas, Zhou, Wei, He, Chaohui, Li, Libo, Krishna, Rajamani, Chang, Ze, Li, Wei, Hu, Tong-Liang, Bu, Xian-He

“…Physical adsorption of gas molecules in microporous materials is an exothermic process, with desorption entropy driving a decrease in uptake with temperature…”
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Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO2 by Chen, Kai-Jie, Madden, David G., Pham, Tony, Forrest, Katherine A., Kumar, Amrit, Yang, Qing-Yuan, Xue, Wei, Space, Brian, Perry IV, John J., Zhang, Jie-Peng, Chen, Xiao-Ming, Zaworotko, Michael J.

“…Porous materials capable of selectively capturing CO2 from flue‐gases or natural gas are of interest in terms of rising atmospheric CO2 levels and methane…”
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Radiation-resistant metal-organic framework enables efficient separation of krypton fission gas from spent nuclear fuel by Elsaidi, Sameh K., Mohamed, Mona H., Helal, Ahmed S., Galanek, Mitchell, Pham, Tony, Suepaul, Shanelle, Space, Brian, Hopkinson, David, Thallapally, Praveen K., Li, Ju

“…Capture and storage of volatile radionuclides that result from processing of used nuclear fuel is a major challenge. Solid adsorbents, in particular…”
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New Reticular Chemistry of the Rod Secondary Building Unit: Synthesis, Structure, and Natural Gas Storage of a Series of Three-Way Rod Amide-Functionalized Metal–Organic Frameworks by Zhang, Yu-Feng, Zhang, Zong-Hui, Ritter, Logan, Fang, Han, Wang, Qian, Space, Brian, Zhang, Yue-Biao, Xue, Dong-Xu, Bai, Junfeng

“…Reticular chemistry and methane storage materials have been predominately focused on finite metal-cluster-based metal–organic frameworks (MOFs). In contrast,…”
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Halogen–C2H2 Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C2H2/CO2 Separation Selectivity by Mukherjee, Soumya, He, Yonghe, Franz, Douglas, Wang, Shi‐Qiang, Xian, Wan‐Ru, Bezrukov, Andrey A., Space, Brian, Xu, Zhengtao, He, Jun, Zaworotko, Michael J.

“…Acetylene (C2H2) capture is a step in a number of industrial processes, but it comes with a high‐energy footprint. Although physisorbents have the potential to…”
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One-step ethylene production from a four-component gas mixture by a single physisorbent by Cao, Jian-Wei, Mukherjee, Soumya, Pham, Tony, Wang, Yu, Wang, Teng, Zhang, Tao, Jiang, Xue, Tang, Hui-Juan, Forrest, Katherine A., Space, Brian, Zaworotko, Michael J., Chen, Kai-Jie

“…One-step adsorptive purification of ethylene (C 2 H 4 ) from four-component gas mixtures comprising acetylene (C 2 H 2 ), ethylene (C 2 H 4 ), ethane (C 2 H 6…”
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Hybrid Ultra-Microporous Materials for Selective Xenon Adsorption and Separation by Mohamed, Mona H., Elsaidi, Sameh K., Pham, Tony, Forrest, Katherine A., Schaef, Herbert T., Hogan, Adam, Wojtas, Lukasz, Xu, Wenqian, Space, Brian, Zaworotko, Michael J., Thallapally, Praveen K.

“…The demand for Xe/Kr separation continues to grow due to the industrial significance of high‐purity Xe gas. Current separation processes rely on energy…”
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Effect of ring rotation upon gas adsorption in SIFSIX-3-M (M = Fe, Ni) pillared square grid networks by Elsaidi, Sameh K, Mohamed, Mona H, Simon, Cory M, Braun, Efrem, Pham, Tony, Forrest, Katherine A, Xu, Wenqian, Banerjee, Debasis, Space, Brian, Zaworotko, Michael J, Thallapally, Praveen K

“…Dynamic and flexible metal-organic frameworks (MOFs) that respond to external stimuli, such as stress, light, heat, and the presence of guest molecules, hold…”
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Putting the Squeeze on CH4 and CO2 through Control over Interpenetration in Diamondoid Nets by Elsaidi, Sameh K, Mohamed, Mona H, Wojtas, Lukasz, Chanthapally, Anjana, Pham, Tony, Space, Brian, Vittal, Jagadese J, Zaworotko, Michael J

“…We report the synthesis, structure, and sorption properties of a family of eight diamondoid (dia) metal–organic materials (MOMs) that are sustained by Co(II)…”
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Efficient CO2 Removal for Ultra‐Pure CO Production by Two Hybrid Ultramicroporous Materials by Chen, Kai‐Jie, Yang, Qing‐Yuan, Sen, Susan, Madden, David G., Kumar, Amrit, Pham, Tony, Forrest, Katherine A., Hosono, Nobuhiko, Space, Brian, Kitagawa, Susumu, Zaworotko, Michael J.

“…Removal of CO2 from CO gas mixtures is a necessary but challenging step during production of ultra‐pure CO as processed from either steam reforming of…”
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On the Mechanism of Hydrogen Storage in a Metal−Organic Framework Material by Belof, Jonathan L, Stern, Abraham C, Eddaoudi, Mohamed, Space, Brian

“…Monte Carlo simulations were performed modeling hydrogen sorption in a recently synthesized metal−organic framework material (MOF) that exhibits large…”
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Efficient propyne/propadiene separation by microporous crystalline physiadsorbents by Peng, Yun-Lei, Wang, Ting, Jin, Chaonan, Deng, Cheng-Hua, Zhao, Yanming, Liu, Wansheng, Forrest, Katherine A., Krishna, Rajamani, Chen, Yao, Pham, Tony, Space, Brian, Cheng, Peng, Zaworotko, Michael J., Zhang, Zhenjie

“…Selective separation of propyne/propadiene mixture to obtain pure propadiene (allene), an essential feedstock for organic synthesis, remains an unsolved…”
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Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution by Nugent, Patrick, Rhodus, Vanessah, Pham, Tony, Tudor, Brant, Forrest, Katherine, Wojtas, Lukasz, Space, Brian, Zaworotko, Michael

“…Pillar substitution in a long-known metal-organic material with saturated metal centres, [Cu(bipy)(2)(SiF(6))](n), has afforded the first crystallographically…”
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Understanding the H2 Sorption Trends in the M‑MOF-74 Series (M = Mg, Ni, Co, Zn) by Pham, Tony, Forrest, Katherine A, Banerjee, Rahul, Orcajo, Gisela, Eckert, Juergen, Space, Brian

“…Electronic structure calculations and simulations of H2 sorption were performed in four members of the M-MOF-74 series: Mg-MOF-74, Ni-MOF-74, Co-MOF-74, and…”
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Highly Selective Separation of C2H2 from CO2 by a New Dichromate-Based Hybrid Ultramicroporous Material by Scott, Hayley S, Shivanna, Mohana, Bajpai, Alankriti, Madden, David G, Chen, Kai-Jie, Pham, Tony, Forrest, Katherine A, Hogan, Adam, Space, Brian, Perry IV, John J, Zaworotko, Michael J

“…A new hybrid ultramicroporous material, [Ni­(1,4-di­(pyridine-2-yl)­benzene)2(Cr2O7)] n (DICRO-4-Ni-i), has been prepared and structurally characterized. Pure…”
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Tuning the Selectivity between C2H2 and CO2 in Molecular Porous Materials by Forrest, Katherine A, Pham, Tony, Chen, Kai-Jie, Jiang, Xue, Madden, David G, Franz, Douglas M, Hogan, Adam, Zaworotko, Michael J, Space, Brian

“…A combined experimental and theoretical study of C2H2 and CO2 adsorption and separation was performed in two isostructural molecular porous materials (MPMs):…”
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