Search Results - "Sowa Jr, John R."
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Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Allylic Alcohols by an Enantioselective Isomerization/Transfer Hydrogenation Mechanism
Published in Angewandte Chemie International Edition (27-02-2012)“…Reducing hazards: A asymmetric transfer hydrogen reaction was developed to reduce prochiral allylic alcohols in high yield and excellent enantioselectivity…”
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Inclusion of Organic Vapors by Crystalline, Solvatochromic [Pt(aryl isonitrile)4][Pd(CN)4] Compounds. "Vapochromic" Environmental Sensors
Published in Chemistry of materials (01-01-1995)Get full text
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3
A rapid, acetonitrile-free, HPLC method for determination of melamine in infant formula
Published in Analytica chimica acta (30-04-2010)“…A simple, precise, accurate and validated, acetonitrile-free, reverse phase high performance liquid chromatography (HPLC) method is developed for the…”
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Utilizing Native Directing Groups: Mechanistic Understanding of a Direct Arylation Leads to Formation of Tetracyclic Heterocycles via Tandem Intermolecular, Intramolecular C–H Activation
Published in Journal of organic chemistry (21-06-2019)“…A mechanistic study on a direct arylation using a native picolylamine directing group is reported. Kinetic studies determined the concentration dependence of…”
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Quantitative Analysis of Polycyclic Aromatic Hydrocarbons at Part Per Billion Levels in Fish Oil by Headspace Solid-Phase Microextraction and Gas Chromatography-Mass Spectrometry (HS-SPME-GC-MS)
Published in Journal of chromatographic science (01-01-2019)“…Abstract Headspace solid-phase microextraction (HS-SPME) was used in combination with gas chromatography-mass spectrometry (GC-MS) for the analysis of…”
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Asymmetric Transfer Hydrogenation of Secondary Allylic Alcohols
Published in European journal of organic chemistry (01-03-2015)“…Racemic secondary allylic alcohols were transformed into optically active secondary alcohols by a combined Ru‐catalyzed isomerization/asymmetric…”
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Attenuated total reflection infrared spectroscopy (ATR-IR) as an in situ technique for dissolution studies
Published in Journal of pharmaceutical and biomedical analysis (02-11-2010)“…Dissolution studies are critical tests for measuring the performance of a drug product. We have developed a novel technique using in situ ATR-IR spectroscopy…”
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Suzuki-Miyaura Cross-Coupling With Quasi-Heterogeneous Palladium
Published in Advanced synthesis & catalysis (01-08-2003)“…The Suzuki–Miyaura cross‐coupling reaction using heterogeneous Pd/C has a homogeneous component. The soluble palladium concentration increases during the…”
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What is the Rate of the Csp2−Csp2 Reductive Elimination Step? Revealing an Unusually Fast Ni-Catalyzed Negishi-Type Oxidative Coupling Reaction
Published in Journal of the American Chemical Society (29-07-2009)“…For a direct quantitative investigation of the Csp2−Csp2 reductive elimination rate within a catalytic cycle, a novel oxidative coupling system in the presence…”
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Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Allylic Alcohols by an Enantioselective Isomerization/Transfer Hydrogenation Mechanism
Published in Angewandte Chemie (27-02-2012)“…Reduzierte Gefahr: Mit der Titelreaktion werden prochirale Allylalkohole mit hohen Ausbeuten und exzellenten Enantioselektivitäten reduziert (siehe Beispiel)…”
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Kinetic study on the epimerization of trityloxymethyl butyrolactol by liquid chromatography
Published in Journal of Chromatography A (23-07-2004)“…The epimerization of trityloxymethyl butyrolactol has been investigated using dynamic chromatography and an approximation function introduced by Trapp and…”
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A theoretical investigation on the mechanism of a palladium-mediated formal 6pi electrocyclic synthesis of 9,10-dihydrophenanthrenes
Published in Journal of organic chemistry (05-02-2010)“…Recently, a new method for the palladium-catalyzed synthesis of 9,10-dihydrophenanthrenes was published. A proposed mechanism indicated that the reaction…”
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13
Kinetic analysis of the asymmetric amplification exhibited by B-chlorodiisopinocampheylborane
Published in Journal of physical organic chemistry (01-04-2004)“…A quantitative investigation was undertaken to determine experimentally the relative reaction rates of the heterochiral and homochiral species of…”
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p-Decylphenyl isocyanide and p-decylbenzonitrile: isomorphous isonitrile/nitrile isomers
Published in Acta crystallographica. Section C, Crystal structure communications (01-06-2004)“…p‐Decylphenyl isocyanide, p‐C10H21–C6H4–NC or C17H25N, and p‐decylbenzonitrile, p‐C10H21–C6H4–CN or C17H25N, are isomorphous. The molecules lie in mirror…”
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p-decylphenyl isocyanide and p-decylbenzonitrile: isomorphous isonitrile/nitrile isomers
Published in Acta crystallographica. Section C, Crystal structure communications (01-06-2004)“…p-Decylphenyl isocyanide, p-C(10)H(21)-C(6)H(4)-NC or C(17)H(25)N, and p-decylbenzonitrile, p-C(10)H(21)-C(6)H(4)-CN or C(17)H(25)N, are isomorphous. The…”
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