Search Results - "Song, Jinshuai"

Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight by Ma, Qiang, Song, Jinshuai, Zhang, Xun, Jiang, Yu, Ji, Li, Liao, Saihu

“…Organocatalytic atom transfer radical polymerization (O-ATRP) is recently emerging as an appealing method for the synthesis of metal-free polymer materials…”
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Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift by Yu, Yinghua, Chakraborty, Pushkin, Song, Jinshuai, Zhu, Lei, Li, Chunsen, Huang, Xueliang

“…Reactions that efficiently construct medium-sized lactones are significant, as they overcome the unfavorable entropic factor and transannular interactions for…”
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Electrophotocatalytic Decarboxylative C−H Functionalization of Heteroarenes by Lai, Xiao‐Li, Shu, Xiao‐Min, Song, Jinshuai, Xu, Hai‐Chao

“…Decarboxylative C−H functionalization reactions are highly attractive methods for forging carbon–carbon bonds considering their inherent step‐ and…”
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Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations by Cai, Chen-Yan, Wu, Zheng-Jian, Liu, Ji-Ying, Chen, Ming, Song, Jinshuai, Xu, Hai-Chao

“…Oxidative allylic C–H functionalization is a powerful tool to streamline organic synthesis as it minimizes the need for functional group activation and…”
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Site‐Selective Electrochemical Benzylic C−H Amination by Hou, Zhong‐Wei, Liu, Ding‐Jin, Xiong, Peng, Lai, Xiao‐Li, Song, Jinshuai, Xu, Hai‐Chao

“…C−H/N‐H cross‐coupling is an ideal strategy to synthesize various amines but remains challenging owing to the requirement for sacrificial chemical oxidants and…”
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Electrochemical C–H phosphorylation of arenes in continuous flow suitable for late-stage functionalization by Long, Hao, Huang, Chong, Zheng, Yun-Tao, Li, Zhao-Yu, Jie, Liang-Hua, Song, Jinshuai, Zhu, Shaobin, Xu, Hai-Chao

“…The development of efficient and sustainable methods for carbon-phosphorus bond formation is of great importance due to the wide application of…”
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Cathode Material Determines Product Selectivity for Electrochemical C−H Functionalization of Biaryl Ketoximes by Zhao, Huai‐Bo, Xu, Pin, Song, Jinshuai, Xu, Hai‐Chao

“…The synthesis of polycyclic N‐heteroaromatic compounds and their corresponding N‐oxides has been developed through electrochemical C−H functionalization of…”
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Reagent‐Free C−H/N−H Cross‐Coupling: Regioselective Synthesis of N‐Heteroaromatics from Biaryl Aldehydes and NH3 by Zhao, Huai‐Bo, Liu, Zhan‐Jiang, Song, Jinshuai, Xu, Hai‐Chao

“…An unprecedented synthesis of N‐heteroaromatics from biaryl aldehydes and NH3 through reagent‐free C−H/N−H cross‐coupling has been developed. The…”
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TEMPO-Catalyzed Electrochemical C–H Thiolation: Synthesis of Benzothiazoles and Thiazolopyridines from Thioamides by Qian, Xiang-Yang, Li, Shu-Qi, Song, Jinshuai, Xu, Hai-Chao

“…Benzothiazoles and thiazolopyridines are widely prevalent in pharmaceuticals and organic materials. Herein, we report a metal- and reagent-free method for the…”
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Fenton-Derived OH Radicals Enable the MPnS Enzyme to Convert 2‑Hydroxyethylphosphonate to Methylphosphonate: Insights from Ab Initio QM/MM MD Simulations by Wang, Binju, Cao, Zexing, Rovira, Carme, Song, Jinshuai, Shaik, Sason

“…The mechanism for dioxygen activation represents one of the core issues in metalloenzymes. In most cases, the activation of the O2 molecule requires additional…”
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The Mechanism of Homogeneous CO2 Reduction by Ni(cyclam): Product Selectivity, Concerted Proton–Electron Transfer and C–O Bond Cleavage by Song, Jinshuai, Klein, Eric L, Neese, Frank, Ye, Shengfa

“…Homogeneous CO2 reduction catalyzed by [NiI(cyclam)]+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) exhibits high efficiency and selectivity yielding CO only at…”
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Electrochemical C−H/N−H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles by Hou, Zhong-Wei, Mao, Zhong-Yi, Zhao, Huai-Bo, Melcamu, Yared Yohannes, Lu, Xin, Song, Jinshuai, Xu, Hai-Chao

“…Indoles and azaindoles are among the most important heterocycles because of their prevalence in nature and their broad utility in pharmaceutical industry…”
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Electrochemical aromatic C–H hydroxylation in continuous flow by Long, Hao, Chen, Tian-Sheng, Song, Jinshuai, Zhu, Shaobin, Xu, Hai-Chao

“…The direct hydroxylation of arene C–H bonds is a highly sought-after transformation but remains an unsolved challenge due to the difficulty in efficient and…”
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Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination by Wu, Zheng‐Jian, Su, Feng, Lin, Weidong, Song, Jinshuai, Wen, Ting‐Bin, Zhang, Hui‐Jun, Xu, Hai‐Chao

“…Transition metal catalyzed C−H phosphorylation remains an unsolved challenge. Reported methods are generally limited in scope and require stoichiometric silver…”
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Amidinyl Radical Formation through Anodic N−H Bond Cleavage and Its Application in Aromatic C−H Bond Functionalization by Zhao, Huai‐Bo, Hou, Zhong‐Wei, Liu, Zhan‐Jiang, Zhou, Ze‐Feng, Song, Jinshuai, Xu, Hai‐Chao

“…We report herein an atom‐economical and sustainable approach to access amidinyl radical intermediates through the anodic cleavage of N−H bonds. The resulting…”
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Electrochemical Synthesis of Polycyclic N‑Heteroaromatics through Cascade Radical Cyclization of Diynes by Hou, Zhong-Wei, Mao, Zhong-Yi, Song, Jinshuai, Xu, Hai-Chao

“…An electrochemical cyclization reaction of easily available urea-tethered diynes has been developed for the synthesis of nitrogen-doped polycyclic aromatic…”
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Computational advances aiding mechanistic understanding of silver-catalyzed carbene/nitrene/silylene transfer reactions by Zhang, Jing, Shan, Chunhui, Zhang, Tao, Song, Jinshuai, Liu, Tao, Lan, Yu

“…Theoretical advances on the mechanistic study of Ag-catalyzed carbene/nitrene/silylene transfer reactions were summarized in this review, which could be…”
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Theory Demonstrated a “Coupled” Mechanism for O2 Activation and Substrate Hydroxylation by Binuclear Copper Monooxygenases by Wu, Peng, Fan, Fangfang, Song, Jinshuai, Peng, Wei, Liu, Jia, Li, Chunsen, Cao, Zexing, Wang, Binju

“…Multiscale simulations have been performed to address the longstanding issue of “dioxygen activation” by the binuclear copper monooxygenases (PHM and DβM),…”
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Unraveling the Pivotal Roles of Various Metal Ion Centers in the Catalysis of Quercetin 2,4-Dioxygenases by Yan, Xueyuan, Xiao, Han, Song, Jinshuai, Li, Chunsen

“…Quercetin 2,4-dioxygenase (QueD) with various transition metal ion co-factors shows great differences, but the internal reasons have not been illustrated in…”
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Electronic Structure of a Formal Iron(0) Porphyrin Complex Relevant to CO2 Reduction by Römelt, Christina, Song, Jinshuai, Tarrago, Maxime, Rees, Julian A, van Gastel, Maurice, Weyhermüller, Thomas, DeBeer, Serena, Bill, Eckhard, Neese, Frank, Ye, Shengfa

“…Iron porphyrins can act as potent electrocatalysts for CO2 functionalization. The catalytically active species has been proposed to be a formal Fe(0) porphyrin…”
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