Search Results - "Solodova, Ekaterina V."
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Synthesis of novel β-dialkylamino-α,β-unsaturated trifluoromethylketones containing cyclobutene fragment and their reactions with organolithium and Grignard reagents
Published in Tetrahedron (08-05-2010)“…The highly reactive trifluoromethylenaminoketones, with a strained cyclobutene and norbornadiene moieties were firstly prepared from the corresponding…”
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The general approach for the synthesis of substituted cyclobutenyl- and norbornadienyllithiums containing masked trifluoromethyl group
Published in Tetrahedron (11-12-2010)“…α,β-Unsaturated trifluoromethylketones of cyclobutene number containing trimethylstannyl substituent in β-position were firstly prepared by the addition of…”
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Synthesis of novel a,ß-unsaturated trifluoromethylketones with cyclobutene structure and their use for the preparation of bicyclic trifluoromethylated pyrroles
Published in Journal of fluorine chemistry (01-03-2018)“…A partial reduction of the strained β-pyrrolidino-α,β-unsaturated trifluoromethyl ketones with LiAlH4 gives the corresponding α,β-unsaturated trifluoromethyl…”
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Synthesis of novel α,β-unsaturated trifluoromethylketones with cyclobutene structure and their use for the preparation of bicyclic trifluoromethylated pyrroles
Published in Journal of fluorine chemistry (01-03-2018)“…[Display omitted] •Selective reduction of carbon-carbon double bond in β-pyrrolidino-α,β-unsaturated trifluoromethyl ketones with LiAlH4.•Acid induced…”
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1-Bromo-2-trifluoroacetylcyclobutenes as novel building blocks for the construction of trifluoromethyl substituted heterocycles. Part 3: Synthesis of trifluoromethylsubstituted pyridines, condensed with cyclobutene moieties
Published in Journal of fluorine chemistry (01-08-2010)“…This paper describes a general synthetic approach to 3-cyano-4-trifluoromethylpyridines fused with cyclobutene rings with variable spiro conjunctions. The…”
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Synthesis and unusual [2+2]-cycloaddition reactions of ethyl 4-chloro-2-oxobut-3-ynoate with unactivated alkenes
Published in Tetrahedron (29-09-2008)“…The highly activated acetylenes, ethyl 4-chloro-2-oxobut-3-ynoate and ethyl 4-bromo-2-oxobut-3-ynoate, were prepared from readily available…”
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1-Bromo-2-trifluoroacetylcyclobutenes as novel building blocks for the construction of trifluoromethyl substituted heterocycles. Part 2: Synthesis of trifluoromethyl substituted thiophenes, condensed with cyclobutene moieties
Published in Journal of fluorine chemistry (01-08-2010)“…This paper describes a novel synthetic approach to 2-cyano-3-trifluoromethylthiophenes fused with cyclobutene rings with variable spiro conjunctions. The…”
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1-Bromo-2-trifluoroacetylcyclobutenes as novel building blocks for the construction of trifluoromethyl substituted heterocycles. Part 1: Synthesis of 5-(trifluoromethyl)-2(5 H)-furanones condensed with substituted cyclobutenes
Published in Journal of fluorine chemistry (01-06-2010)“…The regioselective reduction of substituted 1-bromo-2-trifluoroacetylcyclobutenes by lithium aluminium hydride affords corresponding brominated alcohols,…”
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