Search Results - "Sokolov, Alexei P."
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Fundamental Limitations of Ionic Conductivity in Polymerized Ionic Liquids
Published in Macromolecules (13-11-2018)“…We present detailed studies of ionic conductivity in several polymerized ionic liquids (PolyILs) with different size of mobile ions. Presented analysis…”
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2
Protein dynamics in a broad frequency range: Dielectric spectroscopy studies
Published in Journal of non-crystalline solids (01-01-2015)“…We present detailed dielectric spectroscopy studies of dynamics in two hydrated proteins, lysozyme and myoglobin. We emphasize the importance of explicit…”
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Atomistic details of protein dynamics and the role of hydration water
Published in Biochimica et biophysica acta. General subjects (01-01-2017)“…The importance of protein dynamics for their biological activity is now well recognized. Different experimental and computational techniques have been employed…”
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Rigidity, Secondary Structure, and the Universality of the Boson Peak in Proteins
Published in Biophysical journal (17-06-2014)“…Complementary neutron- and light-scattering results on nine proteins and amino acids reveal the role of rigidity and secondary structure in determining the…”
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5
Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids
Published in Macromolecules (28-06-2016)“…The unique properties of ionic liquids (ILs) have made them promising candidates for electrochemical applications. Polymerization of the corresponding ILs…”
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Big Effect of Small Nanoparticles: A Shift in Paradigm for Polymer Nanocomposites
Published in ACS nano (24-01-2017)“…Polymer nanocomposites (PNCs) are important materials that are widely used in many current technologies and potentially have broader applications in the future…”
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Dynamics at the Polymer/Nanoparticle Interface in Poly(2-vinylpyridine)/Silica Nanocomposites
Published in Macromolecules (11-03-2014)“…The static and dynamic properties of poly(2-vinylpyridine)/silica nanocomposites are investigated by temperature modulated differential scanning calorimetry,…”
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8
Unraveling the Mechanism of Nanoscale Mechanical Reinforcement in Glassy Polymer Nanocomposites
Published in Nano letters (08-06-2016)“…The mechanical reinforcement of polymer nanocomposites (PNCs) above the glass transition temperature, T g, has been extensively studied. However, not much is…”
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9
The Role of Chain-End Association Lifetime in Segmental and Chain Dynamics of Telechelic Polymers
Published in Macromolecules (13-11-2018)“…Broadband dielectric spectroscopy, differential scanning calorimetry, and rheology were employed to study the impact of hydrogen (H)-bonding end-groups on…”
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10
Strong Reduction in Amplitude of the Interfacial Segmental Dynamics in Polymer Nanocomposites
Published in Macromolecules (26-05-2020)“…Despite the wide use of polymer nanocomposites (PNCs) in various applications, our understanding of the microscopic parameters controlling their macroscopic…”
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11
Identification of Structural Relaxation in the Dielectric Response of Water
Published in Physical review letters (09-06-2016)“…One century ago pioneering dielectric results obtained for water and n-alcohols triggered the advent of molecular rotation diffusion theory considered by Debye…”
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12
Examination of the fundamental relation between ionic transport and segmental relaxation in polymer electrolytes
Published in Polymer (Guilford) (05-08-2014)“…Replacing traditional liquid electrolytes by polymers will significantly improve electrical energy storage technologies. Despite significant advantages for…”
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13
Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers
Published in Macromolecules (12-05-2020)“…Fabrication of stretchable functional polymeric materials usually relies on the physical adhesion between functional components and elastic polymers, while the…”
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14
Temperature Dependence of Structural Relaxation in Glass-Forming Liquids and Polymers
Published in Entropy (Basel, Switzerland) (01-08-2022)“…Understanding the microscopic mechanism of the transition of glass remains one of the most challenging topics in Condensed Matter Physics. What controls the…”
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15
Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites
Published in ACS nano (26-07-2016)“…It is generally believed that the strength of the polymer–nanoparticle interaction controls the modification of near-interface segmental mobility in polymer…”
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16
Decoupling of ionic transport from segmental relaxation in polymer electrolytes
Published in Physical review letters (23-02-2012)“…We present detailed studies of the relationship between ionic conductivity and segmental relaxation in polymer electrolytes. The analysis shows that the ionic…”
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17
Interfacial Properties of Polymer Nanocomposites: Role of Chain Rigidity and Dynamic Heterogeneity Length Scale
Published in Macromolecules (28-03-2017)“…While it is known that the properties of polymer nanocomposites are largely dominated by the interfacial layer around nanoparticles, the molecular parameters…”
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18
Transient Nonlinear Response of Dynamically Decoupled Ionic Conductors
Published in Physical review letters (10-08-2018)“…The present study demonstrates that large electric fields progressively enhance the conductivity of ionic systems up to timescales corresponding to those on…”
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19
Distilling nanoscale heterogeneity of amorphous silicon using tip-enhanced Raman spectroscopy (TERS) via multiresolution manifold learning
Published in Nature communications (25-01-2021)“…Accurately identifying the local structural heterogeneity of complex, disordered amorphous materials such as amorphous silicon is crucial for accelerating…”
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20
Effect of Chain Rigidity on the Decoupling of Ion Motion from Segmental Relaxation in Polymerized Ionic Liquids: Ambient and Elevated Pressure Studies
Published in Macromolecules (12-09-2017)“…Conductivity in polymer electrolytes has been generally discussed with the assumption that the segmental motions control charge transport. However, much less…”
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