Search Results - "Sobolev, B.P"
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The periodicity of negative thermal expansion in rare earth trifluorides
Published in Journal of solid state chemistry (01-01-2023)“…Negative thermal expansion (NTE) in trifluorides of rare earth elements (REEs – R) is considered. The electronic structure of R divides RF3 into two…”
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Full quasi-system “from LaF3 to LuF3” as a combination of 14 binary systems of lanthanide trifluorides with maximal chemical proximity
Published in Journal of solid state chemistry (01-08-2022)“…The combination of 15 RF3 (R – rare earth elements – REEs without ScF3 and YF3) into one system “from LaF3 to LuF3” we call a full quasi-system (QS). It…”
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Electron diffraction study and ionic conductivity of fluorite Ba1-xLaxF2+x and tysonite La1-yBayF3-y phases in the BaF2-LaF3 system
Published in Solid state ionics (15-11-2022)“…Crystals of fluorite phases with the CaF2 structure: Ba1−xLaxF2+x (x = 0, 0.05, 0.105, 0.25, 0.35, 0.40) and those of tysonite ones with the LaF3 structure:…”
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Lanthanum and Lanthanide Trifluorides: Lanthanide Contraction and Volume of Fluorine Ion
Published in Crystallography reports (01-03-2020)“…Lanthanide contraction of lanthanum and 14 lanthanides ( Ln ), leading to a decrease in R 3+ ionic radii by ~15% (with respect to the smallest one) with an…”
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Nonstoichiometry in Inorganic Fluorides. IV: The Initial Stage of Anionic Nonstoichiometry in RF3 (R = Y, La, Ln)
Published in Crystallography reports (01-05-2021)“…The anionic nonstoichiometry in inorganic fluorides is at result of substitution of F 1– for O 2– in the anionic sublattice. All families of fluorides exhibit…”
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Nanostructure and F-ionic conductivity of La1−Sr F3− tysonite crystals
Published in Solid state ionics (01-07-2016)Get full text
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Nonstoichiometry in Inorganic Fluorides. III: Anionic Nonstoichiometry in MF2 (M = Ca, Sr, Ba)
Published in Crystallography reports (2020)“…Anionic nonstoichiometry in fluorides (replacement of F 1– with O 2– ) deteriorates the quality of optical materials. Two reviews have been devoted to the…”
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Nanostructure and F-ionic conductivity of La1−ySryF3−y tysonite crystals
Published in Solid state ionics (01-07-2016)“…Phase composition of La1−ySryF3−y (y=0, 0.05, 0.0725, 0.10, 0.15) crystals with the tysonite-type (LaF3) structure has been studied by electron diffraction and…”
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Cation ordered structure and F-ionic conductivity of Er0.7Ca0.3F2.7 tysonite-type crystals
Published in Solid state ionics (15-10-2015)“…Cation ordering in the Er0.7Ca0.3F2.7 monoclinic phase with the tysonite-type (LaF3) structure, which was formed in Er1−yCayF3−y samples of the 65–72.5mol%…”
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Influence of Nonstoichiometry in Fluoride Phase on the Ionic Conductivity of Composite Fluoride‒Oxide Materials 90PrF3 · 10Al2O3 and 90Pr0.95Sr0.05F2.95 · 10Al2O3
Published in Crystallography reports (2018)“…The two-phase fluoride oxide composite 90Pr 0.95 Sr 0.05 F 2.95 · 10Al 2 O 3 (mol %) composed of a highly conductive fluoride matrix with a tysonite structure…”
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Crystal Growth and Thermal Conductivity of the Congruently Melting Solid Solution Cd0.77Sr0.23F2
Published in Inorganic materials (01-05-2019)“…— Crystals of the Cd 0.77 Sr 0.23 F 2 solid solution (sp. gr. Fm m , lattice parameter a = 5.4882(1) Å), corresponding to the minimum in the liquidus and…”
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Growth of Fluorite Solid Solution Crystals in the Ternary SrF2–BaF2–LaF3 System and Investigation of Their Properties
Published in Crystallography reports (01-11-2018)“…A series of three-component isostructural fluorite crystals (Sr 1– x Ba x ) 0.7 La 0.3 F 2.3 (sp. gr. , 0 ≤ x ≤ 1), the compositions of which belong to the Sr…”
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Ionic conductivity of BaF2 + ZnF2 + CdF2 + YbF3 optical fluoride ceramic
Published in Inorganic materials (01-03-2017)“…The electrical conductivity of an optical fluoride ceramic in the quaternary system BaF 2 + ZnF 2 + CdF 2 + YbF 3 has been determined in the temperature range…”
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14
Structural aspects of fast ionic conductivity of rare earth fluorides
Published in Solid state ionics (01-02-2003)“…The structure and ionic conductivity of orthorhombic β-YF 3 structured rare earth fluorides and of tysonite-structured ones are investigated. Temperature…”
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Inelastic neutron scattering study of the superionic solid solutions Ba1−La F2
Published in Solid state ionics (01-04-1999)Get full text
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Properties of CdF2:Ga as a medium for real-time holography
Published in Applied physics. B, Lasers and optics (01-05-2001)“…The metastable nature of the excited state of bistable Ga centers in semiconducting CdF2 crystals allows for the use of CdF2:Ga and CdF2:Ga,Y crystals as…”
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Scintillation characteristics of nonstoichiometric phases formed in MF2–GdF3–CeF3 system Part I. (M=Ba), scintillation of Ba0.9Gd0.1−Ce F2.1 (0⩽x⩽0.1) fluorite-type crystals
Published in Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment (01-01-1999)Get full text
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Scintillation characteristics of nonstoichiometric phases formed in MF2–GdF3–CeF3 system Part II. (M=Ba), scintillation of Ba1−Ce F2+ (0.1⩽x⩽0.45) fluorite type crystals
Published in Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment (01-01-1999)Get full text
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Scintillation characteristics of nonstoichiometric phases formed in MF 2–GdF 3–CeF 3 system Part I. (M=Ba), scintillation of Ba 0.9Gd 0.1− xCe xF 2.1 (0⩽ x⩽0.1) fluorite-type crystals
Published in Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment (1999)“…As the Ce concentration ( x) was increased from 0 to 0.1 (complete replacement of Gd), the emission peak wavelength shifted from 310 (due to Gd 3+ emission) to…”
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Scintillation characteristics of nonstoichiometric phases formed in MF 2–GdF 3–CeF 3 system Part II. (M=Ba), scintillation of Ba 1− xCe xF 2+ x (0.1⩽ x⩽0.45) fluorite type crystals
Published in Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment (1999)“…Among three different Ce-concentrations (10, 27 and 45 mol%) which we tested, the 27 mol% sample showed by far the best radiation hardness and the maximum fast…”
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